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: Chiral inorganic nanostructures strongly interact with photons changing their polarization state. The resulting circularly polarized light emission (CPLE) has cross-disciplinary importance for a variety of chemical/biological processes and is essential for development of chiral photonics. However, the polarization effects are often complex and could be misinterpreted. CPLE in nanostructured media has multiple origins and several optical effects are typically convoluted into a single output. Analysing CPLE data obtained for nanoclusters, NPs, nanoassemblies, and nanocomposites from metals, chalcogenides, perovskite, and other nanostructures, we show that there are several distinct groups of nanomaterials for which CPLE is dominated either by circularly polarized luminescence (CPL) or circularly polarized scattering (CPS); there are also many nanomaterials for which they are comparable. We also show that (1) CPL and CPS contributions involve light-matter interactions at different structural levels; (2) contribution from CPS is especially strong for nanostructured microparticles, nanoassemblies and composites; and (3) engineering of materials with strongly polarized light emission requires synergistic implementation of CPL and CPS effects. These findings are expected to guide development of CPLE materials in a variety of technological fields, including 3D displays, information storage, biosensors, optical spintronics, and biological probes.
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Optical Chirality Detection Using a Topological Insulator Transistor
Abstract Optical chirality is an effective means in screening molecules and their enantiomers in bioengineering, and recently has garnered attention as an implementation of qubits in quantum information processing. The conventional detection of circularly polarized light (CPL) is based on phase retardation and polarization separation using multiple optical components. An intrinsic solid‐state chirality detection device would be favorable for easier integration and implementation. Optical spin injection to the spin‐momentum‐locked topological surface states of topological insulators (TIs) by circularly polarized light leads to a directional DC photocurrent and hence possible circular polarization detection. However, this DC photocurrent is also accompanied by other photo‐responses. Here, a photodetection strategy using a TI transistor which senses CPL without the use of any additional components is demonstrated, it achieves a uniform response over the entire device with a sensitivity ≈5.6%. The Stokes parameters can also be extracted by arithmetic operation of photocurrents obtained with different bias and gate for a complete characterization of a polarized light beam. Therefore, this method enables chirality detection and Stokes parameter analysis using a single device. The proposed miniaturized intrinsic chirality detectors facilitate polarimetry sensing in applications from circular dichroism spectroscopy to biomedical diagnosis.
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- Award ID(s):
- 1641101
- PAR ID:
- 10452999
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Optical Materials
- Volume:
- 9
- Issue:
- 10
- ISSN:
- 2195-1071
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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