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1. Chemical Speciation: Defining the Niche of Hot Spring Ammonia-Oxidizing Archaea (Oral Presentation)

   Weeks, Katelyn; Trembath-Reichert, Elizabeth; Robare, Jordyn; Debes, Vincent R; Howells, Alta; Boyer, Grayson; Shock, Everett L (July 2025, Goldschmidt 2025 Conference)

   The availability of chemical energy supplies is fundamental to environmental and planetary habitability. However, the presence of a chemical energy supply does not guarantee the presence of microorganisms capable of consuming it. In this study, chemical energy supplies available in Yellowstone National Park (YNP) hot springs were calculated, and the results indicate that ammonia oxidation, calculated using total dissolved ammonia, is one of the major energy supplies. Nevertheless, known ammonia-oxidizers (AO) are only present in a small fraction of the hot springs tested. Where AO are present, they do not dominate the microbial communities (relative abundances <5%), even in cases where total dissolved ammonia oxidation is the richest energy supply. The AO in YNP hot springs are predominantly ammonia-oxidizing archaea (AOA), which tend to favor environments with low total ammonia (sum of NH3 and NH4+) concentrations, despite the requirement of ammonia (NH3) as a substrate. Hot spring pH and temperature determine the ratio of NH3 to NH4+ and, consequently, NH3 availability to resident AOA. In this study, total ammonia measurements were collected from YNP hot spring samples using ion chromatography in coordination with biological sampling. DNA was extracted from simultaneously collected samples for 16S rRNA gene sequencing and analysis, and for the identification of known AOA. The WORM-portal (https://worm-portal.asu.edu/) was used to speciate the total ammonia measurements into ammonia and ammonium activities. By performing speciation calculations, we identified a potential lower limit for substrate (NH3) availability and a potential upper limit for NH4+ concentrations for the YNP hot spring AOA. Thus, the niche for AOA across YNP hot springs is dictated by the form of the total dissolved ammonia present, not by the energy supply available for total dissolved ammonia oxidation. 

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2. Urban aerosol chemistry at a land-water transition site during summer – Part 1: Impact of agricultural and industrial ammonia emissions

   Balasus, N. (January 2021, Atmospheric chemistry and physics discussion)

   null (Ed.)

   This study characterizes the impact of the Chesapeake Bay and associated meteorological phenomena on aerosol chemistry during the second Ozone Water-Land Environmental Transition Study (OWLETS-2) field campaign during summer 2018. Measurements of inorganic PM2.5 composition, gas-phase ammonia (NH3), and an array of meteorological parameters were undertaken at Hart-Miller Island (HMI), a land-water transition site just east of downtown Baltimore on the Chesapeake Bay. The observations at HMI were characterized by abnormally high NH3 concentrations (maximum of 19.3 μg m-3, average of 3.83 μg m-3), which were more than a factor of three higher than NH3 levels measured at the closest Atmospheric Ammonia Network (AMoN) site (approximately 45 km away). While sulfate concentrations at HMI agreed quite well with those measured at a regulatory monitoring station 45 km away, aerosol ammonium and nitrate concentrations were significantly higher, due to the ammonia-rich conditions that resulted from the elevated NH3. The high NH3 concentrations were largely due to regional agricultural emissions, including dairy farms in southeastern Pennsylvania and poultry operations in the Delmarva Peninsula (Delaware-Maryland-Virginia). Reduced NH3 deposition during transport over the Chesapeake Bay likely contributed to enhanced concentrations at HMI compared to the more inland AMoN site. Several peak NH3 events were recorded, including the maximum NH3 observed during OWLETS-2, that appear to originate from a cluster of industrial sources near downtown Baltimore. Such events were all associated with nighttime emissions and advection to HMI under low 15 wind speeds (< 1 m s-1) and stable atmospheric conditions. Our results demonstrate the importance of industrial sources, including several that are not represented in the emissions inventory, on urban air quality. Together with our companion paper, which examines aerosol liquid water and pH during OWLETS-2, we highlight unique processes affecting urban air quality of coastal cities that are distinct from continental locations. 

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3. Urban aerosol chemistry at a land–water transition site during summer – Part 1: Impact of agricultural and industrial ammonia emissions

   https://doi.org/10.5194/acp-21-13051-2021  

   Balasus, Nicholas; Battaglia Jr., Michael A.; Ball, Katherine; Caicedo, Vanessa; Delgado, Ruben; Carlton, Annmarie G.; Hennigan, Christopher J. (January 2021, Atmospheric Chemistry and Physics)

