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Abstract Orthorhombic molybdenum trioxide (α‐MoO3) is a highly anisotropic hyperbolic material in nature. Within its wide Reststrahlen bands, α‐MoO3has hyperboloidal dispersion that supports bulk propagation of high‐k phonon polariton modes. These modes can serve as energy transport channels to greatly enhance radiative heat transfer inside the material. In this work, large radiative transfer enabled by phonon polaritons in α‐MoO3is demonstrated. The study first determines the temperature‐dependent permittivity of α‐MoO3from polarized Fourier‐Transform Infrared (FTIR) spectroscopy measurements and then uses a many‐body radiative heat transfer model to predict the equivalent radiative thermal conductivity of hyperbolic phonon polariton. Contribution of radiative transfer to the total thermal transport is experimentally determined from the Time‐Domain Thermoreflectance (TDTR) measurements in a temperature range from −100 to 300 °C. It is found that radiative transfer can account for ≈60% of the total thermal transport at a temperature of 300 °C. That is, conductive thermal transport is enhanced by >100% by radiative transfer, or radiation inside α‐MoO3is greater than that of conduction. These additional energy pathways will have important implications in thermal management in new materials and devices.
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Energy Transport by Radiation in Hyperbolic Material Comparable to Conduction
Abstract Radiation as a heat transfer mode inside a bulk material is usually negligible in comparison to conduction. Here, the contribution of radiation to energy transport inside a hyperbolic material, hexagonal boron nitride (hBN), is investigated. With hyperbolic dispersion, i.e., opposite signs of dielectric components along principal directions, phonon polaritons contribute significantly to energy transport due to a much greater number of propagating modes compared to that in a normal material. A many‐body model is developed to account for radiative heat transfer in a material with a nonuniform temperature distribution. The total radiative heat transfer through hBN is found to be largely contributed by the high‐κ modes within the Reststrahlen bands, and is comparable to phonon conduction. Experimental measurements of temperature‐dependent thermal transport also show that radiative contribution to thermal transport is of the same order as that from phonons. Therefore, this work shows, for the first time, radiative heat transfer inside a material can be comparable to phonon conductive heat transfer.
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- Award ID(s):
- 1804377
- PAR ID:
- 10458635
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Functional Materials
- Volume:
- 30
- Issue:
- 6
- ISSN:
- 1616-301X
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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