We envision programmable matters that can alter their physical properties in desirable manners based on user input or autonomous sensing. This vision motivates the pursuit of mechanical metamaterials that interact with the environment in a programmable fashion. However, this has not been systematically achieved for soft metamaterials because of the highly nonlinear deformation and underdevelopment of rational design strategies. Here, we use computational morphogenesis and multimaterial polymer 3D printing to systematically create soft metamaterials with arbitrarily programmable temperature-switchable nonlinear mechanical responses under large deformations. This is made possible by harnessing the distinct glass transition temperatures of different polymers, which, when optimally synthesized, produce local and giant stiffness changes in a controllable manner. Featuring complex geometries, the generated structures and metamaterials exhibit fundamentally different yet programmable nonlinear force-displacement relations and deformation patterns as temperature varies. The rational design and fabrication establish an objective-oriented synthesis of metamaterials with freely tunable thermally adaptive behaviors. This imbues structures and materials with environment-aware intelligence. 
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                            Laser‐Induced Graphene for Electrothermally Controlled, Mechanically Guided, 3D Assembly and Human–Soft Actuators Interaction
                        
                    
    
            Abstract Mechanically guided, 3D assembly has attracted broad interests, owing to its compatibility with planar fabrication techniques and applicability to a diversity of geometries and length scales. Its further development requires the capability of on‐demand reversible shape reconfigurations, desirable for many emerging applications (e.g., responsive metamaterials, soft robotics). Here, the design, fabrication, and modeling of soft electrothermal actuators based on laser‐induced graphene (LIG) are reported and their applications in mechanically guided 3D assembly and human–soft actuators interaction are explored. Over 20 complex 3D architectures are fabricated, including reconfigurable structures that can reshape among three distinct geometries. Also, the structures capable of maintaining 3D shapes at room temperature without the need for any actuation are realized by fabricating LIG actuators at an elevated temperature. Finite element analysis can quantitatively capture key aspects that govern electrothermally controlled shape transformations, thereby providing a reliable tool for rapid design optimization. Furthermore, their applications are explored in human–soft actuators interaction, including elastic metamaterials with human gesture‐controlled bandgap behaviors and soft robotic fingers which can measure electrocardiogram from humans in an on‐demand fashion. Other demonstrations include artificial muscles, which can lift masses that are about 110 times of their weights and biomimetic frog tongues which can prey insects. 
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                            - Award ID(s):
- 1917630
- PAR ID:
- 10457476
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Materials
- Volume:
- 32
- Issue:
- 17
- ISSN:
- 0935-9648
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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