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1. Electrochemical Battery State Estimation Under Parameter Uncertainty Caused by Aging Using Expansion Measurements

   https://doi.org/10.23919/ACC50511.2021.9482886  

   Pannala, Sravan; Valecha, Puneet; Mohtat, Peyman; Siegel, Jason B.; Stefanopoulou, Anna G. (May 2021, 2021 American Control Conference)

   null (Ed.)

   Accurate tracking of the internal electrochemical states of lithium-ion battery during cycling enables advanced battery management systems to operate the battery safely and maintain high performance while minimizing battery degradation. To this end, techniques based on voltage measurement have shown promise for estimating the lithium surface concentration of active material particles, which is an important state for avoiding aging mechanisms such as lithium plating. However, methods relying on voltage often lead to large estimation errors when the model parameters change during aging. In this paper, we utilize the in-situ measurement of the battery expansion to augment the voltage and develop an observer to estimate the lithium surface concentration distribution in each electrode particle. We demonstrate that the addition of the expansion signal enables us to correct the negative electrode concentration states in addition to the positive electrode. As a result, compared to a voltage only observer, the proposed observer can successfully recover the surface concentration when the electrodes' stoichiometric window changes, which is a common occurrence under aging by loss of lithium inventory. With a 5% shift in the electrodes' stoichiometric window, the results indicate a reduction in state estimation error for the negative electrode surface concentration. Under this simulated aged condition, the voltage based observer had 9.3% error as compared to the proposed voltage and expansion observer which had 0.1% error in negative electrode surface concentration. 

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2. Boosting predictive accuracy of single particle models for lithium-ion batteries using machine learning

   https://doi.org/10.1063/5.0230376  

   Olugbade, Emmanuel; Park, Jonghyun (September 2024, Applied Physics Letters)

   The accuracy of single particle (SP) models for lithium-ion batteries at high C-rates is constrained by lithium concentration gradients in the electrolyte, which affect ionic conductivity, overpotential, and reaction rates. This study addresses these limitations using extreme gradient boosting machine learning (ML). By training our ML model with data from a comprehensive electrochemical (P2D) model and performing sensitivity analysis on key battery parameters, we enhance predictive accuracy. Compared to conventional SP and P2D models under constant current loading, our ML-based SP model achieves similar predictive accuracy to P2D, with significant improvements in computational efficiency. Additionally, the ML-based SP model demonstrates improved predictive accuracy under dynamic loading conditions, providing a practical framework for improving battery management and safety. 

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3. An Electrochemical Impedance Spectrum-Based State of Health Differential Indicator with Reduced Sensitivity to Measurement Errors for Lithium–Ion Batteries

   https://doi.org/10.3390/batteries10100368  

   Abu_Qahouq, Jaber (October 2024, Batteries Journal)

   As the use of electrochemical batteries, especially lithium–ion (Li-Ion) batteries, increases due to emerging applications and expanding markets, the accurate and fast estimation of their state of health (SOH) is becoming increasingly important. The accuracy of the SOH estimation is highly dependent on the correlation strength between the used indicator and SOH and the accuracy of the SOH indicator measurement. This paper presents a new differential indicator which has a strong and consistent correlation with the SOH of Li-Ion batteries, based on a new Electrochemical Impedance Spectrum (EIS) Phase–Magnitude relationship. It is shown in this paper that the EIS Phase–Magnitude relationship exhibits a phase-based differential impedance magnitude SOH indicator between a first-phase peak point and a last-phase valley point. Because of the differential nature of this SOH indicator and because the two impedance values are measured at a phase peak point and a valley phase point regardless of the phase absolute values, the effect of impedance measurement shift/offset (error) on SOH estimation is reduced. This supports the future development of more accurate and faster online and offline SOH estimation algorithms and systems that have a higher immunity to impedance measurement shift/offset (error). Furthermore, in this work, the EIS was measured for a lithium–ion battery that was down to a ~15% SOH, which was not only used to support the conclusions of this paper, but also helped in filling a gap in the literature for EIS data under deep/high degradation levels. 

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4. Comparison of parameter conditioning in output error and equation error approaches in speed and parameter estimation in induction machines

   https://doi.org/10.1109/IEMDC.2001.939282  

   Velez-Reyes, M.; Ramos-Torres, J. (June 2001, 2001 IEEE International Electric Machines and Drives Conference (IEMDC))

   Equation error and output error are common formulations used in speed and parameter estimation for induction machines. This paper presents a study of the quality of the estimated speed and parameters using local sensitivity analysis. We studied parameter conditioning as a function of input signals and estimation methodology at nominal speed. Simulation results are used to show that output error formulation is better conditioned than equation error for speed and parameter estimation using PWM and six-step voltage inputs. 

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5. Battery health management using physics-informed machine learning: Online degradation modeling and remaining useful life prediction

   https://doi.org/10.1016/j.ymssp.2022.109347  

   Shi, Junchuan; Rivera, Alexis; Wu, Dazhong. (November 2022, Mechanical systems and signal processing)

   Wang, Dong (Ed.)

   Lithium-ion batteries have been extensively used to power portable electronics, electric vehicles, and unmanned aerial vehicles over the past decade. Aging decreases the capacity of Lithium-ion batteries. Therefore, accurate remaining useful life (RUL) prediction is critical to the reliability, safety, and efficiency of the Lithium-ion battery-powered systems. However, battery aging is a complex electrochemical process affected by internal aging mechanisms and operating conditions (e.g., cycle time, environmental temperature, and loading condition). In this paper, a physics-informed machine learning method is proposed to model the degradation trend and predict the RUL of Lithium-ion batteries while accounting for battery health and operating conditions. The proposed physics-informed long short-term memory (PI-LSTM) model combines a physics-based calendar and cycle aging (CCA) model with an LSTM layer. The CCA model measures the aging effect of Lithium-ion batteries by combining five operating stress factor models. The PI-LSTM uses an LSTM layer to learn the relationship between the degradation trend determined by the CCA model and the online monitoring data of different cycles (i.e., voltage, current, and cell temperature). After the degradation pattern of a battery is estimated by the PI-LSTM model, another LSTM model is then used to predict the future degradation and remaining useful life (RUL) of the battery by learning the degradation trend estimated by the PI-LSTM model. Monitoring data of eleven Lithium-ion batteries under different operating conditions was used to demonstrate the proposed method. Experimental results have shown that the proposed method can accurately model the degradation behavior as well as predict the RUL of Lithium-ion batteries under different operating conditions. 

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