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Synthetic transformation of d -xylose into a four-membered cyclic ether allows for reactions with carbon dioxide (CO 2 ) leading to linear polycarbonates by either a one-step ring-opening copolymerisation (ROCOP) directly, or by sequential isolation of a preformed six-membered cyclic carbonate followed by ring-opening polymerisation (ROP).
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Synthesis of cyclic carbonate monomer using a simple and efficient method
Cyclic carbonate is an important intermediate for preparing polycarbonates, which are crucial materials in diverse research fields. This study introduced a three-step approach to synthesizing a disulfide-containing cyclic carbonate monomer, with confirmation through proton nuclear magnetic resonances (1H NMR) and high-resolution mass spectrum analysis. The resulting monomer holds the potential for subsequent synthesis of responsive functional aliphatic polycarbonates, providing promise for advanced biomedical applications.
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- Award ID(s):
- 2238812
- PAR ID:
- 10482089
- Editor(s):
- Rajeev Prabhakar
- Publisher / Repository:
- Prof Rajeev Prabhakar
- Date Published:
- Volume:
- 4
- Page Range / eLocation ID:
- 1-4
- Subject(s) / Keyword(s):
- NA
- Format(s):
- Medium: X Other: pdf
- Sponsoring Org:
- National Science Foundation
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