Abstract The sensitivity of urban canopy air temperature ( ) to anthropogenic heat flux ( ) is known to vary with space and time, but the key factors controlling such spatiotemporal variabilities remain elusive. To quantify the contributions of different physical processes to the magnitude and variability of (where represents a change), we develop a forcing-feedback framework based on the energy budget of air within the urban canopy layer and apply it to diagnosing simulated by the Community Land Model Urban over the contiguous United States (CONUS). In summer, the median is around 0.01 over the CONUS. Besides the direct effect of on , there are important feedbacks through changes in the surface temperature, the atmosphere–canopy air heat conductance ( ), and the surface–canopy air heat conductance. The positive and negative feedbacks nearly cancel each other out and is mostly controlled by the direct effect in summer. In winter, becomes stronger, with the median value increased by about 20% due to weakened negative feedback associated with . The spatial and temporal (both seasonal and diurnal) variability of as well as the nonlinear response of to are strongly related to the variability of , highlighting the importance of correctly parameterizing convective heat transfer in urban canopy models.
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Effect of crosslinking fraction, hardener functionality and topological quality on stress recovery of thermoset shape memory polymers: a coarse-grained molecular dynamics study
Abstract We analyzed the effects of crosslinking fraction and number of functional sites per hardener molecule on the stress recovery and topology of thermoset shape memory polymers (TSMPs) via coarse-grained molecular dynamics simulations. After systematically varying the quality of the crosslinked network by manipulating the number of unique epoxies reacted with each hardener, we found that two fingerprints correlate well with stress recovery of TSMPs. These fingerprints are the fraction of epoxy molecules connected to two distinct hardener molecules, and the fraction of molecules that are part of the largest or main network in the system. Their product can be used as a topological score ( ) to quantify the topological feature of the network. When analyzing stress recovery as a function of , we found a strong correlation between and recovery stress. Moreover, we observed that while a higher crosslinking fraction did frequently lead to a higher stress recovery, many exceptions existed. High functionality hardeners tend to exhibit higher stress recovery at similar , especially at high (>0.65) . These results suggest that increasing the number of functional sites per hardener molecule combined with improving the topology of the network with a method such as semi batch monomer addition can lead to an improvement in the stress recovery of TSMPs.
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- Award ID(s):
- 1946231
- PAR ID:
- 10496362
- Publisher / Repository:
- https://iopscience.iop.org/article/10.1088/1361-665X/acfa7d
- Date Published:
- Journal Name:
- Smart Materials and Structures
- Volume:
- 32
- Issue:
- 11
- ISSN:
- 0964-1726
- Page Range / eLocation ID:
- 115001
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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