Abstract Explosive eruptions expel volcanic gases and particles at high pressures and velocities. Within this multiphase fluid, small ash particles affect the flow dynamics, impacting mixing, entrainment, turbulence, and aggregation. To examine the role of turbulent particle behavior, we conducted an analogue experiment using a particle‐laden jet. We used compressed air as the carrier fluid, considering turbulent conditions at Reynolds numbers from approximately 5,000 to 20,000. Two different particles were examined: 14‐μm diameter solid nickel spheres and 13‐μm diameter hollow glass spheres. These resulted in Stokes numbers between 1 and 35 based on the convective scale. The particle mass percentage in the mixture is varied from 0.3% to more than 20%. Based on a 1‐D volcanic plume model, these Stokes numbers and mass loadings corresponded to millimeter‐scale particle diameters at heights of 4–8 km above the vent during large, sustained eruptions. Through particle image velocimetry, we measured the mean flow behavior and the turbulence statistics in the near‐exit region, primarily focusing on the dispersed phase. We show that the flow behavior is dominated by the particle inertia, with high Stokes numbers reducing the entrainment by more than 40%. When applied to volcanic plumes, these results suggest that high‐density particles can greatly increase the probability of column collapse.
more »
« less
The aquatic particle number quandary
Optical surveys of aquatic particles and their particle size spectra have become important tools in studies of light propagation in water, classification of water masses, and the dynamics of trophic interactions affecting particle aggregation and flux. Here, we demonstrate that typical settings used in image analysis vastly underestimate particle numbers due to the particle – gel continuum. Applying a wide range of threshold values to change the sensitivity of our detection system, we show that macrogels cannot be separated from more dense particles, and that a true particle number per volume cannot be ascertained; only relative numbers in relation to a defined threshold value can be reported. A quandary thus presents itself between choosing a detection threshold low enough to accurately record orders of magnitude more particles on one hand or selecting a higher threshold to yield better image quality of plankton on the other. By observing the dynamics of coagulation and dissolution steps unique to cation-bridged gels abundant in aquatic systems, we find naturally occurring gels, and microscopic particles attached to them, to cause the ill-defined particle numbers. In contrast, the slopes in particle number spectra remained largely unaffected by varying sensitivity settings of the image analysis. The inclusion of fainter particles that are not typically captured by imaging systems provides a window into the true microscale spatial heterogeneity at scales relevant to small plankton organisms and processes that are dependent on particle density such as surface-associated chemical reactions as well as particle coagulation and aggregation dynamics.
more »
« less
- Award ID(s):
- 2128438
- PAR ID:
- 10387754
- Date Published:
- Journal Name:
- Frontiers in Marine Science
- Volume:
- 9
- ISSN:
- 2296-7745
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Gas-phase exchange between aerosol populations via evaporation and condensation of semi-volatile organics can be a major mechanism of mixing between accumulation-mode particles with slow coagulation. This exchange may be impeded in highly viscous, semi-solid, or glassy particles due to diffusion limitations. Here we describe experiments on carefully prepared particle populations representing highly viscous or potentially “glassy” aged organic particles (non-volatile sugars 13 C-glucose, sucrose, and raffinose with ammonium sulfate seeds) and fresh biomass burning particles (erythritol with black carbon seeds) to develop a model phase space for organic aerosol systems and better understand when particle phase state impedes mixing. Our hypothesis is that these limitations are alleviated at some relative humidity threshold, which increases with decreasing ambient temperatures. We quantify the mixing state of these particle populations from 10–25 °C and 5–90% RH using an Aerosol Mass Spectrometer (AMS) combining Event Trigger (ET) and Soot Particle (SP) modes. The observed single particle mass spectra are aggregated in short time slices and used to perform a linear combination of relevant reference spectra to determine the contributions each constituent has on the resulting particle signal. Our results suggest that the non-volatile sugar particles have little to no diffusive limitations to mixing at the conditions tested.more » « less
-
