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Abstract Quartz crystal microbalance with dissipation (QCM‐D) monitoring is a powerful tool used to sensitively examine the real‐time responses of polymer films to external responses. For example, the technique is commonly used to monitor film growth, material adsorption, thin film swelling, and ion exchange. With its rapidly expanding use, this review is intended to introduce new users to the basic principles of QCM‐D, along with practical challenges and remedies specific to polymer thin films. For both new and experienced users, specific case studies are highlighted including layer‐by‐layer assembly, electrochemical QCM‐D, swelling, sensing, and biological application. Last, the review recommends future directions for research and areas of growth.
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Experiments, Modelling, and Simulations for a Gel Bonded to a Rigid Substrate
In preparation for a more thorough study based on our own experimental work of the debonding of a thin film gel by stress concentration on the interface with a rigid substrate, in this article we revisit, from the viewpoint of the synergy between mathematics, exper- iments, and finite element simulations, the problem of the swelling of a thin rectangular polyacrylamide gel covalently bonded on the bottom surface to a glass slide. With meth- ods of the calculus of variations and perturbation theory we show that the solution to the corresponding zero-displacement boundary value problem converges, in the thin film limit, to a uniquely defined uniform uniaxial extension on the direction normal to the substrate. Both the experiments and the finite element simulations that we perform confirm that the amount of lateral swelling is very small, with a very good quantitative agreement between the two approaches. The proposed model of minimizing an energy functional comprising both a term for the elastic distortion and the Flory-Huggins expression for the entropy of mixing is thus experimentally and numerically validated, with parameters coming from ex- perimental measurements, including the initial polymer volume fraction of the hydrogel synthesized in the laboratory (which is taken as the reference configuration instead of the dry polymer).
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- PAR ID:
- 10410956
- Date Published:
- Journal Name:
- Journal of Elasticity
- ISSN:
- 0374-3535
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1007/s10659-022-09911-6