   Abstract. This study characterizes the impact of the Chesapeake Bay and associated meteorological phenomena on aerosol chemistry during the second Ozone Water-Land Environmental Transition Study (OWLETS-2) field campaign, which took place from 4 June to 5 July 2018. Measurements of inorganic PM2.5 composition, gas-phase ammonia (NH3), and an array of meteorological parameters were undertaken at Hart-Miller Island (HMI), a land–water transition site just east of downtown Baltimore on the Chesapeake Bay. The observations at HMI were characterized by abnormally high NH3 concentrations (maximum of 19.3 µg m−3, average of 3.83 µg m−3), which were more than a factor of 3 higher than NH3 levels measured at the closest atmospheric Ammonia Monitoring Network (AMoN) site (approximately 45 km away). While sulfate concentrations at HMI agreed quite well with those measured at a regulatory monitoring station 45 km away, aerosol ammonium and nitrate concentrations were significantly higher, due to the ammonia-rich conditions that resulted from the elevated NH3. The high NH3 concentrations were largely due to regional agricultural emissions, including dairy farms in southeastern Pennsylvania and poultry operations in the Delmarva Peninsula (Delaware–Maryland–Virginia). Reduced NH3 deposition during transport over the Chesapeake Bay likely contributed to enhanced concentrations at HMI compared to the more inland AMoN site. Several peak NH3 events were recorded, including the maximum NH3 observed during OWLETS-2, that appear to originate from a cluster of industrial sources near downtown Baltimore. Such events were all associated with nighttime emissions and advection to HMI under low wind speeds (< 1 m s−1) and stable atmospheric conditions. Our results demonstrate the importance of industrial sources, including several that are not represented in the emissions inventory, on urban air quality. Together with our companion paper, which examines aerosol liquid water and pH during OWLETS-2, we highlight unique processes affecting urban air quality of coastal cities that are distinct from continental locations. 

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4. Rotation Periods of TESS Objects of Interest from the Magellan-TESS Survey with Multiband Photometry from Evryscope and TESS

   https://doi.org/10.3847/1538-3881/ac0fe3  

   Howard, Ward S; Teske, Johanna; Corbett, Hank; Law, Nicholas M; Wang, Sharon Xuesong; Ratzloff, Jeffrey K; Galliher, Nathan W; Gonzalez, Ramses; Soto, Alan Vasquez; Glazier, Amy L; et al (September 2021, The Astronomical Journal)

   Abstract Stellar radial-velocity (RV) jitter due to surface activity may bias the RV semiamplitude and mass of rocky planets. The amplitude of the jitter may be estimated from the uncertainty in the rotation period, allowing the mass to be more accurately obtained. We find candidate rotation periods for 17 out of 35 TESS Objects of Interest (TOI) hosting <3R_⊕planets as part of the Magellan-TESS survey, which is the first-ever statistically robust study of exoplanet masses and radii across the photoevaporation gap. Seven periods are ≥3σdetections, two are ≥1.5σ, and eight show plausible variability, but the periods remain unconfirmed. The other 18 TOIs are nondetections. Candidate rotators include the host stars of the confirmed planets L 168-9 b, the HD 21749 system, LTT 1445 A b, TOI 1062 b, and the L 98-59 system. Thirteen candidates have no counterpart in the 1000 TOI rotation catalog of Canto Martins et al. We find periods for G3–M3 dwarfs using combined light curves from TESS and the Evryscope all-sky array of small telescopes, sometimes with longer periods than would be possible with TESS alone. Secure periods range from 1.4 to 26 days with Evryscope-measured photometric amplitudes as small as 2.1 mmag in $g\prime$. We also apply Monte Carlo sampling and a Gaussian process stellar activity model fromexoplanetto the TESS light curves of six TOIs to confirm the Evryscope periods. 

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5. Ab Initio Calculations on the Ground and Excited Electronic States of Thorium–Ammonia, Thorium–Aza-Crown, and Thorium–Crown Ether Complexes

   https://doi.org/10.3390/molecules28124712  

   Lu, Zhongyuan; Jackson, Benjamin A; Miliordos, Evangelos (June 2023, Molecules)

   Positively charged metal–ammonia complexes are known to host peripheral, diffuse electrons around their molecular skeleton. The resulting neutral species form materials known as expanded or liquid metals. Alkali, alkaline earth, and transition metals have been investigated previously in experimental and theoretical studies of both the gas and condensed phase. This work is the first ab initio exploration of an f-block metal–ammonia complex. The ground and excited states are calculated for Th0–3+ complexes with ammonia, crown ethers, and aza-crown ethers. For Th3+ complexes, the one valence electron Th populates the metal’s 6d or 7f orbitals. For Th0–2+, the additional electrons prefer occupation of the outer s- and p-type orbitals of the complex, except Th(NH3)10, which uniquely places all four electrons in outer orbitals of the complex. Although thorium coordinates up to ten ammonia ligands, octa-coordinated complexes are more stable. Crown ether complexes have a similar electronic spectrum to ammonia complexes, but excitations of electrons in the outer orbitals of the complex are higher in energy. Aza-crown ethers disfavor the orbitals perpendicular to the crowns, attributed to the N-H bonds pointing along the plane of the crowns. 

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