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Abstract High ozone concentrations have become the major summertime air quality problem in China. Extensive in situ observations are deployed for developing strategies to effectively control the emissions of ozone precursors, that is, nitrogen oxides (NOX = NO + NO2) and volatile organic compounds (VOCs). The modeling analysis of in situ observations often makes uses of the dependence of ozone peak concentration on NOXand VOC emissions, because ozone observations are among the most widely available air quality measurements. To extract more information from regulatory ozone observations, we extend the ozone‐precursor relationship to ozone peak time in this study. We find that the sensitivities of ozone peak time and concentration are complementary for regions with large anthropogenic emissions such as China. The ozone peak time is sensitive to both VOC and NOXemissions, and the sensitivity is nearly linear in the transition regime of ozone production compared to the changing ozone peak concentration sensitivity in this regime, making the diagnostics of ozone peak time particularly valuable. The extended ozone‐precursor relationships can be readily applied to understand the effects on ozone by emission changes of NOXand VOC and to assess potential biases of NOXand VOC emission inventories. These observation constraints based on regulatory ozone observations can complement the other measurement and modeling analysis methods nicely. Furthermore, we suggest that the ozone peak time sensitivity we discussed here to be used as a model evaluation measure before the empirical kinetic modeling approach (EKMA) diagram is applied to understand the effectiveness of emission control on ozone concentrations.
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Photochemistry of Volatile Organic Compounds in the Yellow River Delta, China: Formation of O 3 and Peroxyacyl Nitrates
Abstract An extensive set of primary and secondary pollutants was measured at a ground site in a remote location in the Yellow River Delta, China during the Ozone Photochemistry and Export from China Experiment (OPECE) from March to April 2018. The measurements include volatile organic compounds (VOCs), peroxyacyl nitrates (PANs), ozone (O3), particulate species, nitrogen oxides (NOx), and SO2. Observed VOC mixing ratios were comparable to those measured in heavily polluted cities in the U.S. and China. The VOC source signatures suggest a strong influence from Oil and Natural Gas (O&NG) emissions with potentially large contributions from Liquified Petroleum Gas (LPG) sources as well. Consistently elevated concentrations of O3, PAN, and its rarely measured homologs peroxybenzoylic nitric anhydride (PBzN) and peroxyacrylic nitric anhydride (APAN) at the OPECE site indicate complex photochemistry in a heterogeneous VOC environment. Diagnostic 0‐D box model simulations are used to investigate the budgets of ROx(OH + HO2 + RO2), and the rate and efficiency of O3production. Model sensitivity calculations indicate that O3production at OPECE site is VOC limited in spring. This suggests that reduction in VOCs should be a priority for reducing O3, where production and fugitive emissions from O&NG provide an attractive target. While initial reductions in NOxmight increase O3production, reduction of NOxalong with VOCs will be a necessary step to achieve long‐term ozone reduction.
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- Award ID(s):
- 1743401
- PAR ID:
- 10446470
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Journal of Geophysical Research: Atmospheres
- Volume:
- 126
- Issue:
- 23
- ISSN:
- 2169-897X
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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