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1. Group 13 ion coordination to pyridyl breaks the reduction potential vs hydricity scaling relationship for NADH models

   https://doi.org/10.1039/d3sc03806h  

   Parsons, Leo_W T; Fettinger, James C; Berben, Louise A (December 2023, Chemical Science)

   The relationshipE_pvs. ΔG_H− correlates the applied potential (E_p) needed to drive organohydride formation with the strength of the hydride donor that is formed: hydride transfer catalysis - as in enzymes like LarA - will be more energy efficient ifE_pis shifted anodically using kinetic effect. 

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2. Ranked Document Retrieval in External Memory

   https://doi.org/10.1145/3559763  

   Shah, Rahul; Sheng, Cheng; Thankachan, Sharma; Vitter, Jeffrey (January 2023, ACM Transactions on Algorithms)

   The ranked (or top-k) document retrieval problem is defined as follows: preprocess a collection{T₁,T₂,… ,T_d}ofdstrings (called documents) of total lengthninto a data structure, such that for any given query(P,k), wherePis a string (called pattern) of lengthp ≥ 1andk ∈ [1,d]is an integer, the identifiers of thosekdocuments that are most relevant toPcan be reported, ideally in the sorted order of their relevance. The seminal work by Hon et al. [FOCS 2009 and Journal of the ACM 2014] presented anO(n)-space (in words) data structure withO(p+klogk)query time. The query time was later improved toO(p+k)[SODA 2012] and further toO(p/log_σn+k)[SIAM Journal on Computing 2017] by Navarro and Nekrich, whereσis the alphabet size. We revisit this problem in the external memory model and present three data structures. The first one takesO(n)-space and answer queries inO(p/B+ log_Bn + k/B+log^*(n/B)) I/Os, whereBis the block size. The second one takesO(nlog^*(n/B)) space and answer queries in optimalO(p/B+ log_Bn + k/B)I/Os. In both cases, the answers are reported in the unsorted order of relevance. To handle sorted top-kdocument retrieval, we present anO(nlog(d/B))space data structure with optimal query cost. 

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3. The Influence of Climate Feedbacks on Regional Hydrological Changes Under Global Warming

   https://doi.org/10.1029/2023GL106648  

   Bonan, David_B; Feldl, Nicole; Siler, Nicholas; Kay, Jennifer_E; Armour, Kyle_C; Eisenman, Ian; Roe, Gerard_H (February 2024, Geophysical Research Letters)

   Abstract The influence of climate feedbacks on regional hydrological changes under warming is poorly understood. Here, a moist energy balance model (MEBM) with a Hadley Cell parameterization is used to isolate the influence of climate feedbacks on changes in zonal‐mean precipitation‐minus‐evaporation (P − E) under greenhouse‐gas forcing. It is shown that cloud feedbacks act to narrow bands of tropicalP − Eand increaseP − Ein the deep tropics. The surface‐albedo feedback shifts the location of maximum tropicalP − Eand increasesP − Ein the polar regions. The intermodel spread in theP − Echanges associated with feedbacks arises mainly from cloud feedbacks, with the lapse‐rate and surface‐albedo feedbacks playing important roles in the polar regions. TheP − Echange associated with cloud feedback locking in the MEBM is similar to that of a climate model with inactive cloud feedbacks. This work highlights the unique role that climate feedbacks play in causing deviations from the “wet‐gets‐wetter, dry‐gets‐drier” paradigm. 

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4. Statistics of Energy in Isothermal Supersonic Turbulence

   https://doi.org/10.3847/1538-4357/ad5008  

   Rabatin, Branislav; Collins, David_C (July 2024, The Astrophysical Journal)

   Abstract Supersonic isothermal turbulence is a common process in astrophysical systems. In this work, we explore the energy in such systems. We show that the conserved energy is the sum of the kinetic energy (K) and Helmholtz free energy (F). We develop analytic predictions for the probability distributions,P(F) andP(K), as well as their nontrivial joint distribution,P(F,K). We verify these predictions with a suite of driven turbulence simulations, finding excellent agreement. The turbulence simulations were performed at Mach numbers ranging from 1 to 8, and three modes of driving: purely solenoidal, purely compressive, and mixed. We find thatP(F) is discontinuous atF= 0, with the discontinuity increasing with Mach number and compressive driving.P(K) resembles a lognormal with a negative skew. The joint distribution,P(F,K), shows a bimodal distribution, with gas either existing at highFand highKor at lowFand lowK. 

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5. Fermi isospectrality for discrete periodic Schrödinger operators

   https://doi.org/10.1002/cpa.22161  

   Liu, Wencai (September 2023, Communications on Pure and Applied Mathematics)

   Abstract Let , where , , are pairwise coprime. Let be the discrete Schrödinger operator, where Δ is the discrete Laplacian on and the potential is Γ‐periodic. We prove three rigidity theorems for discrete periodic Schrödinger operators in any dimension :If at some energy level, Fermi varieties of two real‐valued Γ‐periodic potentialsVandYare the same (this feature is referred to asFermi isospectralityofVandY), andYis a separable function, thenVis separable;If two complex‐valued Γ‐periodic potentialsVandYare Fermi isospectral and both and are separable functions, then, up to a constant, lower dimensional decompositions and are Floquet isospectral, ;If a real‐valued Γ‐potentialVand the zero potential are Fermi isospectral, thenVis zero.In particular, all conclusions in (1), (2) and (3) hold if we replace the assumption “Fermi isospectrality” with a stronger assumption “Floquet isospectrality”. 

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