Abstract N‐Type thermoelectrics typically consist of small molecule dopant+polymer host. Only a few polymer dopant+polymer host systems have been reported, and these have lower thermoelectric parameters. N‐type polymers with high crystallinity and order are generally used for high‐conductivity () organic conductors. Few n‐type polymers with only short‐range lamellar stacking for high‐conductivity materials have been reported. Here, we describe an n‐type short‐range lamellar‐stacked all‐polymer thermoelectric system with highestof 78 S−1, power factor (PF) of 163 μW m−1 K−2, and maximum Figure of merit (ZT) of 0.53 at room temperature with a dopant/host ratio of 75 wt%. The minor effect of polymer dopant on the molecular arrangement of conjugated polymer PDPIN at high ratios, high doping capability, high Seebeck coefficient (S) absolute values relative to, and atypical decreased thermal conductivity () with increased doping ratio contribute to the promising performance.
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Observational Evidence for Two Modes of Coupling Between Sea Surface Temperatures, Tropospheric Temperature Profile, and Shortwave Cloud Radiative Effect in the Tropics
Abstract Tropical average shortwave cloud radiative effect (SWCRE) anomalies observed by CERES/EBAF v4 are explained by observed average sea surface temperature () and the difference between the warmest 30% where deep convection occurs and). Observed tropospheric temperatures show variations in boundary layer capping strength over time consistent with the evolution of SST#. The CERES/EBAF v4 data confirm that associated cloud fraction changes over the colder waters dominate SWCRE. This observational evidence for the “pattern effect” noted in General Circulation Model simulations suggests that SST#captures much of this effect. The observed sensitivities (dSWCRE/dW·m−2·K−1, dSWCRE/dSST#≈−4.8W·m−2·K−1) largely reflect El Niño–Southern Oscillation. As El Niño develops,increases and SST#decreases (both increasing SWCRE). Only after the El Niño peak, SST#increases and SWCRE decreases. SST#is also relevant for the tropical temperature trend profile controversy and the discrepancy between observed and modeled equatorial Pacific SST trends. Causality and implications for future climates are discussed.
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- Award ID(s):
- 1743753
- PAR ID:
- 10453805
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Geophysical Research Letters
- Volume:
- 46
- Issue:
- 16
- ISSN:
- 0094-8276
- Page Range / eLocation ID:
- p. 9890-9898
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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