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1. Organic electro-optic materials combining extraordinary nonlinearity with exceptional stability to enable commercial applications

   https://doi.org/10.1117/12.2622099  

   Hammond, Scott R. ; O'Malley, Kevin M. ; Xu, Huajun ; Elder, Delwin L. ; Johnson, Lewis E. ( March 2022 , Organic Photonic Materials and Devices XXIV)

   Rau, Ileana ; Sugihara, Okihiro ; Shensky, William M. (Ed.)

   Hybrid organic electro-optic (OEO) modulators consist of a layer of ordered organic chromophores confined between layers of metals or semiconductors, enabling optical fields to be tightly confined within the OEO material. The combination of tight confinement with the high electro-optic (EO) performance of state-of-the-art OEO materials enables extraordinary EO modulation performance in silicon-organic hybrid (SOH) and plasmonic-organic hybrid (POH) device architectures. Recent records in POH devices include bandwidths >500 GHz and energy efficiency <100 aJ/bit. To enable commercial applications of these materials and devices, however, they must withstand demanding thermal and environmental conditions, both during manufacture and operation. To address these concerns, we examined the long-term thermal and environmental shelf storage stability of state-of-the-art commercial and developmental OEO materials under a variety of conditions relevant to Telecordia GR-468-CORE standards. We examined the shelf storage of poled OEO materials under a nitrogen atmosphere at a range of temperatures from 85 ̊C up to 150 ̊C to understand the kinetics of the thermally activated de-poling of the OEO materials. We also examined the shelf storage of OEO materials under a variety of atmospheres, including the aggressive 85 ̊C and 85% relative humidity damp heat condition, to understand the relative sensitivities of the materials to water and oxygen at different temperatures. We analyze the results of these studies and discuss their implications for commercial application of these materials and devices, including manufacturing, encapsulation requirements, and expected operational lifetimes. 

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2. Phase transition mechanism and bandgap engineering of Sb2S3 at gigapascal pressures

   https://doi.org/10.1038/s42004-021-00565-4  

   Cui, Zhongxun ; Bu, Kejun ; Zhuang, Yukai ; Donnelly, Mary-Ellen ; Zhang, Dongzhou ; Dalladay-Simpson, Philip ; Howie, Ross T. ; Zhang, Jiandong ; Lü, Xujie ; Hu, Qingyang ( September 2021 , Communications Chemistry)

   Earth-abundant antimony trisulfide (Sb₂S₃), or simply antimonite, is a promising material for capturing natural energies like solar power and heat flux. The layered structure, held up by weak van-der Waals forces, induces anisotropic behaviors in carrier transportation and thermal expansion. Here, we used stress as mechanical stimuli to destabilize the layered structure and observed the structural phase transition to a three-dimensional (3D) structure. We combined in situ x-ray diffraction (XRD), Raman spectroscopy, ultraviolet-visible spectroscopy, and first-principles calculations to study the evolution of structure and bandgap width up to 20.1 GPa. The optical band gap energy of Sb₂S₃followed a two-step hierarchical sequence at approximately 4 and 11 GPa. We also revealed that the first step of change is mainly caused by the redistribution of band states near the conduction band maximum. The second transition is controlled by an isostructural phase transition, with collapsed layers and the formation of a higher coordinated bulky structure. The band gap reduced from 1.73 eV at ambient to 0.68 eV at 15 GPa, making it a promising thermoelectric material under high pressure.

    

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3. Mapping physiology: biophysical mechanisms define scales of climate change impacts

   https://doi.org/10.1093/conphys/coz028  

   Choi, Francis ; Gouhier, Tarik ; Lima, Fernando ; Rilov, Gil ; Seabra, Rui ; Helmuth, Brian ; Seebacher, Frank ( January 2019 , Conservation Physiology)

