Conical surfaces, with a δ function of Gaussian curvature at the apex, are perhaps the simplest example of geometric frustration. We study two-dimensional liquid crystals with p-fold rotational symmetry (p-atics) on the surfaces of cones. For free boundary conditions at the base, we find both the ground state(s) and a discrete ladder of metastable states as a function of both the cone angle and the liquid crystal symmetry p. We find that these states are characterized by a set of fractional defect charges at the apex and that the ground states are in general frustrated due to effects of parallel transport along the azimuthal direction of the cone. We check our predictions for the ground-state energies numerically for a set of commensurate cone angles (corresponding to a set of commensurate Gaussian curvatures concentrated at the cone apex), whose surfaces can be polygonized as a perfect triangular or squaremesh, and find excellent agreement with our theoretical predictions.
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Geometric frustration of hard-disk packings on cones
Conical surfaces pose an interesting challenge to crystal growth: A crystal growing on a cone can wrap around and meet itself at different radii. We use a disk-packing algorithm to investigate how this closure constraint can geometrically frustrate the growth of single crystals on cones with small opening angles. By varying the crystal seed orientation and cone angle, we find that—except at special commensurate cone angles—crystals typically form a seam that runs along the axial direction of the cone, while near the tip, a disordered particle packing forms. We show that the onset of disorder results from a finite-size effect that depends strongly on the circumference and not on the seed orientation or cone angle. This finite-size effect occurs also on cylinders, and we present evidence that on both cylinders and cones, the defect density increases exponentially as circumference decreases. We introduce a simple model for particle attachment at the seam that explains the dependence on the circumference. Our findings suggest that the growth of single crystals can become frustrated even very far from the tip when the cone has a small opening angle. These results may provide insights into the observed geometry of conical crystals in biological and materials applications.
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- Award ID(s):
- 2011754
- PAR ID:
- 10500454
- Publisher / Repository:
- APS
- Date Published:
- Journal Name:
- Physical Review E
- Volume:
- 108
- Issue:
- 5
- ISSN:
- 2470-0045
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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