skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.

Explore Research Products in the PAR
It may take a few hours for recently added research products to appear in PAR search results.


  • NSF Public Access
  • Search Results
  • Carbonation rate of alkali-activated concretes and high-volume SCM concretes: a literature data analysis by RILEM TC 281-CCC
Title: Carbonation rate of alkali-activated concretes and high-volume SCM concretes: a literature data analysis by RILEM TC 281-CCC
Abstract The current understanding of the carbonation and the prediction of the carbonation rate of alkali-activated concretes is complicatedinter aliaby the wide range of binder chemistries used and testing conditions adopted. To overcome some of the limitations of individual studies and to identify general correlations between mix design parameters and carbonation resistance, the RILEM TC 281-CCC ‘Carbonation of Concrete with Supplementary Cementitious Materials’ Working Group 6 compiled and analysed carbonation data for alkali-activated concretes and mortars from the literature. For comparison purposes, data for blended Portland cement-based concretes with a high percentage of SCMs (≥ 66% of the binder) were also included in the database. The analysis indicates that water/CaO ratio and water/binder ratio exert an influence on the carbonation resistance of alkali-activated concretes; however, these parameters are not good indicators of the carbonation resistance when considered individually. A better indicator of the carbonation resistance of alkali-activated concretes under conditions approximating natural carbonation appears to be their water/(CaO + MgOeq + Na2Oeq + K2Oeq) ratio, where the subscript ‘eq’ indicates an equivalent amount based on molar masses. Nevertheless, this ratio can serve as approximate indicator at best, as other parameters also affect the carbonation resistance of alkali-activated concretes. In addition, the analysis of the database points to peculiarities of accelerated tests using elevated CO2concentrations for low-Ca alkali-activated concretes, indicating that even at the relatively modest concentration of 1% CO2, accelerated testing may lead to inaccurate predictions of the carbonation resistance under natural exposure conditions.  more » « less
Award ID(s):
1903457
PAR ID:
10470104
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
RILEM
Date Published:
Journal Name:
Materials and Structures
Volume:
55
Issue:
8
ISSN:
1359-5997
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. ; (, Small)
    Abstract In this work, a new type of multifunctional materials (MFMs) called self‐regenerative Ni‐doped CaTiO3/CaO is introduced for the integrated CO2capture and dry reforming of methane (ICCDRM). These materials consist of a catalytically active Ni‐doped CaTiO3and a CO2sorbent, CaO. The article proposes a concept where the Ni catalyst can be regenerated in situ, which is crucial for ICCDRM. Exsolved Ni nanoparticles are evenly distributed on the surface of CaTiO3under H2or CH4, and are re‐dispersed back into the CaTiO3lattice under CO2. The Ni‐doped CaTiO3/CaO MFMs show stable CO2capture capacity and syngas productivity for 30 cycles of ICCDRM. The presence of CaTiO3between CaO grains prevents CaO/CaCO3thermal sintering during carbonation and decarbonation. Moreover, the strong interaction of CaTiO3with exsolved Ni mitigates severe accumulation of coke deposition. This concept can be useful for developing MFMs with improved properties that can advance integrated carbon capture and conversion. 
    more » « less
  2. ; ; ; ; ; (, AIChE Journal)
    Abstract Portlandite (Ca(OH)2; also known as calcium hydroxide or hydrated lime), an archetypal alkaline solid, interacts with carbon dioxide (CO2) via a classic acid–base “carbonation” reaction to produce a salt (calcium carbonate: CaCO3) that functions as a low‐carbon cementation agent, and water. Herein, we revisit the effects of reaction temperature, relative humidity (RH), and CO2concentration on the carbonation of portlandite in the form of finely divided particulates and compacted monoliths. Special focus is paid to uncover the influences of the moisture state (i.e., the presence of adsorbed and/or liquid water), moisture content and the surface area‐to‐volume ratio (sa/v, mm−1) of reactants on the extent of carbonation. In general, increasing RH more significantly impacts the rate and thermodynamics of carbonation reactions, leading to high(er) conversion regardless of prior exposure history. This mitigated the effects (if any) of allegedly denser, less porous carbonate surface layers formed at lower RH. In monolithic compacts, microstructural (i.e., mass‐transfer) constraints particularly hindered the progress of carbonation due to pore blocking by liquid water in compacts with limited surface area to volume ratios. These mechanistic insights into portlandite's carbonation inform processing routes for the production of cementation agents that seek to utilize CO2borne in dilute (≤30 mol%) post‐combustion flue gas streams. 
