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1. BIOMIMICKING HYDROPHOBICITY USING MICROSCALE STRUCTURES FOR BIOMEDICAL APPLICATIONS

   https://doi.org/10.34107/LWWJ5713177  

   Desai, Roma ; Cordeiro, Jhonatam ; Bastakoti, Bishnu ; Dellinger, Kristen ( July 2022 , Biomedical Sciences Instrumentation)

   Hydrophobic surfaces provide special characteristics for biomedical applications ranging from tunable protein adsorption, cellular interactions, and hemocompatibility to antibacterial coatings. In this research, we biomimic the hair-like micro-whisker structures of magnolia leaf using a synthetic polymeric formulation. Optical and scanning electron microscopy images revealed the presence of micro-whiskers resulting in higher water contact angles. The top layer of the magnolia leaf had a contact angle of 50º as compared to the hydrophobic bottom layer at 98º. A synthetic polymeric formulation was coated on different materials to study its effect on hydrophobicity. The coating was replicated (n=3) on each of the materials used such as glass, polymer, fabric, wood, and stainless steel. A surface tensiometer was used to measure the transition from hydrophilic to hydrophobic interactions between water and the substrate materials. Contact angle measurements revealed an increase in hydrophobicity for all the materials from their original uncoated surface. Glass displayed the highest increase in contact angle from 37º to 90º. Phase analysis of the coated region was performed to characterize the surface exposure of glass substrate to the synthetic polymeric formulation. An increase in the coated region showed a significant increase in contact angle from 50º to 95º. This research lays the foundation to develop and understand hydrophobic coatings for several biomedical applications including non-fouling implant surfaces, lab-on-chip devices, and other diagnostic tools. 

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2. Hydrophobicity versus pore size: polymer coatings to improve membrane wetting resistance for membrane distillation

   https://doi.org/10.1021/acsapm.9b01133  

   McGaughey, Allyson L. ; Karandikar, Prathamesh ; Gupta, Malancha ; Childress, Amy E. ( February 2020 , ACS applied polymer materials)

   null (Ed.)

   Initiated chemical vapor deposition (iCVD) was used to coat two porous substrates (i.e., hydrophilic cellulose acetate (CA) and hydrophobic polytetrafluoroethylene (PTFE)) with a crosslinked fluoropolymer to improve membrane wetting resistance. The coated CA membrane was superhydrophobic and symmetric. The coated PTFE membrane was hydrophobic and asymmetric, with smaller pore size and lower porosity on the top surface than on the bottom surface. Membrane performance was tested in membrane distillation experiments with (1) a high-salinity feed solution and (2) a surfactant-containing feed solution. In both cases, the coated membranes had higher wetting resistance than the uncoated membranes. Notably, wetting resistances were better predicted by LEP distributions than by minimum LEP values. When LEP distributions were skewed towards high LEP values (i.e., when small pores with high LEP were greater in number), significant (measurable) salt passage did not occur. For the high-salinity feed solution, the coated PTFE membrane had greater wetting resistance than the coated CA membrane; thus, reduced surface pore size/porosity (which may reduce intrapore scaling) was more effective than increased surface hydrophobicity (which may reduce surface nucleation) in preventing scaling-induced wetting. Reduced pore size/porosity was equally as effective as increased hydrophobicity in resisting surfactant-induced wetting. However, reduced porosity can negatively impact water flux; this represents a permeability/wetting resistance tradeoff in membrane distillation – especially for high-salinity applications. Membrane and/or membrane coating properties must be optimized to overcome this permeability/wetting resistance tradeoff and make MD viable for the treatment of challenging streams. Then, increasing hydrophobicity may not be necessary to impart high wetting resistance to porous membranes. These results are important for future membrane design, especially as manufacturers seek to replace perfluorinated materials with environmentally friendly alternatives. 

