This content will become publicly available on September 1, 2024
- Award ID(s):
- 1923365
- NSF-PAR ID:
- 10482144
- Publisher / Repository:
- American Astronomical Society
- Date Published:
- Journal Name:
- The Astrophysical Journal
- Volume:
- 955
- Issue:
- 1
- ISSN:
- 0004-637X
- Page Range / eLocation ID:
- 65
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract In this paper we examine a low-energy solar energetic particle (SEP) event observed by IS⊙IS’s Energetic Particle Instrument-Low (EPI-Lo) inside 0.18 au on 2020 September 30. This small SEP event has a very interesting time profile and ion composition. Our results show that the maximum energy and peak in intensity are observed mainly along the open radial magnetic field. The event shows velocity dispersion, and strong particle anisotropies are observed throughout the event, showing that more particles are streaming outward from the Sun. We do not see a shock in the in situ plasma or magnetic field data throughout the event. Heavy ions, such as O and Fe, were detected in addition to protons and 4He, but without significant enhancements in 3He or energetic electrons. Our analysis shows that this event is associated with a slow streamer blowout coronal mass ejection (SBO-CME), and the signatures of this small CME event are consistent with those typical of larger CME events. The time–intensity profile of this event shows that the Parker Solar Probe encountered the western flank of the SBO-CME. The anisotropic and dispersive nature of this event in a shockless local plasma gives indications that these particles are most likely accelerated remotely near the Sun by a weak shock or compression wave ahead of the SBO-CME. This event may represent direct observations of the source of the low-energy SEP seed particle population.more » « less
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Abstract The temperatures of the heavy ions (
T i ) in the solar corona provide critical information about the heating mechanism of the million-degree corona. However, the measurement ofT i is usually challenging due to the nonthermal motion, instrumental limitations, and optically thin nature of the coronal emissions. We present the measurement ofT i and its dependency on the ion charge-to-mass ratio (Z /A ) at the polar coronal hole boundary, only assuming that heavy ions have the same nonthermal velocity. To improve theZ /A coverage and study the influence of the instrumental broadening, we used a coordinated observation from the EUV Imaging Spectrometer on board the Hinode satellite and the Solar Ultraviolet Measurements of Emitted Radiation (SUMER) on board the Solar and Heliospheric Observatory. We found that theT i of ions withZ /A less than 0.20 or greater than 0.33 are much higher than the local electron temperature. We ran the Alfvén Wave Solar Model-realtime to investigate the formation of optically thin emissions along the line of sight (LOS). The simulation suggested that plasma bulk motions along the LOS broaden the widths of hot emission lines in the coronal hole (e.g., Fexii , Fexiii ). We discussed other factors that might affect theT i measurement, including the non-Gaussian wings in some bright SUMER lines, which can be fitted by a double-Gaussian or aκ distribution. Our study confirms the preferential heating of heavy ions in coronal holes and provides new constraints on coronal heating models. -
Rationale Matrix‐assisted ionization (MAI) mass spectrometry does not require voltages, a laser beam, or added heat to initiate ionization, but it is strongly dependent on the choice of matrix and the vacuum conditions. High charge state distributions of nonvolatile analyte ions produced by MAI suggest that the ionization mechanism may be similar to that of electrospray ionization (ESI), but different from matrix‐assisted laser desorption/ionization (MALDI). While significant information is available for MAI using mass spectrometers operating at atmospheric and intermediate pressure, little is known about the mechanism at high vacuum.
Methods Eleven MAI matrices were studied on a high‐vacuum time‐of‐flight (TOF) mass spectrometer using a 266 nm pulsed laser beam under otherwise typical MALDI conditions. Detailed comparisons with the commonly used MALDI matrices and theoretical prediction were made for 3‐nitrobenzonitrile (3‐NBN), which is the only MAI matrix that works well in high vacuum when irradiated with a laser.
Results Screening of MAI matrices with good absorption at 266 nm but with various degrees of volatility and laser energies suggests that volatility and absorption at the laser wavelength may be necessary, but not sufficient, criteria to explain the formation of multiply charged analyte ions. 3‐NBN produces intact, highly charged ions of nonvolatile analytes in high‐vacuum TOF with the use of a laser, demonstrating that ESI‐like ions can be produced in high vacuum. Theoretical calculations and mass spectra suggest that thermally induced proton transfer, which is the major ionization mechanism in MALDI, is not important with the 3‐NBN matrix at 266 nm laser wavelength. 3‐NBN:analyte crystal morphology is, however, important in ion generation in high vacuum.
Conclusions The 3‐NBN MAI matrix produces intact, highly charged ions of nonvolatile compounds in high‐vacuum TOF mass spectrometers with the aid of ablation and/or heating by laser irradiation, and shows a different ionization mechanism from that of typical MALDI matrices.
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