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Abstract Serial section transmission electron microscopy (TEM) has proven to be one of the leading methods for millimeter-scale 3D imaging of brain tissues at nanoscale resolution. It is important to further improve imaging efficiency to acquire larger and more brain volumes. We report here a threefold increase in the speed of TEM by using a beam deflecting mechanism to enable highly efficient acquisition of multiple image tiles (nine) for each motion of the mechanical stage. For millimeter-scale areas, the duty cycle of imaging doubles to more than 30%, yielding a net average imaging rate of 0.3 gigapixels per second. If fully utilized, an array of four beam deflection TEMs should be capable of imaging a dataset of cubic millimeter scale in five weeks. 

Abstract Heterogeneously integrated hybrid photonic crystal cavities enable strong light–matter interactions with solid state, optically addressable quantum memories. A key challenge to realizing high quality factor (Q) hybrid photonic crystals is the reduced index contrast on the substrate compared to suspended devices in air. This challenge is particularly acute for color centers in diamond because of diamond’s high refractive index, which leads to increased scattering loss into the substrate. Here, we develop a design methodology for hybrid photonic crystals utilizing a detailed understanding of substrate-mediated loss, which incorporates sensitivity to fabrication errors as a critical parameter. Using this methodology, we design robust, high-Q, GaAs-on-diamond photonic crystal cavities, and by optimizing our fabrication procedure, we experimentally realize cavities withQapproaching 30,000 at a resonance wavelength of 955 nm. 

Abstract Over the past three decades, studies have indicated a mobile surface layer with steep gradients on glass surfaces. Among various glasses, polymers are unique because intramolecular interactions — combined with chain connectivity — can alter surface dynamics, but their fundamental role has remained elusive. By devising polymer surfaces occupied by chain loops of various penetration depths, combined with surface dissipation experiments and Monte Carlo simulations, we demonstrate that the intramolecular dynamic coupling along surface chains causes the sluggish bulk polymers to suppress the fast surface dynamics. Such effect leads to that accelerated segmental relaxation on polymer glass surfaces markedly slows when the surface polymers extend chain loops deeper into the film interior. The surface mobility suppression due to the intramolecular coupling reduces the magnitude of the reduction in glass transition temperature commonly observed in thin films, enabling new opportunities for tailoring polymer properties at interfaces and under confinement and producing glasses with enhanced thermal stability. 

Abstract The one-dimensional quantum breakdown model, which features spatially asymmetric fermionic interactions simulating the electrical breakdown phenomenon, exhibits an exponential U(1) symmetry and a variety of dynamical phases including many-body localization and quantum chaos with quantum scar states. We investigate the minimal quantum breakdown model with the minimal number of on-site fermion orbitals required for the interaction and identify a large number of local conserved charges in the model. We then reveal a mapping between the minimal quantum breakdown model in certain charge sectors and a quantum link model which simulates theU(1) lattice gauge theory and show that the local conserved charges map to the gauge symmetry generators. A special charge sector of the model further maps to the PXP model, which shows quantum many-body scars. This mapping unveils the rich dynamics in different Krylov subspaces characterized by different gauge configurations in the quantum breakdown model. 

Abstract Thermoplastic elastomers (TPEs) are nanostructured, melt‐processable, elastomeric block copolymers. When TPEs that form cylindrical or lamellar nanostructures are macroscopically oriented, their material properties can exhibit several orders of magnitude of anisotropy. Here it is demonstrated that the flows applied during the 3D printing of a cylinder‐forming TPE enable hierarchical control over material nanostructure and function. It is demonstrated that 3D printing allows for control over the extent of nanostructural and mechanical anisotropy and that thermal annealing of 3D printed structures leads to highly anisotropic properties (up to 85 × anisotropic tensile modulus). This approach is leveraged to print functional soft 3D architectures with tunable local and macroscopic mechanical responses. Further, these printed TPEs intrinsically achieve melt‐reprocessability over multiple cycles, reprogrammability, and robust self‐healing via a brief period of thermal annealing, enabling facile fabrication of highly tunable, robust, and recyclable soft architectures. 

