skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Controlling Light, Heat, and Vibrations in Plasmonics and Phononics
Abstract Plasmonic nanostructures have attracted considerable attention for their ability to couple with light and provide strong electromagnetic energy confinement at subwavelength dimensions. The absorbed portion of the captured electromagnetic energy can lead to significant heating of both the nanostructure and its surroundings, resulting in a rich set of nanoscale thermal processes that defines the subfield of thermoplasmonics with applications ranging from nanochemistry and nanobiology to optoelectronics. Recently, phononic nanostructures have started to attract attention as a platform for manipulation of phonons, enabling control over heat propagation and/or mechanical vibrations. The complex interaction phenomena between photons, electrons, and phonons require appropriate modelling strategies to design nanodevices that simultaneously explore and exploit the optical, thermal, and mechanical degrees of freedom. Examples of such devices are micro‐ and nanoscale opto‐thermo‐mechanical systems for sensing, imaging, energy conversion, and harvesting applications. Here, an overview of the fundamental theory and concepts crucial to the modelling of plasmo‐phonon devices is provided. Particular attention is given to micro‐ and nanoscale modelling frameworks, highlighting their validity ranges and the experimental works that contributed to their validation and led to compelling applications. Finally, an open‐ended outlook focused on emerging applications at the intersection between plasmonics and phononics is presented.  more » « less
Award ID(s):
1941227
PAR ID:
10454335
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
Advanced Optical Materials
Volume:
8
Issue:
24
ISSN:
2195-1071
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Silicon carbide (SiC) supports surface phonons in the infrared region of the electromagnetic spectrum where these modes can be thermally emitted. Additionally, the magnitude, spectrum, and direction of thermal radiation from SiC can be controlled by engineering this material at the sub-wavelength scale. For these reasons, SiC nanopillars are of high interest for thermal-radiation tuning. So far, theoretical and experimental studies of thermal emission from SiC nanopillars have been limited to long-pitch arrays with a microscale interpillar spacing. It is not clear how far-field thermal emission from SiC nanopillars is affected when the interparticle spacing reduces to the nanometer scale, where the near-field interaction between adjacent nanopillars arises and the array becomes zero order. In this Letter, we study physical mechanisms of far-field thermal radiation from zero-order arrays of silicon-carbide nanopillars with a nanoscale interpillar spacing. We show that the increased volume of thermal emitters and thermal radiation of the hybrid waveguide-surface-phonon-polariton mode from zero-order arrays increase the spectral emissivity of silicon carbide to values as large as 1 for a wide range of angles. The enhanced, dispersion-less thermal emission from a zero-order SiC array of nano-frustums with an optimized interspacing of 300 nm is experimentally demonstrated. Our study provides insight into thermal radiation from dense nanostructures and has significant implications for thermal management of electronic devices and energy harvesting applications. 
    more » « less
  2. Abstract This work explores the 2D interfacial energy transport between monolayer WSe2and SiO2while considering the thermal nonequilibrium between optical and acoustic phonons caused by photoexcitation. Recent modeling and experimental work have shown substantial temperature differences between optical and acoustic phonons (ΔTOA) in various nanostructures upon laser irradiation. Generally, characterizations of interfacial thermal resistance (R′′tc) at the nanoscale are difficult and depend on Raman‐probed temperature measurements, which only reveal optical phonon temperature information. Here it is shown that ΔTOAfor supported monolayer WSe2can be as high as 48% of the total temperature rise revealed by optothermal Raman methods—a significant proportion that can introduce sizeable error toR′′tcmeasurements if not properly considered. A frequency energy transport state‐resolved Raman technique (FET‐Raman) along with a 3D finite volume modeling of 2D material laser heating is used to extract the true interfacial thermal resistanceR′′tc(determined by acoustic phonon transport). Additionally, a novel ET‐Raman technique is developed to determine the energy coupling factorGbetween optical and acoustic phonons (on the order of 1015W m−3K−1). This work demonstrates the need for special consideration of thermal nonequilibriums during laser–matter interactions at the nanoscale. 
    more » « less
  3. Abstract Spatially resolved vibrational mapping of nanostructures is indispensable to the development and understanding of thermal nanodevices 1 , modulation of thermal transport 2 and novel nanostructured thermoelectric materials 3–5 . Through the engineering of complex structures, such as alloys, nanostructures and superlattice interfaces, one can significantly alter the propagation of phonons and suppress material thermal conductivity while maintaining electrical conductivity 2 . There have been no correlative experiments that spatially track the modulation of phonon properties in and around nanostructures due to spatial resolution limitations of conventional optical phonon detection techniques. Here we demonstrate two-dimensional spatial mapping of phonons in a single silicon–germanium (SiGe) quantum dot (QD) using monochromated electron energy loss spectroscopy in the transmission electron microscope. Tracking the variation of the Si optical mode in and around the QD, we observe the nanoscale modification of the composition-induced red shift. We observe non-equilibrium phonons that only exist near the interface and, furthermore, develop a novel technique to differentially map phonon momenta, providing direct evidence that the interplay between diffuse and specular reflection largely depends on the detailed atomistic structure: a major advancement in the field. Our work unveils the non-equilibrium phonon dynamics at nanoscale interfaces and can be used to study actual nanodevices and aid in the understanding of heat dissipation near nanoscale hotspots, which is crucial for future high-performance nanoelectronics. 
    more » « less
  4. Abstract Mechanically programmable, reconfigurable micro/nanoscale materials that can dynamically change their mechanical properties or behaviors, or morph into distinct assemblies or swarms in response to stimuli have greatly piqued the interest of the science community due to their unprecedented potentials in both fundamental research and technological applications. To date, a variety of designs of hard and soft materials, as well as actuation schemes based on mechanisms including chemical reactions and magnetic, acoustic, optical, and electric stimuli, have been reported. Herein, state‐of‐the‐art micro/nanostructures and operation schemes for multimodal reconfigurable micro/nanomachines and swarms, as well as potential new materials and working principles, challenges, and future perspectives are discussed. 
    more » « less
  5. Abstract Since the first discovery of graphene, 2D materials are drawing tremendous attention due to their atomic thickness and superior properties. Fabrication of high‐quality micro‐/nanopatterns of 2D materials is essential for their applications in both nanoelectronics and nanophotonics. In this work, an all‐optical lithographic technique, optothermoplasmonic nanolithography (OTNL), is developed to achieve high‐throughput, versatile, and maskless patterning of different atomic layers. Low‐power (≈5 mW µm−2) and high‐resolution patterning of both graphene and MoS2monolayers is demonstrated through exploiting thermal oxidation and sublimation at the highly localized thermoplasmonic hotspots. Density functional theory simulations reveal that Au nanoparticles reduce the formation energy (≈0.6 eV) of C monovacancies through bonding between undercoordinated C and Au, leading to a significant Au‐catalyzed graphene oxidation and a reduction of the required laser operation power. Programmable patterning of 2D materials into complex and large‐scale nanostructures is further demonstrated. With its low‐power, high‐resolution, and versatile patterning capability, OTNL offers the possibility to scale up the fabrication of nanostructured 2D materials for many applications in photonic and electronic devices. 
    more » « less