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Title: Synthesis, crystal and electronic structure of BaLixCd13–x (x ≈ 2)
A new ternary phase has been synthesized and structurally characterized. BaLi x Cd 13– x ( x ≈ 2) adopts the cubic NaZn 13 structure type (space group Fm 3 ¯ c , Pearson symbol cF 112) with unit cell parameter a = 13.5548 (10) Å. Structure refinements from single-crystal X-ray diffraction data demonstrate that the Li atoms are exclusively found at the centers of the Cd 12 -icosahedra. Since a cubic BaCd 13 phase does not exist, and the tetragonal BaCd 11 is the most Cd-rich phase in the Ba–Cd system, BaLi x Cd 13– x ( x ≈ 2) has to be considered as a true ternary compound. As opposed to the typical electron count of ca. 27 e -per formula unit for many known compounds with the NaZn 13 structure type, BaLi x Cd 13– x ( x ≈ 2) only has ca. 26 e -, suggesting that both electronic and geometric factors are at play. Finally, the bonding characteristics of the cubic BaLi x Cd 13– x ( x ≈ 2) and tetragonal BaCd 11 are investigated using the TB-LMTO-ASA method, showing metallic-like behavior.  more » « less
Award ID(s):
2004579
PAR ID:
10411120
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Frontiers in Chemistry
Volume:
10
ISSN:
2296-2646
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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