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Subcritical crack growth can occur under a constant applied load below the threshold value for catastrophic failure, also known as static fatigue. Here, we report how a crack grows under a combination of stress-intensity factor (K) and temperature in a model brittle glass using molecular dynamics simulations. The model glass is under dry conditions, thus avoiding the complexity of corrosion chemistry. The crack growth rate is shown to be inconsistent with the commonly used subcritical crack growth model rooted in the transition state theory (TST), in which the applied stress-intensity factor reduces the transition barrier. A new subcritical crack growth model is proposed with a constant barrier and a K-dependent prefactor in TST, representing the size of the region for potential bond breaking. The thermomechanical condition for subcritical crack growth is also mapped in the K-T domain, in between elastic deformation and catastrophic fracture regimes. Finally, we show substantial crack self-healing once the applied load is removed, under the thermodynamic driving force of surface energy reduction. Our findings provide new insights into the mechanochemical coupling during static fatigue and call for experimental investigation of whether the activation energy is K-dependent.
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Delayed fracture caused by time-dependent damage in PDMS
An experimental and theoretical study of delayed fracture of polydimethlsiloxane (PDMS) is presented. Previous works have demonstrated that delayed fracture in single edge notch specimens is caused by time dependent damage due to chain scission. Here we study the interactions between damage and the elastic field using different specimens and crack geometries with blunt and sharp cracks. Our experiments show that initial toughness is not well defined, as stable slow crack growth can occur over a range of applied loads. Our experiments demonstrate that there is a universal relation between crack growth rate and applied energy release rate. A model coupling the nonlinear elastic deformation and rate dependent bond scission is proposed and is in good agreement with experimental data.
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- Award ID(s):
- 1903308
- PAR ID:
- 10498675
- Publisher / Repository:
- Elsevier
- Date Published:
- Journal Name:
- Journal of the Mechanics and Physics of Solids
- Volume:
- 181
- Issue:
- C
- ISSN:
- 0022-5096
- Page Range / eLocation ID:
- 105459
- Subject(s) / Keyword(s):
- delayed fracture Crack growth Catastrophic failure PDMS Time-dependent damage
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1016/j.jmps.2023.105459
