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Using a flexible form for ladder operators that incorporates confluent hypergeometric functions, we show how one can determine all of the discrete energy eigenvalues and eigenvectors of the time-independent Schrödinger equation via a single factorization step and the satisfaction of boundary (or normalizability) conditions. This approach determines the bound states of all exactly solvable problems whose wavefunctions can be expressed in terms of confluent hypergeometric functions. It is an alternative that shares aspects of the conventional differential equation approach and Schrödinger’s factorization method, but is different from both. We also explain how this approach relates to Natanzon’s treatment of the same problem and illustrate how to numerically determine nontrivial potentials that can be solved this way.
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The Laplace Method for Energy Eigenvalue Problems in Quantum Mechanics
Quantum mechanics has about a dozen exactly solvable potentials. Normally, the time-independent Schrödinger equation for them is solved by using a generalized series solution for the bound states (using the Fröbenius method) and then an analytic continuation for the continuum states (if present). In this work, we present an alternative way to solve these problems, based on the Laplace method. This technique uses a similar procedure for the bound states and for the continuum states. It was originally used by Schrödinger when he solved the wave functions of hydrogen. Dirac advocated using this method too. We discuss why it is a powerful approach to solve all problems whose wave functions are represented in terms of confluent hypergeometric functions, especially for the continuum solutions, which can be determined by an easy-to-program contour integral.
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- Award ID(s):
- 1915130
- PAR ID:
- 10451269
- Date Published:
- Journal Name:
- Quantum Reports
- Volume:
- 5
- Issue:
- 2
- ISSN:
- 2624-960X
- Page Range / eLocation ID:
- 370 to 397
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.3390/quantum5020024
