Although alkyl azides are known to typically form imines under direct irradiation, the product formation mechanism remains ambiguous as some alkyl azides also yield the corresponding triplet alkylnitrenes at cryogenic temperatures. The photoreactivity of 3‐azido‐3‐phenyl‐3
Triplet arylnitrenes may provide direct access to aryl azo‐dimers, which have broad commercial applicability. Herein, the photolysis of
- NSF-PAR ID:
- 10420751
- Publisher / Repository:
- Wiley-Blackwell
- Date Published:
- Journal Name:
- Photochemistry and Photobiology
- Volume:
- 99
- Issue:
- 2
- ISSN:
- 0031-8655
- Page Range / eLocation ID:
- p. 605-615
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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