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1. Room temperature optically detected magnetic resonance of single spins in GaN

   https://doi.org/10.1038/s41563-024-01803-5  

   Luo, Jialun; Geng, Yifei; Rana, Farhan; Fuchs, Gregory D. (February 2024, Nature Materials)

   High-contrast optically detected magnetic resonance is a valuable property for reading out the spin of isolated defect colour centres at room temperature. Spin-active single defect centres have been studied in wide bandgap materials including diamond, SiC and hexagonal boron nitride, each with associated advantages for applications. We report the discovery of optically detected magnetic resonance in two distinct species of bright, isolated defect centres hosted in GaN. In one group, we find negative optically detected magnetic resonance of a few percent associated with a metastable electronic state, whereas in the other, we find positive optically detected magnetic resonance of up to 30% associated with the ground and optically excited electronic states. We examine the spin symmetry axis of each defect species and establish coherent control over a single defect’s ground-state spin. Given the maturity of the semiconductor host, these results are promising for scalable and integrated quantum sensing applications. 

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2. High resolution spectroscopy of thulium atoms implanted in solid noble gas crystals

   https://doi.org/10.1103/PhysRevB.108.214101  

   Gaire, Vinod; Do, Mi Y.; Pei, Yiting; Semenova, Anthony; Parker, Colin V. (December 2023, Physical Review B)

   Optically active defects in solid-state systems have many applications in quantum information and sensing. However, unlike free atoms, which have fixed optical transition frequencies, the inhomogeneous broadening of the transitions in solid-state environments limit their use as identical scatterers for such applications. Here we show that crystals of argon and neon prepared in a closed-cycle cryostat doped with thulium atoms at cryogenic temperatures are an exception. High resolution absorption and emission spectroscopy show that the 1140 nm magnetic dipole transition is split into multiple components. The origin of this splitting is likely a combination of different classes of trapping sites, crystal field effects within each site, and hyperfine interactions. The individual lines have ensemble widths as small as 0.6 GHz, which temperature dependence and pump-probe spectroscopy indicate is likely a homogeneous effect, suggesting inhomogeneity is well below the GHz scale. 

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3. Electrical control of coherent spin rotation of a single-spin qubit

   https://doi.org/10.1038/s41534-020-00308-8  

   Wang, Xiaoche; Xiao, Yuxuan; Liu, Chuanpu; Lee-Wong, Eric; McLaughlin, Nathan J.; Wang, Hanfeng; Wu, Mingzhong; Wang, Hailong; Fullerton, Eric E.; Du, Chunhui Rita (December 2020, npj Quantum Information)

   null (Ed.)

   Abstract Nitrogen vacancy (NV) centers, optically active atomic defects in diamond, have attracted tremendous interest for quantum sensing, network, and computing applications due to their excellent quantum coherence and remarkable versatility in a real, ambient environment. One of the critical challenges to develop NV-based quantum operation platforms results from the difficulty in locally addressing the quantum spin states of individual NV spins in a scalable, energy-efficient manner. Here, we report electrical control of the coherent spin rotation rate of a single-spin qubit in NV-magnet based hybrid quantum systems. By utilizing electrically generated spin currents, we are able to achieve efficient tuning of magnetic damping and the amplitude of the dipole fields generated by a micrometer-sized resonant magnet, enabling electrical control of the Rabi oscillation frequency of NV spins. Our results highlight the potential of NV centers in designing functional hybrid solid-state systems for next-generation quantum-information technologies. The demonstrated coupling between the NV centers and the propagating spin waves harbored by a magnetic insulator further points to the possibility to establish macroscale entanglement between distant spin qubits. 

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4. Sensing spin wave excitations by spin defects in few-layer-thick hexagonal boron nitride

   https://doi.org/10.1126/sciadv.adk8495  

   Zhou, Jingcheng; Lu, Hanyi; Chen, Di; Huang, Mengqi; Yan, Gerald Q; Al-matouq, Faris; Chang, Jiu; Djugba, Dziga; Jiang, Zhigang; Wang, Hailong; et al (May 2024, Science Advances)

   Optically active spin defects in wide bandgap semiconductors serve as a local sensor of multiple degrees of freedom in a variety of “hard” and “soft” condensed matter systems. Taking advantage of the recent progress on quantum sensing using van der Waals (vdW) quantum materials, here we report direct measurements of spin waves excited in magnetic insulator Y₃Fe₅O₁₂(YIG) by boron vacancy $V_{\mathrm{B}}^{-}$spin defects contained in few-layer-thick hexagonal boron nitride nanoflakes. We show that the ferromagnetic resonance and parametric spin excitations can be effectively detected by $V_{\mathrm{B}}^{-}$spin defects under various experimental conditions through optically detected magnetic resonance measurements. The off-resonant dipole interaction between YIG magnons and $V_{\mathrm{B}}^{-}$spin defects is mediated by multi-magnon scattering processes, which may find relevant applications in a range of emerging quantum sensing, computing, and metrology technologies. Our results also highlight the opportunities offered by quantum spin defects in layered two-dimensional vdW materials for investigating local spin dynamic behaviors in magnetic solid-state matters. 

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5. Room-temperature quantum sensing with photoexcited triplet electrons in organic crystals

   https://doi.org/10.1103/PhysRevResearch.7.013192  

   Singh, Harpreet; D'Souza, Noella; Zhong, Keyuan; Druga, Emanuel; Oshiro, Julianne; Blankenship, Brian; Montis, Riccardo; Reimer, Jeffrey A; Breeze, Jonathan D; Ajoy, Ashok (February 2025, Physical Review Research)

   Quantum sensors have notably advanced high-sensitivity magnetic field detection. Here, we report quantum sensors constructed from polarized spin-triplet electrons in photoexcited organic chromophores, specifically focusing on pentacene-doped para-terphenyl $(\approx 0.1\%)$. We demonstrate essential quantum sensing properties at room temperature (RT): optically generated electronic polarization and state-dependent fluorescence contrast by leveraging differential pumping and relaxation rates between triplet and ground states. We measure high optically detected magnetic resonance contrast $\approx 16.8\%$of the triplet states at RT, along with long coherence times under spin echo and Carr-Purcell-Meiboom-Gill (CPMG) sequences, $T_2=2.7\mu \mathrm{s}$and $T_2^{\text{DD}}=18.4\mu \mathrm{s}$, respectively, limited only by the triplet lifetimes. The material offers several advantages for quantum sensing, including the ability to grow large (cm scale) crystals at low cost, absence of paramagnetic impurities, and electronic diamagnetism when not optically illuminated. Utilizing pentacene as a representative of a broader class of spin triplet- polarizable organic molecules, this paper highlights the potential for quantum sensing in chemical systems. 

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