Abstract We report new measurements of branching fractions for 20 UV and blue lines in the spectrum of neutral silicon (Sii) originating in the 3s23p4s3Po1,2,1Po1, and 3s3p31Do1,2upper levels. Transitions studied include both strong, nearly pure LS multiplets as well as very weak spin-forbidden transitions connected to these upper levels. We also report a new branching fraction measurement of the4P1/2–2Po1/2,3/2intercombination lines in the spectrum of singly ionized silicon (Siii). The weak spin-forbidden lines of Siiand Siiiprovide a stringent test on recent theoretical calculations, to which we make comparison. The branching fractions from this study are combined with previously reported radiative lifetimes to yield transition probabilities and log(gf) values for these lines. We apply these new measurements to abundance determinations in five metal-poor stars.
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Multiexciton quintet state populations in a rigid pyrene-bridged parallel tetracene dimer
The multiexciton quintet state,5TT, generated as a singlet fission intermediate in pairs of molecular chromophores, is a promising candidate as a qubit or qudit in future quantum information science schemes.
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- Award ID(s):
- 2102713
- PAR ID:
- 10512592
- Publisher / Repository:
- Royal Society of Chemistry
- Date Published:
- Journal Name:
- Chemical Science
- Volume:
- 14
- Issue:
- 41
- ISSN:
- 2041-6520
- Page Range / eLocation ID:
- 11554 to 11565
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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