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Abstract In this concept review, the fundamental and polymerization chemistry of inverse vulcanization for the preparation of statistical and segmented sulfur copolymers, which have been actively developed and advanced in various applications over the past decade is discussed. This concept review delves into a discussion of step‐growth polymerization constructs to describe the inverse vulcanization process and discuss prepolymer approaches for the synthesis of segmented sulfur polyurethanes. Furthermore, this concept review discusses the advantages of inverse vulcanization in conjunction with dynamic covalent polymerization and post‐polymerization modifications to prepare segmented block copolymers with enhanced thermomechanical and flame retardant properties of these materials.
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Nuclear magnetic resonance structural characterization of sulfur‐derived copolymers from inverse vulcanization. Part 1: Styrene
Abstract Organosulfur polymers prepared via the inverse vulcanization of elemental sulfur with olefinic comonomers represent a new class of high‐chalcogenide content organic/inorganic macromolecules. Extensive reporting on new synthetic advances and materials derived from the inverse vulcanization process have been explored in the past decade. However, detailed structural analysis of these sulfur copolymers have not been rigorously conducted, due to the poor solubility of many of these materials, coupled with the numerous side‐reactions that result in complex microstructures from these synthetic methods. In the current report, we revisit analysis of the solution13C NMR spectral data for poly(S‐r‐Sty) and identify for the first time previously unidentified carbon peaks that offer new insights into a corrected repeating unit structure of this sulfur copolymer.
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- PAR ID:
- 10385789
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Journal of Polymer Science
- Volume:
- 60
- Issue:
- 24
- ISSN:
- 2642-4150
- Page Range / eLocation ID:
- p. 3471-3477
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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