skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.

Attention:

The NSF Public Access Repository (PAR) system and access will be unavailable from 11:00 PM ET on Thursday, June 12 until 2:00 AM ET on Friday, June 13 due to maintenance. We apologize for the inconvenience.


Title: Raman study of layered breathing kagome lattice semiconductor Nb 3 Cl 8
Abstract Niobium chloride (Nb3Cl8) is a layered two-dimensional semiconducting material with many exotic properties including a breathing kagome lattice, a topological flat band in its band structure, and a crystal structure that undergoes a structural and magnetic phase transition at temperatures below 90 K. Despite being a remarkable material with fascinating new physics, the understanding of its phonon properties is at its infancy. In this study, we investigate the phonon dynamics of Nb3Cl8in bulk and few layer flakes using polarized Raman spectroscopy and density-functional theory (DFT) analysis to determine the material’s vibrational modes, as well as their symmetrical representations and atomic displacements. We experimentally resolved 12 phonon modes, five of which areA1gmodes while the remaining seven areEgmodes, which is in strong agreement with our DFT calculation. Layer-dependent results suggest that the Raman peak positions are mostly insensitive to changes in layer thickness, while peak intensity and full width at half maximum are affected. Raman measurements as a function of excitation wavelength (473–785 nm) show a significant increase of the peak intensities when using a 473 nm excitation source, suggesting a near resonant condition. Temperature-dependent Raman experiments carried out above and below the transition temperature did not show any change in the symmetries of the phonon modes, suggesting that the structural phase transition is likely from the high temperatureP 3 m ˉ 1 phase to the low-temperatureR 3 m ˉ phase. Magneto-Raman measurements carried out at 140 and 2 K between −2 and 2 T show that the Raman modes are not magnetically coupled. Overall, our study presented here significantly advances the fundamental understanding of layered Nb3Cl8material which can be further exploited for future applications.  more » « less
Award ID(s):
1719797 2121953
PAR ID:
10506547
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
IOP Science
Date Published:
Journal Name:
2D Materials
Volume:
10
Issue:
4
ISSN:
2053-1583
Page Range / eLocation ID:
045030
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract State transitions in black hole X-ray binaries are likely caused by gas evaporation from a thin accretion disk into a hot corona. We present a height-integrated version of this process, which is suitable for analytical and numerical studies. With radiusrscaled to Schwarzschild units and coronal mass accretion rate m ̇ c to Eddington units, the results of the model are independent of black hole mass. State transitions should thus be similar in X-ray binaries and an active galactic nucleus. The corona solution consists of two power-law segments separated at a break radiusrb∼ 103(α/0.3)−2, whereαis the viscosity parameter. Gas evaporates from the disk to the corona forr>rb, and condenses back forr<rb. Atrb, m ̇ c reaches its maximum, m ̇ c , max 0.02 ( α / 0.3 ) 3 . If atr≫rbthe thin disk accretes with m ̇ d < m ̇ c , max , then the disk evaporates fully before reachingrb, giving the hard state. Otherwise, the disk survives at all radii, giving the thermal state. While the basic model considers only bremsstrahlung cooling and viscous heating, we also discuss a more realistic model that includes Compton cooling and direct coronal heating by energy transport from the disk. Solutions are again independent of black hole mass, andrbremains unchanged. This model predicts strong coronal winds forr>rb, and aT∼ 5 × 108K Compton-cooled corona forr<rb. Two-temperature effects are ignored, but may be important at small radii. 
    more » « less
  2. Abstract Charge density wave (CDW) ordering has been an important topic of study for a long time owing to its connection with other exotic phases such as superconductivity and magnetism. The$$R{\textrm{Te}}_{3}$$ R Te 3 (R= rare-earth elements) family of materials provides a fertile ground to study the dynamics of CDW in van der Waals layered materials, and the presence of magnetism in these materials allows to explore the interplay among CDW and long range magnetic ordering. Here, we have carried out a high-resolution angle-resolved photoemission spectroscopy (ARPES) study of a CDW material$${\textrm{Gd}}{\textrm{Te}}_{3}$$ Gd Te 3 , which is antiferromagnetic below$$\sim \mathrm {12~K}$$ 12 K , along with thermodynamic, electrical transport, magnetic, and Raman measurements. Our ARPES data show a two-fold symmetric Fermi surface with both gapped and ungapped regions indicative of the partial nesting. The gap is momentum dependent, maximum along$${\overline{\Gamma }}-\mathrm{\overline{Z}}$$ Γ ¯ - Z ¯ and gradually decreases going towards$${\overline{\Gamma }}-\mathrm{\overline{X}}$$ Γ ¯ - X ¯ . Our study provides a platform to study the dynamics of CDW and its interaction with other physical orders in two- and three-dimensions. 
