skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Synthesis and Characterization of Novel Thienothiadiazole-Based D−π–A−π–D Fluorophores as Potential NIR Imaging Agents
Award ID(s):
1757220
PAR ID:
10426686
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  ;  ;  ;  
Publisher / Repository:
American Chemical Society
Date Published:
Journal Name:
ACS Omega
Volume:
8
Issue:
27
ISSN:
2470-1343
Page Range / eLocation ID:
p. 24513-24523
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. A bstract An amplitude analysis of the D + → π − π + π + decay is performed with a sample corresponding to 1.5 fb − 1 of integrated luminosity of pp collisions at a centre-of-mass energy $$ \sqrt{s} $$ s = 8 TeV collected by the LHCb detector in 2012. The sample contains approximately six hundred thousand candidates with a signal purity of 95%. The resonant structure is studied through a fit to the Dalitz plot where the π − π + S-wave amplitude is extracted as a function of π − π + mass, and spin-1 and spin-2 resonances are included coherently through an isobar model. The S-wave component is found to be dominant, followed by the ρ (770) 0 π + and f 2 (1270) π + components. A small contribution from the ω (782) → π − π + decay is seen for the first time in the D + → π − π + π + decay. 
    more » « less
  2. Abstract The multihadron decays $$ {\Lambda}_b^0 $$ Λ b 0 → D + pπ−π− and $$ {\Lambda}_b^0 $$ Λ b 0 → D * + pπ−π− are observed in data corresponding to an integrated luminosity of 3 fb − 1 , collected in proton-proton collisions at centre-of-mass energies of 7 and 8 TeV by the LHCb detector. Using the decay $$ {\Lambda}_b^0 $$ Λ b 0 → $$ {\Lambda}_c^{+} $$ Λ c + π + π − π − as a normalisation channel, the ratio of branching fractions is measured to be $$ \frac{\mathcal{B}\left({\Lambda}_b^0\to {D}^{+}p{\pi}^{-}{\pi}^{-}\right)}{\mathcal{B}\left({\Lambda}_b^0\to {\Lambda}_c^0{\pi}^{+}{\pi}^{-}{\pi}^{-}\right)}\times \frac{\mathcal{B}\left({D}^{+}\to {K}^{-}{\pi}^{+}{\pi}^{+}\right)}{\mathcal{B}\left({\Lambda}_c^0\to {pK}^{-}{\pi}^{-}\right)}=\left(5.35\pm 0.21\pm 0.16\right)\%, $$ B Λ b 0 → D + p π − π − B Λ b 0 → Λ c 0 π + π − π − × B D + → K − π + π + B Λ c 0 → pK − π − = 5.35 ± 0.21 ± 0.16 % , where the first uncertainty is statistical and the second systematic. The ratio of branching fractions for the $$ {\Lambda}_b^0 $$ Λ b 0 → D *+ pπ − π − and $$ {\Lambda}_b^0 $$ Λ b 0 → D + pπ − π − decays is found to be $$ \frac{\mathcal{B}\left({\Lambda}_b^0\to {D}^{\ast +}p{\pi}^{-}{\pi}^{-}\right)}{\mathcal{B}\left({\Lambda}_b^0\to {D}^{+}p{\pi}^{-}{\pi}^{-}\right)}\times \left(\mathcal{B}\left({D}^{\ast +}\to {D}^{+}{\pi}^0\right)+\mathcal{B}\left({D}^{\ast +}\to {D}^{+}\gamma \right)\right)=\left(61.3\pm 4.3\pm 4.0\right)\%. $$ B Λ b 0 → D ∗ + p π − π − B Λ b 0 → D + p π − π − × B D ∗ + → D + π 0 + B D ∗ + → D + γ = 61.3 ± 4.3 ± 4.0 % . 
    more » « less
  3. A bstract Measurements of CP observables in B ± → D (*) K ± and B ± → D (*) π ± decays are presented, where D (∗) indicates a neutral D or D ∗ meson that is an admixture of meson and anti-meson states. Decays of the D (∗) meson to the Dπ 0 and Dγ final states are partially reconstructed without inclusion of the neutral pion or photon. Decays of the D meson are reconstructed in the K ± π ∓ , K + K − , and π + π − final states. The analysis uses a sample of charged B mesons produced in proton-proton collisions and collected with the LHCb experiment, corresponding to integrated luminosities of 2.0, 1.0, and 5.7 fb − 1 taken at centre-of-mass energies of 7, 8, and 13 TeV, respectively. The measurements of partially reconstructed B ± → D (*) K ± and B ± → D (∗) π ± with D → K ∓ π ± decays are the first of their kind, and a first observation of the B ± → $$ {\left(D{\pi}^0\right)}_{D^{\ast }}{\pi}^{\pm } $$ D π 0 D ∗ π ± decay is made with a significance of 6.1 standard deviations. All CP observables are measured with world-best precision, and in combination with other LHCb results will provide strong constraints on the CKM angle γ . 
    more » « less
  4. The development of new two-dimensional (2D) d-π conjugated metal-organic frameworks (MOFs) holds great promise for the construction of a new generation of porous and semiconductive materials. This paper describes the synthesis, structural characterization, and electronic properties of a new d-π conjugated 2D MOF based on the use of a new ligand 2,3,8,9,14,15-hexahydroxytrinaphthylene. The reticular self-assembly of this large π-conjugated organic building block with Cu(II) ions in a mixed solvent system of 1,3-dimethyl-2-imidazolidinone (DMI) and H2O with the addition of ammonia water or ethylenediamine leads to a highly crystalline MOF Cu3(HHTN)2, which possesses pore aperture of 2.5 nm. Cu3(HHTN)2 MOF shows moderate electrical conductivity of 9.01 × 10−8 S·cm−1 at 385 K and temperature-dependent band gap ranging from 0.75 to 1.65 eV. After chemical oxidation by I2, the conductivity of Cu3(HHTN)2 can be increased by 360 times. This access to HHTN based MOF adds an important member to previously reported MOF systems with hexagonal lattice, paving the way towards systematic studies of structure-property relationships of semiconductive MOFs. 
    more » « less