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Abstract. The South Pole Ice Core (SPICEcore) was drilled in 2014–2016 to provide adetailed multi-proxy archive of paleoclimate conditions in East Antarcticaduring the Holocene and late Pleistocene. Interpretation of these recordsrequires an accurate depth–age relationship. Here, we present the SPICEcore (SP19) timescale for the age of the ice of SPICEcore. SP19 is synchronized to theWD2014 chronology from the West Antarctic Ice Sheet Divide (WAIS Divide) icecore using stratigraphic matching of 251 volcanic events. These eventsindicate an age of 54 302±519 BP (years before 1950) at thebottom of SPICEcore. Annual layers identified in sodium and magnesium ionsto 11 341 BP were used to interpolate between stratigraphic volcanic tiepoints, yielding an annually resolved chronology through the Holocene.Estimated timescale uncertainty during the Holocene is less than 18 yearsrelative to WD2014, with the exception of the interval between 1800 to 3100BP when uncertainty estimates reach ±25 years due to widely spacedvolcanic tie points. Prior to the Holocene, uncertainties remain within 124 years relative to WD2014. Results show an average Holocene accumulation rateof 7.4 cm yr−1 (water equivalent). The time variability of accumulation rateis consistent with expectations for steady-state ice flow through the modernspatial pattern of accumulation rate. Time variations in nitrateconcentration, nitrate seasonal amplitude and δ15N of N2 in turn are as expected for the accumulation rate variations. The highlyvariable yet well-constrained Holocene accumulation history at the site canhelp improve scientific understanding of deposition-sensitive climateproxies such as δ15N of N2 and photolyzed chemicalcompounds.
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The new Kr-86 excess ice core proxy for synoptic activity: West Antarctic storminess possibly linked to Intertropical Convergence Zone (ITCZ) movement through the last deglaciation
Abstract. Here we present a newly developed ice core gas-phase proxy that directlysamples a component of the large-scale atmospheric circulation:synoptic-scale pressure variability. Surface pressure changes weakly disrupt gravitational isotopic settling in the firn layer, which is recorded in krypton-86 excess (86Krxs). The 86Krxs may therefore reflect the time-averaged synoptic pressure variability over several years (site “storminess”), but it likely cannot record individual synoptic events as ice core gas samples typically average over several years. We validate 86Krxs using late Holocene ice samples from 11 Antarctic ice cores and 1 Greenland ice core that collectively represent a wide range of surface pressure variability in the modern climate. We find a strong spatial correlation (r=-0.94, p<0.01) between site average 86Krxs and time-averaged synoptic variability from reanalysis data. The main uncertainties in the analysis are the corrections for gas loss and thermal fractionation and the relatively large scatter in the data. Limited scientific understanding of the firn physics and potential biases of 86Krxs require caution in interpreting this proxy at present. We show that Antarctic 86Krxs appears to be linked to the position of the Southern Hemisphere eddy-driven subpolar jet (SPJ), with a southern position enhancing pressure variability. We present a 86Krxs record covering the last 24 kyr from the West Antarctic Ice Sheet (WAIS) Divide ice core. Based on the empirical spatial correlation of synoptic activity and 86Krxs at various Antarctic sites, we interpret this record to show that West Antarctic synoptic activity is slightly below modern levels during the Last Glacial Maximum (LGM), increases during the Heinrich Stadial 1 and Younger Dryas North Atlantic cold periods, weakens abruptly at the Holocene onset, remains low during the early and mid-Holocene, and gradually increases to its modern value. The WAIS Divide 86Krxs record resembles records of monsoon intensity thought to reflect changes in the meridional position of the Intertropical Convergence Zone (ITCZ) on orbital and millennial timescales such that West Antarctic storminess is weaker when the ITCZ is displaced northward and stronger when it is displaced southward. We interpret variations in synoptic activity as reflecting movement of the South Pacific SPJ in parallel to the ITCZ migrations, which is the expected zonal mean response of the eddy-driven jet in models and proxy data. Past changes to Pacific climate and the El Niño–Southern Oscillation (ENSO) may amplify the signal of the SPJ migration. Our interpretation is broadly consistent with opal flux records from the Pacific Antarctic zone thought to reflect wind-driven upwelling. We emphasize that 86Krxs is a new proxy, and more work is called for to confirm, replicate, and better understand these results; until such time, our conclusions regarding past atmospheric dynamics remainspeculative. Current scientific understanding of firn air transport andtrapping is insufficient to explain all the observed variations in86Krxs. A list of suggested future studies is provided.
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- Award ID(s):
- 1643716
- PAR ID:
- 10448791
- Author(s) / Creator(s):
- ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; more »
- Date Published:
- Journal Name:
- Climate of the Past
- Volume:
- 19
- Issue:
- 3
- ISSN:
- 1814-9332
- Page Range / eLocation ID:
- 579 to 606
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract Firn is the pervasive surface material across Antarctica, and its structures reflect its formation and history in response to environmental perturbations. In addition to the role of firn in thermally isolating underlying glacial ice, it defines near-surface elastic and density structure and strongly influences high-frequency (> 5 Hz) seismic phenomena observed near the surface. We investigate high-frequency seismic data collected with an array of seismographs deployed on the West Antarctic Ice Sheet (WAIS) near WAIS Divide camp in January 2019. Cross-correlations of anthropogenic noise originating from the approximately 5 km-distant camp were constructed using a 1 km-diameter circular array of 22 seismographs. We distinguish three Rayleigh (elastic surface) wave modes at frequencies up to 50 Hz that exhibit systematic spatially varying particle motion characteristics. The horizontal-to-vertical ratio for the second mode shows a spatial pattern of peak frequencies that matches particle motion transitions for both the fundamental and second Rayleigh modes. This pattern is further evident in the appearance of narrow band spectral peaks. We find that shallow lateral structural variations are consistent with these observations, and model spectral peaks as Rayleigh wave amplifications within similarly scaled shallow basin-like structures delineated by the strong velocity and density gradients typical of Antarctic firn.more » « less
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.5194/cp-19-579-2023
