Abstract The iterative association of monomer units through noncovalent interactions often leads to chiral supramolecular polymers. Monomers comprising these materials can be further divided into those with chiral centers and those without. The latter class is often less studied but attractive since it features monomer designs with chirality at the core rather than the periphery of the molecules. In this mini‐review, we summarize the existing strategies to construct supramolecular polymers from chiral molecules with no chiral centers and offer perspectives on fundamental trends and differences between them and their counterparts with chiral centers. © 2020 Society of Industrial Chemistry
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Impact of Chiral Symmetry Breaking on Spin-Texture and Lone Pair Expression in Chiral Crystals of Hybrid Antimony and Bismuth Halides
- Award ID(s):
- 1729297
- PAR ID:
- 10487628
- Publisher / Repository:
- American Chemical Society
- Date Published:
- Journal Name:
- Chemistry of Materials
- Volume:
- 35
- Issue:
- 21
- ISSN:
- 0897-4756
- Page Range / eLocation ID:
- 9086 to 9101
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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