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Abstract The biological chromophore xanthommatin (Xa) contributes to the yellow, red, and brown colors and hues in cephalopods and arthropods. In many cases, Xa is also present as part of or coupled to supramolecular nanostructures, whose function has yet to be fully explored. To investigate how such structural elements impact the perceived color of these natural chromophores, amorphous photonic assemblies containing Xa chemically coupled to 100 nm polystyrene nanoparticles (PS100‐XA) are fabricated, and blended with pure polystyrene (PS) nanoparticles of varying sizes. Structural colors are observed comprising these bidispersed colloidal assemblies that are tuned by the particle size of PS nanoparticles, the concentration of PS100‐XA, the local environment, and the method of assembly. In all cases, the addition of PS100‐XA regulates the color hue and contrast of the resultant assemblies by increasing light absorption while minimizing incoherent light scattering. Taken together, the results demonstrate how biochromes like Xa can enhance the color intensity and the diversity in colors present in common photonic assemblies.
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Predicting the Structural Colors of Films of Disordered Photonic Balls
Photonic balls are spheres tens of micrometers in diameter containing assemblies of nanoparticles or nanopores with a spacing comparable to the wavelength of light. When these nanoscale features are disordered, but still correlated, the photonic balls can show structural color with low angle-dependence. Their colors, combined with the ability to add them to a liquid formulation, make photonic balls a promising new type of pigment particle for paints, coatings, and other applications. However, it is challenging to predict the color of materials made from photonic balls because the sphere geometry and multiple scattering must be accounted for. To address these challenges, we develop a multiscale modeling approach involving Monte Carlo simulations of multiple scattering at two different scales: we simulate multiple scattering and absorption within a photonic ball and then use the results to simulate multiple scattering and absorption in a film of photonic balls. After validating against experimental spectra, we use the model to show that films of photonic balls scatter light in fundamentally different ways than do homogeneous films of nanopores or nanoparticles, because of their increased surface area and refraction at the interfaces of the balls. Both effects tend to sharply reduce color saturation relative to a homogeneous nanostructured film. We show that saturated colors can be achieved by placing an absorber directly in the photonic balls and mitigating surface roughness. With these design rules, we show that photonic-ball films have an advantage over homogeneous nanostructured films: their colors are even less dependent on the angle.
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- Award ID(s):
- 2011754
- PAR ID:
- 10500419
- Publisher / Repository:
- ACS
- Date Published:
- Journal Name:
- ACS Photonics
- Volume:
- 10
- Issue:
- 1
- ISSN:
- 2330-4022
- Page Range / eLocation ID:
- 58 to 70
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1021/acsphotonics.2c00892
