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  • Chaotropic Salt‐Aided “Water‐In‐Organic” Electrolyte for Highly Reversible Zinc‐Ion Batteries Across a Wide Temperature Range
Title: Chaotropic Salt‐Aided “Water‐In‐Organic” Electrolyte for Highly Reversible Zinc‐Ion Batteries Across a Wide Temperature Range
Abstract Aqueous zinc‐ion batteries are promising alternatives to lithium‐ion batteries due to their cost‐effectiveness and improved safety. However, several challenges, including corrosion, dendrites, and water decomposition at the Zn anode, hinder their performance. Herein, an approach is proposed, that deviates from the conventional design by adding water into a propylene carbonate‐based organic electrolyte to prepare a non‐flammable “water‐in‐organic” electrolyte. The chaotropic salt Zn(ClO4)2exploits the Hofmeister effect to promote the miscibility of immiscible liquid phases. Interactions between propylene carbonate and water restrict water activity and mitigate unfavorable reactions. This electrolyte facilitates preferential Zn (002) deposition and the formation of solid electrolyte interphase. Consequently, the “water‐in‐organic” electrolyte achieves a 99.5% Coulombic efficiency at 1 mA cm−2over 1000 cycles in Zn/Cu cells, and constant cycling over 1000 h in Zn/Zn symmetric cells. A Na0.33V2O5/Zn battery exhibits impressive cycling stability with a capacity of 175 mAh g−1for 800 cycles at 2 A g−1. Additionally, this electrolyte enables sustainable cycling across a wide temperature range from −20 to 50 °C. The design of a “water‐in‐organic” electrolyte employing a chaotropic salt presents a potential strategy for high‐performance electrolytes in zinc‐ion batteries with a large stability window and a wide temperature range.  more » « less
Award ID(s):
1720595
PAR ID:
10509911
Author(s) / Creator(s):
; ; ; ; ; ;
Publisher / Repository:
Wiley
Date Published:
Journal Name:
Advanced Functional Materials
Volume:
34
Issue:
9
ISSN:
1616-301X
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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