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Abstract Extensive research concerns dropwise condensation of low surface tension fluids to promote energy efficiency and decarbonization in thermal energy systems. However, it is challenging as these fluids typically result in filmwise condensation. Drawing inspiration from the Namib desert beetle that enhances condensation through patterned wettability, conventional beetle‐inspired surfaces excel in water condensation but flood when condensing low surface tension fluids. In this work, a patterned quasi‐liquid surface is reported that achieves exceptional dropwise condensation of low surface tension fluids. The surface consists of alternating stripes with low surface energy, that is, a perfluoropolyether (PFPE) and fluorinated quasi‐liquid surface (FQLS), that shows ultralow contact angle hysteresis for ethanol and hexane. The PFPE stripes are slightly more slippery, acting as slippery bridges that accelerate droplet coalescence and removal. It is experimentally demonstrated that the striped PFPE‐FQLS pattern exhibits a heat transfer coefficient 85%, 330%, and 550% higher than that of PFPE, fluorinated silane, and filmwise condensation, respectively. This study reveals that a high contact angle is desired to sustain dropwise condensation, irrespective of contact angle hysteresis. These findings provide a new paradigm for promoting the dropwise condensation of low surface tension fluids and offer valuable insights into surface design for energy sustainability.
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Pushing the Limit of Beetle‐Inspired Condensation on Biphilic Quasi‐Liquid Surfaces
Abstract Massive studies concern the development of low‐carbon water and energy systems. Specifically, surfaces with special wettability to promote vapor‐to‐liquid condensation have been widely studied, but current solutions suffer from poor heat transfer performances due to inefficient droplet removal. In this study, the limit of condensation on a beetle‐inspired biphilic quasi‐liquid surface (QLS) in a steam environment is pushed, which provides a heat flux 100 times higher than that in atmospheric condensation. Unlike the beetle‐inspired surfaces that have sticky hydrophilic domains, the biphilic QLS consists of PEGylated and siloxane polymers as hydrophilic and hydrophobic quasi‐liquid patterns with the contact angle hysteresis of 3° and 1°, respectively. More importantly, each hydrophilic slippery pattern behaves like a slippery bridge that accelerates droplet coalescence and removal. As a result, the condensed droplets grow rapidly and shed off. It is demonstrated that the biphilic‐striped QLS shows a 60% higher water harvesting rate in atmospheric condensation and a 170% higher heat transfer coefficient in steam condensation than the conventional beetle‐inspired surface. This study provides a new paradigm to push the limit of condensation heat transfer at a high heat flux, which sheds light on the next‐generation surface design for water and energy sustainability.
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- Award ID(s):
- 2044348
- PAR ID:
- 10389767
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Functional Materials
- Volume:
- 33
- Issue:
- 11
- ISSN:
- 1616-301X
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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