    more » « less
  3. ; ; ; ; ; ; (, AGU Advances)
    Abstract U.S. rice paddies, critical for food security, are increasingly contributing to non‐CO2greenhouse gas (GHG) emissions like methane (CH4) and nitrous oxide (N2O). Yet, the full assessment of GHG balance, considering trade‐offs between soil organic carbon (SOC) change and non‐CO2GHG emissions, is lacking. Integrating an improved agroecosystem model with a meta‐analysis of multiple field studies, we found that U.S. rice paddies were the rapidly growing net GHG emission sources, increased 138% from 3.7 ± 1.2 Tg CO2eq yr−1in the 1960s to 8.9 ± 2.7 Tg CO2eq yr−1in the 2010s. CH4, as the primary contributor, accounted for 10.1 ± 2.3 Tg CO2eq yr−1in the 2010s, alongside a notable rise in N2O emissions by 0.21 ± 0.03 Tg CO2eq yr−1. SOC change could offset 14.0% (1.45 ± 0.46 Tg CO2eq yr−1) of the climate‐warming effects of soil non‐CO2GHG emissions in the 2010s. This escalation in net GHG emissions is linked to intensified land use, increased atmospheric CO2, higher synthetic nitrogen fertilizer and manure application, and climate change. However, no/reduced tillage and non‐continuous irrigation could reduce net soil GHG emissions by approximately 10% and non‐CO2GHG emissions by about 39%, respectively. Despite the rise in net GHG emissions, the cost of achieving higher rice yields has decreased over time, with an average of 0.84 ± 0.18 kg CO2eq ha−1emitted per kilogram of rice produced in the 2010s. The study suggests the potential for significant GHG emission reductions to achieve climate‐friendly rice production in the U.S. through optimizing the ratio of synthetic N to manure fertilizer, reducing tillage, and implementing intermittent irrigation. 
    more » « less
  4. ; ; ; ; ; ; ; ; ; ; et al (, Journal of the American Ceramic Society)
    Abstract Glass properties are governed by the interplay between network formers and network modifiers; for a given composition of network formers, the ratio of different cationic modifiers compensating the anionic species in the network has a profound effect, which is often nonlinear, called a mixed modifier effect (MME). We have investigated the MME of sodium (Na) and calcium (Ca) in an aluminosilicate (NCAS) glass series following the formula [Na2O]30−x[CaO]x[Al2O3]10[SiO2]60, wherex = 0, 7.5, 15, 22.5, and 30. A nonadditive trend was observed in hardness and indentation toughness, with aqueous corrosion resistance exhibiting a shift from incongruent to congruent corrosion, whereas the network structure determined by molecular dynamics simulations revealed no significant trend with composition. Additionally, the NCAS glass containing both [Na2O] and [CaO] within an intermediate range exhibited superior resistance to wear at high humidity, a clear MME phenomenon previously only observed in soda–lime silica. 
    more » « less
  5. ; (, Agronomy for Sustainable Development)
    Abstract Agriculture is a key contributor to gaseous emissions causing climate change, the degradation of water quality, and biodiversity loss. The extant climate change crisis is driving a focus on mitigating agricultural gaseous emissions, but wider policy objectives, beyond net zero, mean that evidence on the potential co-benefits or trade-offs associated with on-farm intervention is warranted. For novelty, aggregated data on farm structure and spatial distribution for different farm types were integrated with high-resolution data on the natural environment to generate representative model farms. Accounting for existing mitigation effects, the Catchment Systems Model was then used to quantify global warming potential, emissions to water, and other outcomes for water management catchments across England under both business-as-usual and a maximum technically feasible mitigation potential scenario. Mapped spatial patterns were overlain with the distributions of areas experiencing poor water quality and biodiversity loss to examine potential co-benefits. The median business-as-usual GWP20 and GWP100, excluding embedded emissions, were estimated to be 4606 kg CO2eq. ha−1(inter-quartile range 4240 kg CO2eq. ha−1) and 2334 kg CO2eq. ha−1(inter-quartile range 1462 kg CO2eq. ha−1), respectively. The ratios of business-as-usual GHG emissions to monetized farm production ranged between 0.58 and 8.89 kg CO2eq. £−1for GWP20, compared with 0.53–3.99 kg CO2eq. £−1for GWP100. The maximum mitigation potentials ranged between 17 and 30% for GWP20 and 19-27% for GWP100 with both corresponding medians estimated to be ~24%. Here, we show for the first time that the co-benefits for water quality associated with reductions in phosphorus and sediment loss were both equivalent to around a 34% reduction, relative to business-as-usual, in specific management catchment reporting units where excess water pollutant loads were identified. Several mitigation measures included in the mitigation scenario were also identified as having the potential to deliver co-benefits for terrestrial biodiversity. 
    more » « less
  • Citation Formats
  • MLA
  • APA
  • Chicago
  • BibTeX
  • Save / Share this Record
  • Send to Email