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1. Characterizing the fundamental bending vibration of a linear polyatomic molecule for symmetry violation searches

   https://doi.org/10.1088/1367-2630/ace471  

   Jadbabaie, Arian; Takahashi, Yuiki; Pilgram, Nickolas H; Conn, Chandler J; Zeng, Yi; Zhang, Chi; Hutzler, Nicholas R (July 2023, New Journal of Physics)

   Abstract Polyatomic molecules have been identified as sensitive probes of charge-parity violating and parity violating physics beyond the Standard Model (BSM). For example, many linear triatomic molecules are both laser-coolable and have parity doublets in the ground electronic $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state arising from the bending vibration, both features that can greatly aid BSM searches. Understanding the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state is a crucial prerequisite to precision measurements with linear polyatomic molecules. Here, we characterize the fundamental bending vibration of ${}^{174}$YbOH using high-resolution optical spectroscopy on the nominally forbidden $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$ $\to \tilde{A}{}^2{\mathrm{\Pi }}_{1/2}\left(000\right)$transition at 588 nm. We assign 39 transitions originating from the lowest rotational levels of the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state, and accurately model the state’s structure with an effective Hamiltonian using best-fit parameters. Additionally, we perform Stark and Zeeman spectroscopy on the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state and fit the molecule-frame dipole moment to $D_{\mathrm{m}\mathrm{o}\mathrm{l}}=2.16\left(1\right)$Dand the effective electrong-factor to $g_S=2.07\left(2\right)$. Further, we use an empirical model to explain observed anomalous line intensities in terms of interference from spin–orbit and vibronic perturbations in the excited $\tilde{A}{}^2{\mathrm{\Pi }}_{1/2}\left(000\right)$state. Our work is an essential step toward searches for BSM physics in YbOH and other linear polyatomic molecules. 

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2. (Nearly) Model-independent Constraints on the Neutral Hydrogen Fraction in the Intergalactic Medium at z ∼ 5–7 Using Dark Pixel Fractions in Lyα and Lyβ Forests

   https://doi.org/10.3847/1538-4357/aca678  

   Jin, Xiangyu; Yang, Jinyi; Fan, Xiaohui; Wang, Feige; Bañados, Eduardo; Bian, Fuyan; Davies, Frederick B.; Eilers, Anna-Christina; Farina, Emanuele Paolo; Hennawi, Joseph F.; et al (January 2023, The Astrophysical Journal)

   Abstract Cosmic reionization was the last major phase transition of hydrogen from neutral to highly ionized in the intergalactic medium (IGM). Current observations show that the IGM is significantly neutral atz> 7 and largely ionized byz∼ 5.5. However, most methods to measure the IGM neutral fraction are highly model dependent and are limited to when the volume-averaged neutral fraction of the IGM is either relatively low ( ${\overline{x}}_{\mathrm{H}\mathrm{I}}\lesssim {10}^{-3}$) or close to unity ( ${\overline{x}}_{\mathrm{H}\mathrm{I}}\sim 1$). In particular, the neutral fraction evolution of the IGM at the critical redshift range ofz= 6–7 is poorly constrained. We present new constraints on ${\overline{x}}_{\mathrm{H}\mathrm{I}}$atz∼ 5.1–6.8 by analyzing deep optical spectra of 53 quasars at 5.73 <z< 7.09. We derive model-independent upper limits on the neutral hydrogen fraction based on the fraction of “dark” pixels identified in the Lyαand Lyβforests, without any assumptions on the IGM model or the intrinsic shape of the quasar continuum. They are the first model-independent constraints on the IGM neutral hydrogen fraction atz∼ 6.2–6.8 using quasar absorption measurements. Our results give upper limits of ${\overline{x}}_{\mathrm{H}\mathrm{I}}(z=6.3)<0.79\pm 0.04$(1σ), ${\overline{x}}_{\mathrm{H}\mathrm{I}}(z=6.5)<0.87\pm 0.03$(1σ), and ${\overline{x}}_{\mathrm{H}\mathrm{I}}(z=6.7)<{0.94}_{-0.09}^{+0.06}$(1σ). The dark pixel fractions atz> 6.1 are consistent with the redshift evolution of the neutral fraction of the IGM derived from Planck 2018. 

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3. The metastable Q ³ Δ ₂ state of ThO: a new resource for the ACME electron EDM search

   https://doi.org/10.1088/1367-2630/ab6a3a  

   Wu, X.; Han, Z.; Chow, J.; Ang, D. G.; Meisenhelder, C.; Panda, C. D.; West, E. P.; Gabrielse, G.; Doyle, J. M.; DeMille, D. (February 2020, New Journal of Physics)

   Abstract The best upper limit for the electron electric dipole moment was recently set by the ACME collaboration. This experiment measures an electron spin-precession in a cold beam of ThO molecules in their metastable $H{(}^3{\mathrm{\Delta }}_1)$state. Improvement in the statistical and systematic uncertainties is possible with more efficient use of molecules from the source and better magnetometry in the experiment, respectively. Here, we report measurements of several relevant properties of the long-lived $Q{(}^3{\mathrm{\Delta }}_2)$state of ThO, and show that this state is a very useful resource for both these purposes. TheQstate lifetime is long enough that its decay during the time of flight in the ACME beam experiment is negligible. The large electric dipole moment measured for theQstate, giving rise to a large linear Stark shift, is ideal for an electrostatic lens that increases the fraction of molecules detected downstream. The measured magnetic moment of theQstate is also large enough to be used as a sensitive co-magnetometer in ACME. Finally, we show that theQstate has a large transition dipole moment to the $C{(}^1{\mathrm{\Pi }}_1)$state, which allows for efficient population transfer between the ground state $X{(}^1{\mathrm{\Sigma }}^{+})$and theQstate via $X-C-Q$Stimulated Raman Adiabatic Passage (STIRAP). We demonstrate 90 % STIRAP transfer efficiency. In the course of these measurements, we also determine the magnetic moment ofCstate, the $X\to C$transition dipole moment, and branching ratios of decays from theCstate. 