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3. MXene/graphene oxide nanocomposites for friction and wear reduction of rough steel surfaces

   https://doi.org/10.1038/s41598-023-37844-0  

   Macknojia, Ali Zayaan ; Ayyagari, Aditya ; Shevchenko, Elena ; Berman, Diana ( July 2023 , Scientific Reports)

   Development of solid lubricant materials that render reliable performance in ambient conditions, are amenable to industrial size and design complexities, and work on engineered surfaces is reported. These coatings are composed of Ti₃C₂T_x-Graphene Oxide blends, spray-coated onto bearing steel surfaces. The tribological assessment was carried out in ambient environmental conditions and high contact pressures in a ball-on-disc experimental set-up. The evaluation yielded that the use of Ti₃C₂T_x-Graphene-Oxide coatings led to substantial reduction in friction down to 0.065 (at 1 GPa contact pressure and 100 mm/s) in comparison to the uncoated of single-component-coated surfaces, surpassing the state-of-the-art. The coatings also provided excellent protection against wear loss of the substrate and counter-face. The results were explained based on the observations from Raman spectroscopy, scanning electron microscopy, transmission electron microscopy, and nanoindentation measurements.In operandoformation of a dense, hard and stiff, dangling-bond-saturated tribolayer was observed to be the reason for the sustained lubricity even at high test loads and sliding speeds. This report presents the holistic exploration and correlation of structure-property-processing pertaining to the advancement of solid lubrication science.

    

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4. A Novel Approach to Friction Surfacing: Experimental Analysis of Deposition from Radial Surface of a Consumable Tool

   https://doi.org/10.3390/coatings10111016  

   Seidi, Ebrahim ; Miller, Scott F. ( November 2020 , Coatings)

   null (Ed.)

   The friction surfacing technique is an advanced method for creating coatings of various materials onto the surface of a similar or dissimilar material substrate. In this method, there is no external source of heat energy, and all the heat energy required in this method is generated by friction. In this paper, a novel method of friction surfacing from the side of the consumable tool is introduced. The most significant difference in this technique is that material transfer will occur from the radial surface of the consumable tool as opposed to the end of the tool as in conventional friction surfacing. In lateral friction surfacing, the side of the rotating consumable tool is pressed against the substrate surface, which generates frictional heating and shear forces at the interface between tool and substrate. A layer of tool material is transferred from the consumable rod to the substrate surface as the tool moves across. In this study, 6063 aluminum alloy and AISI 1018 carbon steel are used as the materials of consumable tool and substrate, respectively. The impact of process factors, surface roughness values, tool mass loss, and deposition thickness are discussed in detail. The experimental results of this study reveal that lateral friction surfacing produces a very smooth ultra-thin deposition with full coverage, with coating layers with roughness values in the order of 1 µm. Additionally, there is no flash formed in this technique which reduces material consumption. Moreover, temperatures at the interface between the consumable tool and workpiece were measured to be lower than for that in friction surfacing from the end of the tool, which is beneficial for the metallurgical characteristics of the deposited material. 

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5. Tribocatalytically-activated formation of protective friction and wear reducing carbon coatings from alkane environment

   https://doi.org/10.1038/s41598-021-00044-9  

   Shirani, Asghar ; Li, Yuzhe ; Eryilmaz, Osman Levent ; Berman, Diana ( December 2021 , Scientific Reports)

   Abstract Minimizing the wear of the surfaces exposed to mechanical shear stresses is a critical challenge for maximizing the lifespan of rotary mechanical parts. In this study, we have discovered the anti-wear capability of a series of metal nitride-copper nanocomposite coatings tested in a liquid hydrocarbon environment. The results indicate substantial reduction of the wear in comparison to the uncoated steel substrate. Analysis of the wear tracks indicates the formation of carbon-based protective films directly at the sliding interface during the tribological tests. Raman spectroscopy mapping of the wear track suggests the amorphous carbon (a-C) nature of the formed tribofilm. Further analysis of the tribocatalytic activity of the best coating candidate, MoN-Cu, as a function of load (0.25–1 N) and temperature (25 °C and 50 °C) was performed in three alkane solutions, decane, dodecane, and hexadecane. Results indicated that elevated temperature and high contact pressure lead to different tribological characteristics of the coating tested in different environments. The elemental energy dispersive x-ray spectroscopy analysis and Raman analysis revealed formation of the amorphous carbon film that facilitates easy shearing at the contact interface thus enabling more stable friction behavior and lower wear of the tribocatalytic coating. These findings provide new insights into the tribocatalysis mechanism that enables the formation of zero-wear coatings. 

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