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1. Mechanical Control of the Optical Bandgap in One-Dimensional Photonic Crystals

   https://doi.org/10.3390/mi13122248  

   Stinson, V. Paige; Shuchi, Nuren; McLamb, Micheal; Boreman, Glenn D.; Hofmann, Tino (December 2022, Micromachines)

   Over the last several years, two-photon polymerization has been a popular fabrication approach for photonic crystals due to its high spatial resolution. One-dimensional photonic crystals with photonic bandgap reflectivities over 90% have been demonstrated for the infrared spectral range. With the success of these structures, methods which can provide tunability of the photonic bandgap are being explored. In this study, we demonstrate the use of mechanical flexures in the design of one-dimensional photonic crystals fabricated by two-photon polymerization for the first time. Experimental results show that these photonic crystals provide active mechanically induced spectral control of the photonic bandgap. An analysis of the mechanical behavior of the photonic crystal is presented and elastic behavior is observed. These results suggest that one-dimensional photonic crystals with mechanical flexures can successfully function as opto-mechanical structures. 

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2. Photonic Crystals Fabricated by Two-Photon Polymerization with Mechanical Defects

   https://doi.org/10.3390/opt4020021  

   Stinson, Victoria Paige; Shuchi, Nuren; Louisos, Dustin; McLamb, Micheal; Boreman, Glenn D.; Hofmann, Tino (June 2023, Optics)

   One-dimensional photonic crystals have been used in sensing applications for decades, due to their ability to induce highly reflective photonic bandgaps. In this study, one-dimensional photonic crystals with alternating low- and high-density layers were fabricated from a single photosensitive polymer (IP-Dip) by two-photon polymerization. The photonic crystals were modified to include a central defect layer with different elastic properties compared to the surrounding layers, for the first time. It was observed that the defect mode resonance can be controlled by compressive force. Very good agreement was found between the experimentally measured spectra and the model data. The mechanical properties of the flexure design used in the defect layer were calculated. The calculated spring constant is of similar magnitude to those reported for microsprings fabricated on this scale using two-photon polymerization. The results of this study demonstrate the successful control of a defect resonance in one-dimensional photonic crystals fabricated by two-photon polymerization by mechanical stimuli, for the first time. Such a structure could have applications in fields, such as micro-robotics, and in micro-opto–electro–mechanical systems (MOEMSs), where optical sensing of mechanical fluctuations is desired. 

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3. Terahertz anisotropic response of additively manufactured one-dimensional photonic crystals

   https://doi.org/10.1364/OL.422929  

   Park, Serang; Stinson, V_Paige; Boreman, Glenn_D; Hofmann, Tino (July 2021, Optics Letters)

   A polymer-based, one-dimensional photonic crystal exhibiting anisotropic responses was demonstrated in the terahertz frequency range. The photonic crystal was composed of alternating compact and low-density polymethacrylate layers. The low-density layers consisted of sub-wavelength sized columns, which were slanted 45° with respect to the substrate surface normal to achieve form-birefringence. Normal incidence polarized terahertz transmission measurements were carried out for characterization of the fabricated photonic crystals in the range from 82 to 125 GHz. The experimental data revealed a 2 GHz shift in the center frequency of the photonic bandgap as a function of in-plane orientation, well demonstrating the anisotropic behavior of the fabricated crystal. The transmission data were analyzed using stratified optical layer model calculations. A good agreement was found between the relevant model parameters and the corresponding design parameters. 

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4. Towards Two-Photon Polymerization-Compatible Diffractive Optics for Micro-Mechanical Applications

   https://doi.org/10.3390/mi14071319  

   Stinson, Victoria Paige; Subash, Uma; Poutous, Menelaos K.; Hofmann, Tino (July 2023, Micromachines)

   Diffractive optics are structured optical surfaces that manipulate light based on the principles of interference and diffraction. By carefully designing the diffractive optical elements, the amplitude, phase, direction, and polarization of the transmitted and reflected light can be controlled. It is well-known that the propagation of light through diffractive optics is sensitive to changes in their structural parameters. In this study, a numerical analysis is conducted to evaluate the capabilities of slanted-wire diffraction gratings to function opto-mechanically in the infrared spectral range. The slanted wire array is designed such that it is compatible with fabrication by two-photon polymerization, a direct laser-writing approach. The modeled optical and mechanical capabilities of the diffraction grating are presented. The numerical results demonstrate a high sensitivity of the diffracted light to changes in the slant angle of the wires. The compressive force by which desired slant angles may be achieved as a function of the number of wires in the grating is investigated. The ability to fabricate the presented design using two-photon polymerization is supported by the development of a prototype. The results of this study suggest that slanted-wire gratings fabricated using two-photon polymerization may be effective in applications such as tunable beam splitting and micro-mechanical sensing. 

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5. Surface-Aligned Cholesteric Liquid Crystalline Elastomers with Tunable Mechanical Properties via Thiol–Ene Chemistry

   https://doi.org/10.1021/acs.macromol.5c00861  

   Phillips, Alexis T; Chen, Judy C; Kennedy, David T; White, Timothy J (June 2025, Macromolecules)

   Cholesteric liquid crystals (CLCs) exhibit Bragg reflection due to their spontaneous self-assembly into a one-dimensional photonic structure. Retaining this cholesteric order in a polymer network requires functionalizing liquid crystals with reactive end groups. However, conventional chemistries for synthesizing cholesteric liquid crystalline polymers often result in poor surface alignment and reduced optical quality. In this work, we investigate a thiol−ene step-growth polymerization approach to fabricate cholesteric liquid crystalline elastomers (CLCEs) with tunable mechanical properties and improved optical quality. By varying the cross-link density, we systematically study the effects on haze, cross-linking degree, and mechanical response. Compared to existing cholesteric liquid crystalline polymers, the thiol−ene-based CLCEs exhibit enhanced surface alignment, reduced haze, and greater mechanical tunability. These materials are further benchmarked against CLCEs synthesized via thiol−acrylate chain transfer polymerization, highlighting the advantages of the thiol−ene reaction for achieving precisely controlled properties in cholesteric polymer networks. 

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