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In lyotropic chromonic liquid crystals (LCLCs), twist distortion of the nematic director costs much less energy than splay or bend distortion. This feature leads to novel mirror-symmetry breaking director configurations when the LCLCs are confined by interfaces or contain suspended particles. Spherical colloids in an aligned LCLC nematic phase, for example, induce chiral director perturbations (“twisted tails”). The asymmetry of rod-like particles in an aligned LCLC offer a richer set of possibilities due to their aspect ratio ( α ) and mean orientation angle (〈 θ 〉) between their long axis and the uniform far-field director. Here we report on the director configuration, equilibrium orientation, and angular diffusion of rod-like particles with planar anchoring suspended in an aligned LCLC. Video microscopy reveals, counterintuitively, that two-thirds of the rods have an angled equilibrium orientation (〈 θ 〉 ≠ 0) that decreases with increasing α , while only one-third of the rods are aligned (〈 θ 〉 = 0). Polarized optical video-microscopy and Landau–de Gennes numerical modeling demonstrate that the angled and aligned rods are accompanied by distinct chiral director configurations. Angled rods have a longitudinal mirror plane (LMP) parallel to their long axis and approximately parallel to the substrate walls. Aligned rods have a transverse and longitudinal mirror plane (TLMP), where the transverse mirror plane is perpendicular to the rod's long axis. Effectively, the small twist elastic constant of LCLCs promotes chiral director configurations that modify the natural tendency of rods to orient along the far-field director. Additional diffusion experiments confirm that rods are angularly confined with strength that depends on α .
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Magnetic field-induced Freedericksz transition in a chiral liquid crystal
A wedge cell made of homeotropically treated glass plates is filled with a chirally doped nematic liquid crystal. When a sufficiently large magnetic field is applied in the cell plane, a bend-like distortion occurs above a Fréedericksz threshold field H th . H th is reduced from the achiral case because of a field-induced bend distortion that facilitates a chiral twist distortion. Measurements of H th vs sample thickness are reported and compared favorably with a theoretical model presented herein. A further theoretical comparison is made between H th and the electric-field-induced transition in a geometry, exhibiting a 2π azimuthal degeneracy. The results may have technological implications in, for example, in-plane switching devices.
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- Award ID(s):
- 1901797
- PAR ID:
- 10404773
- Date Published:
- Journal Name:
- Applied Physics Letters
- Volume:
- 122
- Issue:
- 13
- ISSN:
- 0003-6951
- Page Range / eLocation ID:
- 134101
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1063/5.0146506
