skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Liquid metal-based soft, hermetic, and wireless-communicable seals for stretchable systems
Soft materials tend to be highly permeable to gases, making it difficult to create stretchable hermetic seals. With the integration of spacers, we demonstrate the use of liquid metals, which show both metallic and fluidic properties, as stretchable hermetic seals. Such soft seals are used in both a stretchable battery and a stretchable heat transfer system that involve volatile fluids, including water and organic fluids. The capacity retention of the battery was ~72.5% after 500 cycles, and the sealed heat transfer system showed an increased thermal conductivity of approximately 309 watts per meter-kelvin while strained and heated. Furthermore, with the incorporation of a signal transmission window, we demonstrated wireless communication through such seals. This work provides a route to create stretchable yet hermetic packaging design solutions for soft devices.  more » « less
Award ID(s):
2032409
PAR ID:
10496545
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
Science
Date Published:
Journal Name:
Science
Volume:
379
Issue:
6631
ISSN:
0036-8075
Page Range / eLocation ID:
488 to 493
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. The soft composition of many natural thermofluidic systems allows them to effectively move heat and control its transfer rate by dynamically changing shape ( e.g. dilation or constriction of capillaries near our skin). So far, making analogous deformable “soft thermofluidic systems” has been limited by the low thermal conductivity of materials with suitable mechanical properties. By remaining soft and stretchable despite the addition of filler, elastomer composites with thermal conductivity enhanced by liquid-metal micro-droplets provide an ideal material for this application. In this work, we use these materials to develop an elementary thermofluidic system consisting of a soft, heat generating pipe that is internally cooled with flow of water and explore its thermal behavior as it undergoes large shape change. The transient device shape change invalidates many conventional assumptions employed in thermal design making analysis of this devices’ operation a non-trivial undertaking. To this end, using time scale analysis we demonstrate when the conventional assumptions break down and highlight conditions under which the quasi-static assumption is applicable. In this gradual shape modulation regime the actuated devices’ thermal behavior at a given stretch approaches that of a static device with equivalent geometry. We validate this time scale analysis by experimentally characterizing thermo-fluidic behavior of our soft system as it undergoes axial periodic extension–retraction at varying frequencies during operation. By doing so we explore multiple shape modulation regimes and provide a theoretical foundation to be used in the design of soft thermofluidic systems undergoing transient deformation. 
    more » « less
  2. Immersion-cooled battery thermal management systems (BTMSs) are generally designed and analyzed using numerical simulations. These models must couple the electrochemical and thermal–fluid physics for accurate results. However, such a numerical approach is computationally expensive and may not be feasible, particularly for large systems. Here, we develop a computationally efficient approach to study immersion cooling-based BTMSs with the coupled physics. After validating the simplified immersion-cooled battery model for fixed convection coefficient, we then define two simplified immersion cooling models: one using existing heat transfer correlations and the other employing customized correlations trained from fully-coupled numerical models. The trained models are highly accurate (error <3%). Moreover, they are very flexible as they can be formulated to study different combinations of mass flow rates, fluids, and discharge rates using a single heat transfer correlation. Additionally, the trained models are data-frugal, requiring only data from two mass flow rates (for a given fluid and discharge rate) to predict the response for other mass flow rates. The significant reduction in computation cost [from hours or days for the fully-coupled numerical models to seconds for proposed models] makes the proposed approach more suitable for rapid analysis, optimization, and real-time implementation of the immersion-cooled BTMSs. 
    more » « less
  3. Structure–property–process relationships are a controlling factor in the performance of materials. This offers opportunities in emerging areas, such as stretchable conductors, to control process conditions during printing to enhance performance. Herein, by systematically tuning direct ink write (DIW) process parameters, the electrical conductivity of multiphase liquid metal (LM)-silver stretchable conductors is increased by a maximum of 400% to over 1.06 × 106 S·m–1. This is achieved by modulating the DIW print velocity, which enables the in situ elongation, coalescence, and percolation of these multiphase inclusions during printing. These DIW printed filaments are conductive as fabricated and are soft (modulus as low as 1.1 MPa), stretchable (strain limit >800%), and show strain invariant conductivity up to 80% strain. These capabilities are demonstrated through a set of electromagnetic induction coils that can transfer power wirelessly through air and water, even under deformation. This work provides a methodology to program properties in stretchable conductors, where the combination of material composition and process parameters leads to greatly enhanced performance. This approach can find use in applications such as soft robots, soft electronics, and printed materials for deformable, yet highly functional devices. 
    more » « less
  4. Abstract Microvascular materials containing internal microchannels are able to achieve multi-functionality by flowing different fluids through vasculature. Active cooling is one application to protect structural components and devices from thermal overload, which is critical to modern technology including electric vehicle battery packaging and solar panels on space probes. Creating thermally efficient vascular network designs requires state-of-the-art computational tools. Prior optimization schemes have only considered steady-state cooling, rendering a knowledge gap for time-varying heat transfer behavior. In this study, a transient topology optimization framework is presented to maximize the active-cooling performance and mitigate computational cost. Here, we optimize the channel layout so that coolant flowing within the vascular network can remove heat quickly and also provide a lower steady-state temperature. An objective function for this new transient formulation is proposed that minimizes the area beneath the average temperature versus time curve to simultaneously reduce the temperature and cooling time. The thermal response of the system is obtained through a transient Geometric Reduced Order Finite Element Model (GRO-FEM). The model is verified via a conjugate heat transfer simulation in commercial software and validated by an active-cooling experiment conducted on a 3D-printed microvascular metal. A transient sensitivity analysis is derived to provide the optimizer with analytical gradients of the objective function for further computational efficiency. Example problems are solved demonstrating the method’s ability to enhance cooling performance along with a comparison of transient versus steady-state optimization results. In this comparison, both the steady-state and transient frameworks delivered different designs with similar performance characteristics for the problems considered in this study. This latest computational framework provides a new thermal regulation toolbox for microvascular material designers. 
    more » « less
  5. Significance We develop temperature sensors on the basis of charges accumulated at the electrolyte/dielectric interface and dielectric/electrode interface. The accumulated charges make the temperature sensors self-powered, which simplifies circuit design and enables portable sensing. The sensors are stretchable, but deformation does not affect temperature sensing. The sensors have high sensitivity and fast response. They can be made small and transparent. Such temperature sensors open new possibilities to create human–machine interfaces and soft robots in healthcare and engineering. 
    more » « less