skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Eye Tear Activated Mg‐Air Battery Driven by Natural Eye Blinking for Smart Contact Lenses
Abstract A sliding electrolyte metal‐air microbattery driven by natural eye blinking motion is demonstrated as a source of electrical energy that can be integrated with smart contact lens platforms. The metal‐air battery (footprint 10 mm2) consists of a Mg anode and a Pt cathode, patterned on an insulating substrate and the battery electrolyte is a film of eye‐tear fluid that is periodically dragged on top of the electrodes during the natural eye‐blinking cycle, which activates the battery. When tested with an eye emulator, the open‐circuit voltage across the eye‐tear activated metal‐air battery (ETMAB) is 2.2 V. Impedance matching analysis reveals a maximum battery‐specific capacity of 3561 mAh g–1obtained at a discharge current density of 5 mA cm–2. The blinking activated battery exhibits the maximum generated power density of 1.3 mW cm–2at the load of 740 Ω. The blinking ETMAB delivers eight times higher energy output and more than three times longer lifetime than achievable with static ETMAB designs.  more » « less
Award ID(s):
1932602
PAR ID:
10390656
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
Advanced Materials Technologies
Volume:
8
Issue:
1
ISSN:
2365-709X
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. We report a thin film wearable aluminum-air battery that utilizes the flow of a biological fluid (eye tear) as a moving electrolyte. When the eye blinks, the eye-tear fluid comes into contact with two metal electrodes, and it produces spontaneous redox reactions, which generate an electric current when connected to a load. In this paper, we demonstrate that a 5×5 mm2 tear-activated Al-air battery is capable of providing maximum energy of 45 μJ per eyeblinking cycle. Furthermore, we investigate the effect of different air-breathing electrodes, including gold, platinum, and silver, on the battery's performance. Results demonstrate that the battery's maximum voltage and current outputs are 1 V and 220 μA while using Pt as the cathode. The moving biofluid Al-air battery with the Pt cathode charges up a 10 μF capacitor in 10 s. Furthermore, load line analysis shows a maximum deliverable load power density of 64 μW·cm-2 for this device. 
    more » « less
  2. Abstract On‐the‐eye microsystems such as smart contacts for vision correction, health monitoring, drug delivery, and displaying information represent a new emerging class of low‐profile (≤ 1 mm) wireless microsystems that conform to the curvature of the eyeball surface. The implementation of suitable low‐profile power sources for eye‐based microsystems on curved substrates is a major technical challenge addressed in this paper. The fabrication and characterization of a hybrid energy generation unit composed of a flexible silicon solar cell and eye‐blinking activated Mg–O2metal–air harvester capable of sustainably supplying electrical power to smart ocular devices are reported. The encapsulated photovoltaic device provides a DC output with a power density of 42.4 µW cm−2and 2.5 mW cm−2under indoor and outdoor lighting conditions, respectively. The eye‐blinking activated Mg–air harvester delivers pulsed power output with a maximum power density of 1.3 mW cm−2. A power management circuit with an integrated 11 mF supercapacitor is used to convert the harvesters’ pulsed voltages to DC, boost up the voltages, and continuously deliver ≈150 µW at a stable 3.3 V DC output. Uniquely, in contrast to wireless power transfer, the power pack continuously generates electric power and does not require any type of external accessories for operation. 
    more » « less
  3. Abstract It remains a challenge to design aqueous electrolytes to secure the complete reversibility of zinc metal anodes. The concentrated water‐in‐salt electrolytes, e.g., 30 m ZnCl2, are promising candidates to address the challenges of the Zn metal anode. However, the pure 30 m ZnCl2electrolyte fails to deliver a smooth surface morphology and a practically relevant Coulombic efficiency. Herein, it is reported that a small concentration of vanillin, 5 mg mLwater−1, added to 30 m ZnCl2transforms the reversibility of Zn metal anode by eliminating dendrites, lowering the Hammett acidity, and forming an effective solid electrolyte interphase. The presence of vanillin in the electrolyte enables the Zn metal anode to exhibit a high Coulombic efficiency of 99.34% at a low current density of 0.2 mA cm−2, at which the impacts of the hydrogen evolution reaction are allowed to play out. Using this new electrolyte, a full cell Zn metal battery with an anode/cathode capacity (N/P) ratio of 2:1 demonstrates no capacity fading over 800 cycles. 
    more » « less
  4. Abstract A major challenge in the pursuit of higher‐energy‐density lithium batteries for carbon‐neutral‐mobility is electrolyte compatibility with a lithium metal electrode. This study demonstrates the robust and stable nature of acloso‐borate based gel polymer electrolyte (GPE), which enables outstanding electrochemical stability and capacity retention upon extensive cycling. The GPE developed herein has an ionic conductivity of 7.3 × 10−4 S cm−2at room temperature and stability over a wide temperature range from −35 to 80 °C with a high lithium transference number ( = 0.51). Multinuclear nuclear magnetic resonance and Fourier transform infrared are used to understand the solvation environment and interaction between the GPE components. Density functional theory calculations are leveraged to gain additional insight into the coordination environment and support spectroscopic interpretations. The GPE is also established to be a suitable electrolyte for extended cycling with four different active electrode materials when paired with a lithium metal electrode. The GPE can also be incorporated into a flexible battery that is capable of being cut and still functional. The incorporation of acloso‐borate into a gel polymer matrix represents a new direction for enhancing the electrochemical and physical properties of this class of materials. 
    more » « less
  5. Abstract Lithium metal (Li0) solid‐state batteries encounter implementation challenges due to dendrite formation, side reactions, and movement of the electrode–electrolyte interface in cycling. Notably, voids and cracks formed during battery fabrication/operation are hot spots for failure. Here, a self‐healing, flowable yet solid electrolyte composed of mobile ceramic crystals embedded in a reconfigurable polymer network is reported. This electrolyte can auto‐repair voids and cracks through a two‐step self‐healing process that occurs at a fast rate of 5.6 µm h−1. A dynamical phase diagram is generated, showing the material can switch between liquid and solid forms in response to external strain rates. The flowability of the electrolyte allows it to accommodate the electrode volume change during Li0stripping. Simultaneously, the electrolyte maintains a solid form with high tensile strength (0.28 MPa), facilitating the regulation of mossy Li0deposition. The chemistries and kinetics are studied by operando synchrotron X‐ray and in situ transmission electron microscopy (TEM). Solid‐state NMR reveals a dual‐phase ion conduction pathway and rapid Li+diffusion through the stable polymer‐ceramic interphase. This designed electrolyte exhibits extended cycling life in Li0–Li0cells, reaching 12 000 h at 0.2 mA cm−2and 5000 h at 0.5 mA cm−2. Furthermore, owing to its high critical current density of 9 mA cm−2, the Li0–LiNi0.8Mn0.1Co0.1O2(NMC811) full cell demonstrates stable cycling at 5 mA cm−2for 1100 cycles, retaining 88% of its capacity, even under near‐zero stack pressure conditions. 
    more » « less