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ABSTRACT The physical aging behavior, time‐dependent densification, of thin polystyrene (PS) films supported on silicon are investigated using ellipsometry for a large range of molecular weights (MWs) fromMw = 97 to 10,100 kg mol−1. We report an unexpected MW dependence to the physical aging rate ofh < 80‐nm thick films not present in bulk films, where samples made from ultra‐high MWs ≥ 6500 kg mol−1exhibit on average a 45% faster aging response at an aging temperature of 40 °C compared with equivalent films made from (merely) high MWs ≤ 3500 kg mol−1. This MW‐dependent difference in physical aging response indicates that the breadth of the gradient in dynamics originating from the free surface in these thin films is diminished for films of ultra‐high MW PS. In contrast, measures of the film‐average glass transition temperatureTg(h) and effective average film density (molecular packing) show no corresponding change for the same range of film thicknesses, suggesting physical aging may be more sensitive to differences in dynamical gradients. These results contribute to growing literature reports signaling that chain connectivity and entropy play a subtle, but important role in how glassy dynamics are propagated from interfaces. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys.2019,57, 1224–1238
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Validation of quartz crystal rheometry in the megahertz frequency regime
ABSTRACT The utility of the quartz crystal microbalance (QCM) as a high‐frequency rheometer operating at 15 MHz was demonstrated. High‐frequency data obtained from a series of rubbery materials were compared with results obtained from traditional dynamic mechanical analysis (DMA) at much lower frequencies. The high‐frequency data enable meaningful shift factors to be obtained at temperatures much further above glass‐transition temperature (Tg) than would otherwise be possible, giving a more complete picture of the temperature dependence of the viscoelastic properties. The QCM can also be used to quantify mass uptake and changes in viscoelastic properties during sample oxidation. The viscoelastic response spanning the full range of behaviors from the rubber to glassy regimes was found to fit well with a six‐element model consisting of three power‐law springpot elements. One of these elements is particularly sensitive to the behavior in the transition regime where the phase angle is maximized. The value of this quantity is obtained from the maximum phase angle, which can be obtained from a temperature sweep at fixed frequency, proving a means for more detailed frequency‐dependent rheometric information to be obtained from a fixed‐frequency measurement at a range of temperatures. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys.2019,57, 1246–1254
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- Award ID(s):
- 1710491
- PAR ID:
- 10461566
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Journal of Polymer Science Part B: Polymer Physics
- Volume:
- 57
- Issue:
- 18
- ISSN:
- 0887-6266
- Page Range / eLocation ID:
- p. 1246-1254
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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