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Title: Engineering Small HOMO–LUMO Gaps in Polycyclic Aromatic Hydrocarbons with Topologically Protected States
Topological phases in laterally-confined low-dimensional nanographenes have emerged as versatile design tools that can imbue otherwise unremarkable materials with exotic band structures ranging from topological semiconductors, quantum dots, to intrinsically metallic bands. The periodic boundary conditions that define the topology of a given lattice have thus far prevented the translation of this technology to the quasi zero-dimensional (0D) domain of small molecular structures. Here, we describe the synthesis of a polycyclic aromatic hydrocarbon (PAH) featuring two localized zero modes (ZMs) formed by the topological junction interface between a trivial and non-trivial phase within a single molecule. First-principles density functional theory calculations predict a strong hybridization between adjacent ZMs that gives rise to an exceptionally small HOMO-LUMO gap. Scanning tunneling microscopy and spectroscopy corroborate the molecular structure of 9/7/9-double quantum dots and reveal an experimental quasi-particle gap of 0.16 eV, corresponding to a carbon-based small molecule long-wavelength infrared (LWIR) absorber.  more » « less
Award ID(s):
2203911
PAR ID:
10515591
Author(s) / Creator(s):
; ; ; ; ; ; ;
Publisher / Repository:
Nano Letters
Date Published:
Journal Name:
Nano Letters
Volume:
24
Issue:
17
ISSN:
1530-6984
Page Range / eLocation ID:
5387 to 5392
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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