For domains in R d \mathbb {R}^d , d ≥ 2 d\geq 2 , we prove universal upper and lower bounds on the product of the bottom of the spectrum for the Laplacian to the power p > 0 p>0 and the supremum over all starting points of the p p -moments of the exit time of Brownian motion. It is shown that the lower bound is sharp for integer values of p p and that for p ≥ 1 p \geq 1 , the upper bound is asymptotically sharp as d → ∞ d\to \infty . For all p > 0 p>0 , we prove the existence of an extremal domain among the class of domains that are convex and symmetric with respect to all coordinate axes. For this class of domains we conjecture that the cube is extremal.
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Deuteration of heptamethine cyanine dyes enhances their emission efficacy
We demonstrate that deuteration is a generally applicable strategy that leads to enhanced quantum yields of fluorescence, longer-lived singlet excited states and suppressed rates of non-radiative deactivation processes.
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- Award ID(s):
- 2204263
- PAR ID:
- 10489631
- Publisher / Repository:
- Royal Society of Chemistry
- Date Published:
- Journal Name:
- Chemical Communications
- Volume:
- 60
- Issue:
- 8
- ISSN:
- 1359-7345
- Page Range / eLocation ID:
- 1000 to 1003
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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