skip to main content


Title: Carbon Fluxes and Primary Magma CO 2 Contents Along the Global Mid‐Ocean Ridge System
Abstract

The concentration of carbon in primary mid‐ocean ridge basalts (MORBs), and the associated fluxes of CO2outgassed at ocean ridges, is examined through new data obtained by secondary ion mass spectrometry (SIMS) on 753 globally distributed MORB glasses. MORB glasses are typically 80–90% degassed of CO2. We thus use the limited range in CO2/Ba (81.3 ± 23) and CO2/Rb (991 ± 129), derived from undegassed MORB and MORB melt inclusions, to estimate primary CO2concentrations for ridges that have Ba and/or Rb data. When combined with quality‐controlled volatile‐element data from the literature (n = 2,446), these data constrain a range of primary CO2abundances that vary from 104 ppm to 1.90 wt%. Segment‐scale data reveal a range in MORB magma flux varying by a factor of 440 (from 6.8 × 105to 3.0 × 108m3/year) and an integrated global MORB magma flux of 16.5 ± 1.6 km3/year. When combined with CO2/Ba and CO2/Rb‐derived primary magma CO2abundances, the calculated segment‐scale CO2fluxes vary by more than 3 orders of magnitude (3.3 × 107to 4.0 × 1010mol/year) and sum to an integrated global MORB CO2flux of × 1012mol/year. Variations in ridge CO2fluxes have a muted effect on global climate; however, because the vast majority of CO2degassed at ridges is dissolved into seawater and enters the marine bicarbonate cycle. MORB degassing would thus only contribute to long‐term variations in climate via degassing directly into the atmosphere in shallow‐water areas or where the ridge system is exposed above sea level.

 
more » « less
Award ID(s):
1634421
PAR ID:
10457135
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  ;  ;  ;  
Publisher / Repository:
DOI PREFIX: 10.1029
Date Published:
Journal Name:
Geochemistry, Geophysics, Geosystems
Volume:
20
Issue:
3
ISSN:
1525-2027
Format(s):
Medium: X Size: p. 1387-1424
Size(s):
p. 1387-1424
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract

    Subduction‐related lavas have higher Fe3+/∑Fe than midocean ridge basalts (MORB). Hypotheses for this offset include imprint from subducting slabs and differentiation in thickened crust. These ideas are readily tested through examination of the time‐dependent evolution of slab‐derived signatures, thickening crust of the overriding plate, and evolving redox during subduction initiation. Here, we present Fe3+/ΣFe and volatile element abundances of volcanic glasses recovered from International Ocean Discovery Program (IODP) Expedition 352 to the Izu‐Bonin‐Mariana (IBM) forearc. The samples include forearc basalts (FAB) that are stratigraphically overlain by low‐ and high‐silica boninite lavas. The FAB glasses have 0.18–0.85 wt% H2O, 75–233 ppm CO2, S contents controlled by saturation with a sulfide phase (602–1,386 ppm), Ba/La from 3.9‐10, and Fe3+/ΣFe ratios from 0.136 to 0.177. These compositions are similar to MORB and suggest that decompression melting of dry and reduced mantle dominates the earliest stages of subduction initiation. Low‐ and high‐silica boninite glasses have 1.51–3.19 wt% H2O, CO2below detection, S contents below those required for sulfide saturation (5–235 ppm), Ba/La from 11 to 29, and Fe3+/∑Fe from 0.181 to 0.225. The compositions are broadly similar to modern arc lavas in the IBM arc. These data demonstrate that the establishment of fluid‐fluxed melting of the mantle, which occurs in just 0.6–1.2 my after subduction initiation, is synchronous with the production of oxidized, mantle‐derived magmas. The coherence of high Fe3+/∑Fe and Ba/La ratios with high H2O contents in Expedition 352 glasses and the modern IBM arc rocks strongly links the production of oxidized arc magmas to signatures of slab dehydration.

     
    more » « less
  2. Abstract

    Continental flood basalts intruded and erupted millions of km3of magma over ∼1–5 Ma. Previous work proposed the presence of large (–106 km3) crustal magma reservoirs to feed these eruptions. However, in Paper I, we illustrated that this model is inconsistent with observations, by combining eruptive rate constraints with geochemical and geophysical observations from the Deccan Traps and other Continental flood basalt provinces (CFBs). Here, we use a new mechanical magma reservoir model to calculate the variation of eruptive fluxes (km3/year) and volumes for different magmatic architectures. We find that a single magma reservoir cannot explain the eruptive rate and duration constraints for CFBs. Using a 1D thermal model and characteristic timescales for magma reservoirs, we conclude that CFB eruptions were likely fed by a number of interconnected small‐medium (∼102–103 km3) magma reservoirs. It is unlikely that each individual magma reservoir participated in every eruption, thus permitting the occasional formation of large xenocrysts (e.g., megacrystic plagioclase). This magmatic architecture permits (a) large volume eruptive episodes with 10–100s of years duration, and (b) relatively short time‐periods separating eruptive episodes (1000s of years) since multiple mechanisms can trigger eruptions (via magma recharge or volatile exsolution, as opposed to long term (105–106 year) accumulation of buoyancy overpressure), and (c) lack of large upper‐crustal intrusive bodies in various geophysical datasets. Our new proposed magmatic architecture has significant implications for the tempo of CFB volatile release (CO2and SO2), potentially helping explain the pre‐K‐Pg warming associated with Deccan Traps.

