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Title: Cavity-modified Fermi’s golden rule rate constants: Beyond the single mode approximation
We extend our recently proposed theoretical framework for estimating cavity-modified equilibrium Fermi’s golden rule (FGR) rate constants beyond the single cavity mode case to cases where the molecular system is coupled to multiple cavity modes. We show that the cumulative effect of simultaneous coupling to multiple modes can enhance FGR rate constants by orders of magnitude relative to the single mode case. We also present an analysis of the conditions necessary for maximizing this effect in the Marcus limit of FGR-based rate theory.  more » « less
Award ID(s):
2154114
PAR ID:
10500769
Author(s) / Creator(s):
; ;
Publisher / Repository:
American Institute of Physics
Date Published:
Journal Name:
The Journal of Chemical Physics
Volume:
159
Issue:
15
ISSN:
0021-9606
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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