Titanium carbide/reduced graphene oxide (Ti 3 C 2 T z /rGO) gels were prepared by a one-step hydrothermal process. The gels show a highly porous structure with a surface area of ∼224 m 2 g −1 and average pore diameter of ∼3.6 nm. The content of GO and Ti 3 C 2 T z nanosheets in the reaction precursor was varied to yield different microstructures. The supercapacitor performance of Ti 3 C 2 T z /rGO gels varied significantly with composition. Specific capacitance initially increased with increasing Ti 3 C 2 T z content, but at high Ti 3 C 2 T z content gels cannot be formed. Also, the retention of capacitance decreased with increasing Ti 3 C 2 T z content. Ti 3 C 2 T z /rGO gel electrodes exhibit enhanced supercapacitor properties with high potential window (1.5 V) and large specific capacitance (920 F g −1 ) in comparison to pure rGO and Ti 3 C 2 T z . The synergistic effect of EDLC from rGO and redox capacitance from Ti 3 C 2 T z was the reason for the enhanced supercapacitor performance. A symmetric two-electrode supercapacitor cell was constructed with Ti 3 C 2 T z /rGO, which showed very high areal capacitance (158 mF cm −2 ), large energy density (∼31.5 μW h cm −2 corresponding to a power density of ∼370 μW cm −2 ), and long stability (∼93% retention) after 10 000 cycles.
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Finite Capacitive Response at the Quantum Hall Plateau
We study ultra-high-mobility two-dimensional (2D) electron/hole systems with high precision capacitance measurement. It is found that the capacitance charge appears only at the fringe of the gate at high magnetic field when the 2D conductivity decreases significantly. At integer quantum Hall effects, the capacitance vanishes and forms a plateau at high temperatures T ≳ 300 mK, which surprisingly disappears at T ≲ 100 mK. This anomalous behavior is likely a manifestation that dilute particles/vacancies in the top-most Landau level form Wigner crystals, which have finite compressibility and can host polarization current.
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- Award ID(s):
- 2011750
- PAR ID:
- 10413574
- Date Published:
- Journal Name:
- Chinese Physics Letters
- Volume:
- 39
- Issue:
- 9
- ISSN:
- 0256-307X
- Page Range / eLocation ID:
- 097301
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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