Laser ablation tandem mass spectrometry is a burgeoning field forin situRb‐Sr geochronology. Here, we determined simultaneous isotope ratios of87Sr/86Sr and87Rb/86Sr in metamorphic biotite from western Maine, using an ESL™ imageGEO™193 excimer laser ablation system coupled to a Thermo Scientific™ Neoma™ MC‐ICP‐MS/MS. Measurements were made on Faraday cups with Rb+at mass 87; Sr isotopes were reacted with SF6gas and measured as SrF+at masses 103–107. Twenty‐two laser spots in biotite from a single sample yield a traditional Rb‐Sr isochron date of 289 ± 6 Ma. Time‐resolved signals reveal significant zoning in87Sr/86Sr and87Rb/86Sr within single spot analyses, which were used to construct single spot isochrons. Individual laser spots contain multiple isochronous subpopulations; some spots contain up to three distinct Rb‐Sr isochrons that are decoupled from variations in Rb/Sr. Thirty‐five isochron dates were determined using this sub‐spot approach, with87Sr/86Sr intercepts that systematically vary with Rb‐Sr date; two‐point isochrons were calculated for individual integrations (n= 780) based on these variable intercepts. Both methods yield age peaks at 303, 270 and 240 Ma. These data suggest that the Rb‐Sr system has the potential to record multiple heating, cooling or fluid‐alteration events spanning ~ 100 My within small domains in single biotite crystals.
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Thermo‐Hydro‐Chemical Simulation of Mid‐Ocean Ridge Hydrothermal Systems: Static 2D Models and Effects of Paleo‐Seawater Chemistry
Abstract Decades of research have resulted in characterization of the ocean floor manifestations of mid‐ocean ridge (MOR) hydrothermal systems, yet numerical models accounting for the connections between heat transfer, hydrology and geochemistry have been slow to develop. The Thermo‐hydro‐chemical code ToughReact can be used to describe the coupled effects of fluid flow, heat transfer, and fluid‐rock chemical interactions that occur in MOR systems. We describe the results of 2‐dimensional simulations of steady state flow in fractured diabase with mineral‐fluid chemical reactions. Basal heating and specified permeability yield maximum temperature of 400°C. Total fluid flux and high fracture flow velocities are in accord with observations. Fluid chemistry, mineralogical changes and87Sr/86Sr ratios can be compared to observations to assess and calibrate models. Simulated high temperature fracture fluids have Mg and SO4near zero, elevated Ca and87Sr/86Sr of about 0.7040. Total alteration is 10%–50% for simple models of spreading. Anhydrite forms mainly near the base of the upwelling zone and results in substantial local fracture porosity reduction. A calibrated model is used to predict how Sr isotopes and other features of altered oceanic crust would be different in the Cretaceous (95 Ma) early Proterozoic (1,800 Ma) and Archean (3,800 Ma), when seawater may have had high Ca and Sr concentrations, lower pH, higher temperature, and lower Na, Mg, and SO4. The simulations are offered as a start on what ultimately may require a longer‐term community effort to better understand the role of MOR thermo‐hydro‐chemical systems in Earth evolution.
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- Award ID(s):
- 2103214
- PAR ID:
- 10384587
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Geochemistry, Geophysics, Geosystems
- Volume:
- 23
- Issue:
- 12
- ISSN:
- 1525-2027
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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