     
    more » « less
  3. Abstract

    Quantifying the global volcanic CO2output from subaerial volcanism is key for a better understanding of rates and mechanisms of carbon cycling in and out of our planet and their consequences for the long‐term evolution of Earth's climate over geological timescales. Although having been the focus of intense research since the early 1990s, and in spite of recent progress, the global volcanic CO2output remains inaccurately known. Here we review past developments and recent progress and examine limits and caveats of our current understanding and challenges for future research. We show that CO2flux measurements are today only available for ~100 volcanoes (cumulative measured flux, 44 Tg CO2/year), implying that extrapolation is required to account for the emissions of the several hundred degassing volcanoes worldwide. Recent extrapolation attempts converge to indicate that persistent degassing through active crater fumaroles and plumes releases ~53–88 Tg CO2/year, about half of which is released from the 125 most actively degassing subaerial volcanoes (36.4 ± 2.4 Tg CO2/year from strong volcanic gas emitters,Svge). The global CO2output sustained by diffuse degassing via soils, volcanic lakes, and volcanic aquifers is even less well characterized but could be as high as 83 to 93 Tg CO2/year, rivaling that from the far more manifest crater emissions. Extrapolating these current fluxes to the past geological history of the planet is challenging and will require a new generation of models linking subduction parameters to magma and volatile (CO2) fluxes.

     
    more » « less
  4. Abstract

    The degassing of CO2and S from arc volcanoes is fundamentally important to global climate, eruption forecasting, ore deposits, and the cycling of volatiles through subduction zones. However, all existing thermodynamic/empirical models have difficulties reproducing CO2‐H2O‐S trends observed in melt inclusions and provide widely conflicting results regarding the relationships between pressure and CO2/SO2in the vapor. In this study, we develop an open‐source degassing model, Sulfur_X, to track the evolution of S, CO2, H2O, and redox states in melt and vapor in ascending mafic‐intermediate magma. Sulfur_X describes sulfur degassing by parameterizing experimentally derived sulfur partition coefficients for two equilibria: RxnI. FeS (m) + H2O (v H2S (v) + FeO (m), and RxnII. CaSO4(m)  SO2(v) + O2(v) + CaO (m), based on the sulfur speciation in the melt (m) and co‐existing vapor (v). Sulfur_X is also the first to track the evolution offO2and sulfur and iron redox states accurately in the system using electron balance and equilibrium calculations. Our results show that a typical H2O‐rich (4.5 wt.%) arc magma with high initial S6+/ΣS ratio (>0.5) will degas much more (∼2/3) of its initial sulfur at high pressures (>200 MPa) than H2O‐poor ocean island basalts with low initial S6+/ΣS ratio (<0.1), which will degas very little sulfur until shallow pressures (<50 MPa). The pressure‐S relationship in the melt predicted by Sulfur_X provides new insights into interpreting the CO2/STratio measured in high‐T volcanic gases in the run‐up to the eruption.

     
    more » « less
  5. Abstract

    Mount Cleveland is one of Alaska's most active volcanoes, yet little is known about the magmatic system driving persistent and dynamic volcanic activity. Volcanic gas and melt inclusion (MI) data from 2016 were combined to investigate shallow magmatic processes. SO2emission rates were between 166 and 324 t/day and the H2O/SO2was 600 ± 53, whereas CO2and H2S were below detection. Olivine‐, clinopyroxene‐, and plagioclase‐hosted MIs have up to 3.8 wt.% H2O, 514 ppm CO2, and 2,320 ppm S. Equilibration depths, based on MI H2O contents, suggest that a magmatic column extended from 0.5 to 3.0 km (~10–60 MPa). We used MI data to empirically model open‐system H‐C‐S degassing from 0 to 12 km and found that a column of magma between 0.5 and 3 km could produce the measured gas H2O/SO2ratio. However, additional magma deeper than 3 km is required to sustain emissions over periods greater than days to weeks, if the observed vent dimension is a valid proxy for the conduit. Assuming an initial S content of 2,320 ppm, the total magma supply needed to sustain the annual SO2flux was 5 to 9.8 Mm3/yr, suggesting a maximum intrusive‐to‐extrusive ratio of 13:1. The model predicts degassing of <50 t/day CO2for July 2016, which corresponds to a maximum predicted CO2/SO2of 0.2. Ultimately, frequent recharge from deeper, less degassed magma is required to drive the continuous activity observed over multiple years. During periods of recharge we would expect lower H2O/SO2and measurable volcanic CO2.

     
    more » « less