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4. What Does the Geometry of the Hβ BLR Depend On?

   https://doi.org/10.3847/1538-4357/accc84  

   Villafaña, Lizvette; Williams, Peter R.; Treu, Tommaso; Brewer, Brendon J.; Barth, Aaron J.; U, Vivian; Bennert, Vardha N.; Guo, Hengxiao; Bentz, Misty C.; Canalizo, Gabriela; et al (May 2023, The Astrophysical Journal)

   Abstract We combine our dynamical modeling black-hole mass measurements from the Lick AGN Monitoring Project 2016 sample with measured cross-correlation time lags and line widths to recover individual scale factors,f, used in traditional reverberation-mapping analyses. We extend our sample by including prior results from Code for AGN Reverberation and Modeling of Emission Lines (caramel) studies that have utilized our methods. Aiming to improve the precision of black-hole mass estimates, as well as uncover any regularities in the behavior of the broad-line region (BLR), we search for correlations betweenfand other AGN/BLR parameters. We find (i) evidence for a correlation between the virial coefficient ${\log }_{10}\left(f_{\mathrm{mean},\sigma }\right)$and black-hole mass, (ii) marginal evidence for a similar correlation between ${\log }_{10}\left(f_{\mathrm{rms},\sigma }\right)$and black-hole mass, (iii) marginal evidence for an anticorrelation of BLR disk thickness with ${\log }_{10}\left(f_{\mathrm{mean},\mathrm{FWHM}}\right)$and ${\log }_{10}\left(f_{\mathrm{rms},\mathrm{FWHM}}\right)$, and (iv) marginal evidence for an anticorrelation of inclination angle with ${\log }_{10}\left(f_{\mathrm{mean},\mathrm{FWHM}}\right)$, ${\log }_{10}\left(f_{\mathrm{rms},\sigma }\right)$, and ${\log }_{10}\left(f_{\mathrm{mean},\sigma }\right)$. Last, we find marginal evidence for a correlation between line-profile shape, when using the root-mean-square spectrum, ${\log }_{10}{\left(\mathrm{FWHM}/\sigma \right)}_{\mathrm{rms}}$, and the virial coefficient, ${\log }_{10}\left(f_{\mathrm{rms},\sigma }\right)$, and investigate how BLR properties might be related to line-profile shape usingcaramelmodels. 

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5. Now You See It, Now You Don’t: Star Formation Truncation Precedes the Loss of Molecular Gas by ∼100 Myr in Massive Poststarburst Galaxies at z ∼ 0.6

   https://doi.org/10.3847/1538-4357/ac3dfa  

   Bezanson, Rachel; Spilker, Justin S.; Suess, Katherine A.; Setton, David J.; Feldmann, Robert; Greene, Jenny E.; Kriek, Mariska; Narayanan, Desika; Verrico, Margaret (February 2022, The Astrophysical Journal)

   Abstract We use ALMA observations of CO(2–1) in 13 massive (M_*≳ 10¹¹M_⊙) poststarburst galaxies atz∼ 0.6 to constrain the molecular gas content in galaxies shortly after they quench their major star-forming episode. The poststarburst galaxies in this study are selected from the Sloan Digital Sky Survey spectroscopic samples (Data Release 14) based on their spectral shapes, as part of the Studying QUenching at Intermediate-z Galaxies: Gas, angu $\overrightarrow{L}\mathrm{ar}$momentum, and Evolution ( $\mathit{SQuIGG}\vec{L}E$) program. Early results showed that two poststarburst galaxies host large H₂reservoirs despite their low inferred star formation rates (SFRs). Here we expand this analysis to a larger statistical sample of 13 galaxies. Six of the primary targets (45%) are detected, with $M_{{\mathrm{H}}_2}\gtrsim {10}^9$M_⊙. Given their high stellar masses, this mass limit corresponds to an average gas fraction of $〈f_{{\mathrm{H}}_2}\equiv M_{{\mathrm{H}}_2}/M_{*}〉\sim 7\%$or ∼14% using lower stellar masses estimates derived from analytic, exponentially declining star formation histories. The gas fraction correlates with theD_n4000 spectral index, suggesting that the cold gas reservoirs decrease with time since burst, as found in local K+A galaxies. Star formation histories derived from flexible stellar population synthesis modeling support this empirical finding: galaxies that quenched ≲150 Myr prior to observation host detectable CO(2–1) emission, while older poststarburst galaxies are undetected. The large H₂reservoirs and low SFRs in the sample imply that the quenching of star formation precedes the disappearance of the cold gas reservoirs. However, within the following 100–200 Myr, the $\mathit{SQuIGG}\vec{L}E$galaxies require the additional and efficient heating or removal of cold gas to bring their low SFRs in line with standard H₂scaling relations. 

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