An official website of the United States government
Using a flexible form for ladder operators that incorporates confluent hypergeometric functions, we show how one can determine all of the discrete energy eigenvalues and eigenvectors of the time-independent Schrödinger equation via a single factorization step and the satisfaction of boundary (or normalizability) conditions. This approach determines the bound states of all exactly solvable problems whose wavefunctions can be expressed in terms of confluent hypergeometric functions. It is an alternative that shares aspects of the conventional differential equation approach and Schrödinger’s factorization method, but is different from both. We also explain how this approach relates to Natanzon’s treatment of the same problem and illustrate how to numerically determine nontrivial potentials that can be solved this way.
more »
« less
Continuum Energy Eigenstates via the Factorization Method
The factorization method was introduced by Schrödinger in 1940. Its use in bound-state problems is widely known, including in supersymmetric quantum mechanics; one can create a factorization chain, which simultaneously solves a sequence of auxiliary Hamiltonians that share common eigenvalues with their adjacent Hamiltonians in the chain, except for the lowest eigenvalue. In this work, we generalize the factorization method to continuum energy eigenstates. Here, one does not generically have a factorization chain—instead all energies are solved using a “single-shot factorization”, enabled by writing the superpotential in a form that includes the logarithmic derivative of a confluent hypergeometric function. The single-shot factorization approach is an alternative to the conventional method of “deriving a differential equation and looking up its solution”, but it does require some working knowledge of confluent hypergeometric functions. This can also be viewed as a method for solving the Ricatti equation needed to construct the superpotential.
more »
« less
- Award ID(s):
- 1915130
- PAR ID:
- 10451272
- Date Published:
- Journal Name:
- Symmetry
- Volume:
- 15
- Issue:
- 4
- ISSN:
- 2073-8994
- Page Range / eLocation ID:
- 797
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
We generalize Schrödinger’s factorization method for Hydrogen from the conventional separation into angular and radial coordinates to a Cartesian-based factorization. Unique to this approach is the fact that the Hamiltonian is represented as a sum over factorizations in terms of coupled operators that depend on the coordinates and momenta in each Cartesian direction. We determine the eigenstates and energies, the wavefunctions in both coordinate and momentum space, and we also illustrate how this technique can be employed to develop the conventional confluent hypergeometric equation approach. The methodology developed here could potentially be employed for other Hamiltonians that can be represented as the sum over coupled Schrödinger factorizations.more » « less
-
The confluent hypergeometric equation, also known as Kummer's equation, is one of the most important differential equations in physics, chemistry, and engineering. Its two power series solutions are the Kummer function, M(a,b,z), often referred to as the confluent hypergeometric function of the first kind, and M ≡ z1-bM(1+a-b, 2-b,z), where a and b are parameters that appear in the differential equation. A third function, the Tricomi function, U(a,b,z), sometimes referred to as the confluent hypergeometric function of the second kind, is also a solution of the confluent hypergeometric equation that is routinely used. Contrary to common procedure, all three of these functions (and more) must be considered in a search for the two linearly independent solutions of the confluent hypergeometric equation. There are situations, when a, b, and a - b are integers, where one of these functions is not defined, or two of the functions are not linearly independent, or one of the linearly independent solutions of the differential equation is different from these three functions. Many of these special cases correspond precisely to cases needed to solve problems in physics. This leads to significant confusion about how to work with confluent hypergeometric equations, in spite of authoritative references such as the NIST Digital Library of Mathematical Functions. Here, we carefully describe all of the different cases one has to consider and what the explicit formulas are for the two linearly independent solutions of the confluent hypergeometric equation. The procedure to properly solve the confluent hypergeometric equation is summarized in a convenient table. As an example, we use these solutions to study the bound states of the hydrogenic atom, correcting the standard treatment in textbooks. We also briefly consider the cutoff Coulomb potential. We hope that this guide will aid physicists to properly solve problems that involve the confluent hypergeometric differential equation.more » « less
-
Abstract The Morse potential is an important problem to examine due to its applications in describing vibrations and bond breaking in molecules. It also shares some properties with the simpler harmonic oscillator, at the same time displaying differences, allowing for an interesting contrast to its well-studied counterpart. The solution of the Morse potential is not usually taught in a quantum mechanics class, since using differential equations makes it very tedious. Here, we illustrate how to solve the Morse potential using the Schrödinger factorization method. This operator method is a powerful tool to find the energy eigenvalues, eigenstates, and wavefunctions without using differential equations in position space, allowing us to solve more problems without requiring a discussion of hypergeometric or confluent hypergeometric functions.more » « less
-
Quantum mechanics has about a dozen exactly solvable potentials. Normally, the time-independent Schrödinger equation for them is solved by using a generalized series solution for the bound states (using the Fröbenius method) and then an analytic continuation for the continuum states (if present). In this work, we present an alternative way to solve these problems, based on the Laplace method. This technique uses a similar procedure for the bound states and for the continuum states. It was originally used by Schrödinger when he solved the wave functions of hydrogen. Dirac advocated using this method too. We discuss why it is a powerful approach to solve all problems whose wave functions are represented in terms of confluent hypergeometric functions, especially for the continuum solutions, which can be determined by an easy-to-program contour integral.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.3390/sym15040797