   Abstract The rocky intertidal zone is a highly dynamic and thermally variable ecosystem, where the combined influences of solar radiation, air temperature and topography can lead to differences greater than 15°C over the scale of centimetres during aerial exposure at low tide. For most intertidal organisms this small-scale heterogeneity in microclimates can have enormous influences on survival and physiological performance. However, the potential ecological importance of environmental heterogeneity in determining ecological responses to climate change remains poorly understood. We present a novel framework for generating spatially explicit models of microclimate heterogeneity and patterns of thermal physiology among interacting organisms. We used drone photogrammetry to create a topographic map (digital elevation model) at a resolution of 2 × 2 cm from an intertidal site in Massachusetts, which was then fed into to a model of incident solar radiation based on sky view factor and solar position. These data were in turn used to drive a heat budget model that estimated hourly surface temperatures over the course of a year (2017). Body temperature layers were then converted to thermal performance layers for organisms, using thermal performance curves, creating ‘physiological landscapes’ that display spatially and temporally explicit patterns of ‘microrefugia’. Our framework shows how non-linear interactions between these layers lead to predictions about organismal performance and survivorship that are distinct from those made using any individual layer (e.g. topography, temperature) alone. We propose a new metric for quantifying the ‘thermal roughness’ of a site (RqT, the root mean square of spatial deviations in temperature), which can be used to quantify spatial and temporal variability in temperature and performance at the site level. These methods facilitate an exploration of the role of micro-topographic variability in driving organismal vulnerability to environmental change using both spatially explicit and frequency-based approaches. 

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4. Experimental study on combined effect of mechanical loads and corrosion using tube-packaged long-gauge fiber Bragg grating sensors

   https://doi.org/10.1177/14759217231164961  

   Xu, Luyang ; Shi, Shuomang ; Yan, Fei ; Huang, Ying ; Bao, Yi ( April 2023 , Structural Health Monitoring)

   This study presents an experimental investigation on the combined effect of mechanical loads and corrosion using the designed polytetrafluoroethylene tube-packaged fiber Bragg grating (FBG) sensors, as to implement long-gauge FBG (LFBG) sensors in corrosion detection practices for structural health monitoring. A simplified LFBG-based sensing model was proposed for strain measurement in terms of the Bragg wavelength change. Correspondingly, a systematic corrosion assessment strategy was developed to estimate corrosion severity and average corrosion rate. Upon this, the experimental study was performed on epoxy-coated steel specimens embedded with LFBG sensors, where the loading, corrosion, and combined loading–corrosion tests were used to explore the effect of mechanical loads on corrosion behavior. Test results revealed that the specimens subjected to combined conditions exhibited more severe corrosion damage. The maximum mass loss was observed to be 1.82 and 2.43 in percentage under individual corrosion and combined loading–corrosion conditions, respectively. Also, the pit depth under combined conditions was found to develop rapidly in the early stage. The pit depth severity ratio was around 0.2–0.8 during the 67 days of exposure, indicating an evident impact of loading on corrosion severity. Furthermore, the maximum average corrosion rate under combined conditions was found to be 5.66 times that under individual corrosion conditions.

    

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5. An entropy method for geodynamic modelling of phase transitions: capturing sharp and broad transitions in a multiphase assemblage

   https://doi.org/10.1093/gji/ggac293  

   Dannberg, Juliane ; Gassmöller, Rene ; Li, Ranpeng ; Lithgow-Bertelloni, Carolina ; Stixrude, Lars ( July 2022 , Geophysical Journal International)

   Phase transitions play an important role for the style of mantle convection. While observations and theory agree that a substantial fraction of subducted slabs and rising plumes can move through the whole mantle at present day conditions, this behaviour may have been different throughout Earth’s history. Higher temperatures, such as in the early Earth, cause different phase transitions to be dominant, and also reduce mantle viscosity, favouring a more layered style of convection induced by phase transitions. A period of layered mantle convection in Earth’s past would have significant implications for the secular evolution of the mantle temperature and the mixing of mantle heterogeneities. The transition from layered to whole mantle convection could lead to a period of mantle avalanches associated with a dramatic increase in magmatic activity. Consequently, it is important to accurately model the influence of phase transitions on mantle convection. However, existing numerical methods generally preclude modelling phase transitions that are only present in a particular range of pressures, temperatures or compositions, and they impose an artificial lower limit on the thickness of phase transitions. To overcome these limitations, we have developed a new numerical method that solves the energy equation for entropy instead of temperature. This technique allows for robust coupling between thermodynamic and geodynamic models and makes it possible to model realistically sharp phase transitions with a wide range of properties and dynamic effects on mantle processes. We demonstrate the utility of our method by applying it in regional and global convection models, investigating the effect of individual phase transitions in the Earth’s mantle with regard to their potential for layering flow. We find that the thickness of the phase transition has a bigger influence on the style of convection than previously thought: with all other parameters being the same, a thin phase transition can induce fully layered convection where a broad phase transition would lead to whole-mantle convection. Our application of the method to convection in the early Earth illustrates that endothermic phase transitions may have induced layering for higher mantle temperatures in the Earth’s past.

    

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