    more » « less
  3. Abstract We measure the CO-to-H2conversion factor (αCO) in 37 galaxies at 2 kpc resolution, using the dust surface density inferred from far-infrared emission as a tracer of the gas surface density and assuming a constant dust-to-metal ratio. In total, we have ∼790 and ∼610 independent measurements ofαCOfor CO (2–1) and (1–0), respectively. The mean values forαCO (2–1)andαCO (1–0)are 9.3 5.4 + 4.6 and 4.2 2.0 + 1.9 M pc 2 ( K km s 1 ) 1 , respectively. The CO-intensity-weighted mean is 5.69 forαCO (2–1)and 3.33 forαCO (1–0). We examine howαCOscales with several physical quantities, e.g., the star formation rate (SFR), stellar mass, and dust-mass-weighted average interstellar radiation field strength ( U ¯ ). Among them, U ¯ , ΣSFR, and the integrated CO intensity (WCO) have the strongest anticorrelation with spatially resolvedαCO. We provide linear regression results toαCOfor all quantities tested. At galaxy-integrated scales, we observe significant correlations betweenαCOandWCO, metallicity, U ¯ , and ΣSFR. We also find thatαCOin each galaxy decreases with the stellar mass surface density (Σ) in high-surface-density regions (Σ≥ 100Mpc−2), following the power-law relations α CO ( 2 1 ) Σ 0.5 and α CO ( 1 0 ) Σ 0.2 . The power-law index is insensitive to the assumed dust-to-metal ratio. We interpret the decrease inαCOwith increasing Σas a result of higher velocity dispersion compared to isolated, self-gravitating clouds due to the additional gravitational force from stellar sources, which leads to the reduction inαCO. The decrease inαCOat high Σis important for accurately assessing molecular gas content and star formation efficiency in the centers of galaxies, which bridge “Milky Way–like” to “starburst-like” conversion factors. 
    more » « less
  4. Abstract Parker Solar Probe (PSP) observed sub-Alfvénic solar wind intervals during encounters 8–14, and low-frequency magnetohydrodynamic (MHD) turbulence in these regions may differ from that in super-Alfvénic wind. We apply a new mode decomposition analysis to the sub-Alfvénic flow observed by PSP on 2021 April 28, identifying and characterizing entropy, magnetic islands, forward and backward Alfvén waves, including weakly/nonpropagating Alfvén vortices, forward and backward fast and slow magnetosonic (MS) modes. Density fluctuations are primarily and almost equally entropy- and backward-propagating slow MS modes. The mode decomposition provides phase information (frequency and wavenumberk) for each mode. Entropy density fluctuations have a wavenumber anisotropy ofk≫k, whereas slow-mode density fluctuations havek>k. Magnetic field fluctuations are primarily magnetic island modes (δBi) with anO(1) smaller contribution from unidirectionally propagating Alfvén waves (δBA+) giving a variance anisotropy of δ B i 2 / δ B A 2 = 4.1 . Incompressible magnetic fluctuations dominate compressible contributions from fast and slow MS modes. The magnetic island spectrum is Kolmogorov-like k 1.6 in perpendicular wavenumber, and the unidirectional Alfvén wave spectra are k 1.6 and k 1.5 . Fast MS modes propagate at essentially the Alfvén speed with anticorrelated transverse velocity and magnetic field fluctuations and are almost exclusively magnetic due toβp≪ 1. Transverse velocity fluctuations are the dominant velocity component in fast MS modes, and longitudinal fluctuations dominate in slow modes. Mode decomposition is an effective tool in identifying the basic building blocks of MHD turbulence and provides detailed phase information about each of the modes. 
    more » « less
  5. Abstract The growth of supermassive black holes is strongly linked to their galaxies. It has been shown that the population mean black hole accretion rate ( BHAR ¯ ) primarily correlates with the galaxy stellar mass (M) and redshift for the general galaxy population. This work aims to provide the best measurements of BHAR ¯ as a function ofMand redshift over ranges of 109.5<M< 1012Mandz< 4. We compile an unprecedentedly large sample with 8000 active galactic nuclei (AGNs) and 1.3 million normal galaxies from nine high-quality survey fields following a wedding cake design. We further develop a semiparametric Bayesian method that can reasonably estimate BHAR ¯ and the corresponding uncertainties, even for sparsely populated regions in the parameter space. BHAR ¯ is constrained by X-ray surveys sampling the AGN accretion power and UV-to-infrared multiwavelength surveys sampling the galaxy population. Our results can independently predict the X-ray luminosity function (XLF) from the galaxy stellar mass function (SMF), and the prediction is consistent with the observed XLF. We also try adding external constraints from the observed SMF and XLF. We further measure BHAR ¯ for star-forming and quiescent galaxies and show that star-forming BHAR ¯ is generally larger than or at least comparable to the quiescent BHAR ¯
    more » « less