null (Ed.)The characterization of particle and plankton populations, as well as microscale biophysical interactions, is critical to several important research areas in oceanography and limnology. A growing number of aquatic researchers are turning to holography as a tool of choice to quantify particle fields in diverse environments, including but not limited to, studies on particle orientation, thin layers, phytoplankton blooms, and zooplankton distributions and behavior. Holography provides a non-intrusive, free-stream approach to imaging and characterizing aquatic particles, organisms, and behavior in situ at high resolution through a 3-D sampling volume. Compared to other imaging techniques, e.g., flow cytometry, much larger volumes of water can be processed over the same duration, resolving particle sizes ranging from a few microns to a few centimeters. Modern holographic imaging systems are compact enough to be deployed through various modes, including profiling/towed platforms, buoys, gliders, long-term observatories, or benthic landers. Limitations of the technique include the data-intensive hologram acquisition process, computationally expensive image reconstruction, and coherent noise associated with the holograms that can make post-processing challenging. However, continued processing refinements, rapid advancements in computing power, and development of powerful machine learning algorithms for particle/organism classification are paving the way for holography to be used ubiquitously across different disciplines in the aquatic sciences. This review aims to provide a comprehensive overview of holography in the context of aquatic studies, including historical developments, prior research applications, as well as advantages and limitations of the technique. Ongoing technological developments that can facilitate larger employment of this technique toward in situ measurements in the future, as well as potential applications in emerging research areas in the aquatic sciences are also discussed.more » « less
-
null (Ed.)Colloidal gels represent an important class of soft matter, in which networks formed due to strong, short-range interactions display solid-like mechanical properties, such as a finite low-frequency elastic modulus. Here we examine the effect of embedded active colloids on the linear viscoelastic moduli of fractal cluster colloidal gels. We find that the autonomous, out-of-equilibrium dynamics of active colloids incorporated into the colloidal network decreases gel elasticity, in contrast to observed stiffening effects of myosin motors in actin networks. Fractal cluster gels are formed by the well-known mechanism of aggregating polystyrene colloids through addition of divalent electrolyte. Active Janus particles with a platinum hemisphere are created from the same polystyrene colloids and homogeneously embedded in the gels at dilute concentration at the time of aggregation. Upon addition of hydrogen peroxide – a fuel that drives the diffusiophoretic motion of the embedded Janus particles – the microdynamics and mechanical rheology change in proportion to the concentration of hydrogen peroxide and the number of active colloids. We propose a theoretical explanation of this effect in which the decrease in modulus is mediated by active motion-induced softening of the inter-particle attraction. Furthermore, we characterize the failure of the fluctuation–dissipation theorem in the active gels by identifying a discrepancy between the frequency-dependent macroscopic viscoelastic moduli and the values predicted by microrheology from measurement of the gel microdynamics. These findings support efforts to engineer gels for autonomous function by tuning the microscopic dynamics of embedded active particles. Such reconfigurable gels, with multi-state mechanical properties, could find application in materials such as paints and coatings, pharmaceuticals, self-healing materials, and soft robotics.more » « less
-
Abstract. Extractive electrospray ionization (EESI) has been a well-knowntechnique for high-throughput online molecular characterization of chemicalreaction products and intermediates, detection of native biomolecules, invivo metabolomics, and environmental monitoring with negligible thermal andionization-induced fragmentation for over two decades. However, the EESIextraction mechanism remains uncertain. Prior studies disagree on whetherparticles between 20 and 400 nm diameter are fully extracted or if theextraction is limited to the surface layer. Here, we examined the analyteextraction mechanism by assessing the influence of particle size and coatingthickness on the detection of the molecules therein. We find that particlesare extracted fully: organics-coated NH4NO3 particles with afixed core volume (156 and 226 nm in diameter without coating) showedconstant EESI signals for NH4NO3 independent of the shell coatingthickness, while the signals of the secondary organic molecules comprisingthe shell varied proportionally to the shell volume. We also found that theEESI sensitivity exhibited a strong size dependence, with an increase insensitivity by 1–3 orders of magnitude as particle size decreasedfrom 300 to 30 nm. This dependence varied with the electrospray (ES)droplet size, the particle size and the residence time for coagulation in theEESI inlet, suggesting that the EESI sensitivity was influenced by thecoagulation coefficient between particles and ES droplets. Overall, ourresults indicate that, in the EESI, particles are fully extracted by the ESdroplets regardless of the chemical composition, when they are collected bythe ES droplets. However, their coalescence is not complete and dependsstrongly on their size. This size dependence is especially relevant whenEESI is used to probe size-varying particles as is the case in aerosolformation and growth studies with size ranges below 100 nm.more » « less
An official website of the United States government