Abstract Quantum materials are often characterized by a marked sensitivity to minute changes in their physical environment, a property that can lead to new functionalities and thereby, to novel applications. One such key property is the magneto-elastoresistance (MER), the change in magnetoresistance (MR) of a metal induced by uniaxial strain. Understanding and modeling this response can prove challenging, particularly in systems with complex Fermi surfaces. Here, we present a thorough analysis of the MER in the nearly compensated Dirac nodal-line semi-metal ZrSiSe. Small amounts of strain (0.27%) lead to large changes (7%) in the MR. Subsequent analysis reveals that the MER response is driven primarily by a change in transport mobility that varies linearly with the applied strain. This study showcases how the effect of strain tuning on the electrical properties can be both qualitatively and quantitatively understood. A complementary Shubnikov-de Haas oscillation study sheds light on the root of this change in quantum mobility. Moreover, we unambiguously show that the Fermi surface consists of distinct electron and hole pockets revealed in quantum oscillation measurements originating from magnetic breakdown. 

Abstract The topological phases of non-interacting fermions have been classified by their symmetries, culminating in a modern electronic band theory where wavefunction topology can be obtained from momentum space. Recently, Real Space Invariants (RSIs) have provided a spatially local description of the global momentum space indices. The present work generalizes this real space classification to interacting 2D states. We construct many-body local RSIs as the quantum numbers of a set of symmetry operators on open boundaries, but which are independent of the choice of boundary. Using theU(1) particle number, they yield many-body fragile topological indices, which we use to identify which single-particle fragile states are many-body topological or trivial at weak coupling. To this end, we construct an exactly solvable Hamiltonian with single-particle fragile topology that is adiabatically connected to a trivial state through strong coupling. We then define global many-body RSIs on periodic boundary conditions. They reduce to Chern numbers in the band theory limit, but also identify strongly correlated stable topological phases with no single-particle counterpart. Finally, we show that the many-body local RSIs appear as quantized coefficients of Wen-Zee terms in the topological quantum field theory describing the phase. 

Abstract The long-time behavior of highly elastic fibers in a shear flow is investigated experimentally and numerically. Characteristic attractors of the dynamics are found. It is shown that for a small ratio of bending to hydrodynamic forces, most fibers form a spinning elongated double helix, performing an effective Jeffery orbit very close to the vorticity direction. Recognition of these oriented shapes, and how they form in time, may prove useful in the future for understanding the time history of complex microstructures in fluid flows and considering processing steps for their synthesis. 

Abstract While ∼30% of materials are reported to be topological, topological insulators are rare. Magnetic topological insulators (MTI) are even harder to find. Identifying crystallographic features that can host the coexistence of a topological insulating phase with magnetic order is vital for finding intrinsic MTI materials. Thus far, most materials that are investigated for the determination of an MTI are some combination of known topological insulators with a magnetic ion such as MnBi₂Te₄. Motivated by the recent success of EuIn₂As₂, the role of chemical pressure on topologically trivial insulator is investigated, Eu₅In₂Sb₆via Ga substitution. Eu₅Ga₂Sb₆is predicted to be topological but is synthetically difficult to stabilize. The intermediate compositions between Eu₅In₂Sb₆and Eu₅Ga₂Sb₆are observed through theoretical works to explore a topological phase transition and band inversion mechanism. The band inversion mechanism is attributed to changes in Eu–Sb hybridization as Ga is substituted for In due to chemical pressure. Eu₅In_4/3Ga_2/3Sb₆is also synthesized, the highest Ga concentration in Eu₅In_2‐xGa_xSb₆, and report the thermodynamic, magnetic, transport, and Hall properties. Overall, the work paints a picture of a possible MTI via band engineering and explains why Eu‐based Zintl compounds are suitable for the co‐existence of magnetism and topology. 

Abstract 2D hybrid organic–inorganic perovskites are potentially promising materials as passivation layers that can enhance the efficiency and stability of perovskite photovoltaics. The ability to suppress ion transport is proposed as a stabilization mechanism, yet an effective characterization of relevant modes of halide diffusion in 2D perovskites is nascent. In light of this knowledge gap, molecular dynamics simulations with enhanced sampling and experimental validation to systematically characterize how ligand chemistry in seven (R‐NH₃)₂PbI₄systems impacts halide diffusion, particularly in the out‐of‐plane direction is combined. It is found that increasing stiffness and length of ligands generally inhibits ion transport, while increasing ligand polarization generally enhances it. Structural and energetic analyses of the migration pathways provide quantitative explanations for these trends, which reflect aspects of the disorder of the organic layer. Overall, this mechanistic analysis greatly enhances the current understanding of halide migration in 2D hybrid organic–inorganic perovskites and yields insights that can inform the design of future passivation materials.