skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Recognition of porphyry quartz in stream sediments by fluid inclusion petrography and cathodoluminescence microscopy: Results of systematic dispersion studies and potential applications in porphyry exploration
Abstract Regional stream sediment surveys are an important exploration tool used in the search for concealed or partially concealed porphyry deposits. It is shown here that quartz contained in the coarse fraction of stream sediments can be used as an indicator mineral to supplement geochemical analyses conducted on the fine fraction, such as the measurement of the bulk cyanide leach extractable gold content. A method is proposed that allows separation of quartz grains from the coarse rejects of stream sediment samples to prepare grain mounts for petrographic analysis. Based on optical cathodoluminescence microscopy and fluid inclusion petrography, the number of porphyry quartz grains in each grain mount is then identified. Case studies conducted at Vert de Gris in Haiti and Hides Creek in Papua New Guinea show that porphyry quartz grains could be confidently identified in sediments in the catchment areas of both porphyries. Because the cost of microscopic analysis of quartz is small compared to the expense of sampling and geochemical analysis, the developed technique could be routinely used in large greenfield exploration programs. It is envisaged here that petrographic analysis of quartz grains can contribute valuable information for prioritization of targets defined based on their geochemical signatures.  more » « less
Award ID(s):
2310920 1822146
PAR ID:
10525198
Author(s) / Creator(s):
; ; ;
Publisher / Repository:
Society of Economic Geologists
Date Published:
Journal Name:
Economic Geology
Volume:
119
Issue:
3
ISSN:
0361-0128
Page Range / eLocation ID:
713 to 724
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract. Silt-rich meltwater plume deposits (MPDs) analyzed from marine sediment cores have elucidated relationships that are clearly connected, yet difficult to constrain, between subglacial hydrology, ice-marginal landforms, and grounding-zone retreat patterns for several glacial catchments. Few attempts have been made to infer details of subglacial hydrology, such as flow regime, geometry of drainage pathways, and mode(s) of sediment transport through time, from grain-scale characteristics of MPDs. Using sediment samples from MPD, till, and grounding-zone proximal diamicton collected offshore of six modern and relict glacial catchments in both hemispheres, we examine grain shape distributions and microtextures (collectively, grain micromorphology) of the silt fraction to explore whether grains are measurably altered from their subglacial sources via meltwater action. We find that 75 % of all imaged grains (n = 9400) can be described by 25 % of the full range of measured shape morphometrics, indicating grain shape homogenization through widespread and efficient abrasive processes in subglacial environments. Although silt grains from MPDs exhibit edge rounding more often than silt grains from tills, grain surface textures indicative of fluvial transport (e.g., v-shaped percussions) occur in only a modest number of grains. Furthermore, MPD grain surfaces retain several textures consistent with transport beneath glacial ice (e.g., straight or arcuate steps, (sub)linear fractures) in comparable abundances to till grains. Significant grain shape alteration in MPDs compared to their till sources is observed in sediments from glacial regions where (1) high-magnitude, potentially catastrophic meltwater drainage events are inferred from marine sediment records and (2) submarine landforms suggest supraglacial melt contributed to the subglacial hydrological budget. This implies that quantifiable grain shape alteration in MPDs could reflect a combination of high-energy flow of subglacial meltwater, persistent sediment entrainment, and/or long sediment transport distances through subglacial drainage pathways. Integrating grain micromorphology into analysis of MPDs in site-specific studies could therefore aid in distinguishing periods of persistent, well-connected subglacial discharge from periods of sluggish or disorganized drainage. In the wider context of deglacial marine sedimentary and bathymetric records, a grain micromorphological approach may bolster our ability to characterize ice response to subglacial meltwater transmission through time. This work additionally demonstrates that glacial and fluvial surface textures are retained on silt-sized quartz grains in adequate amounts for microtexture analysis, which has heretofore been conducted exclusively on the sand fraction. Therefore, grain microtextures can be examined on silt-rich glaciogenic deposits that contain little to no sand as a means to evaluate sediment transport processes. 
    more » « less
  2. Abstract On high‐latitude continental margins sediment is supplied from land to the deep sea through a variety of processes, including iceberg and sea‐ice rafting, and bottom current transport. The accurate reconstruction of sediment fluxes from these sources through time is important in palaeoclimate reconstructions. The goal of this study was to assess a shift in the intensity of glacial processes, iceberg and sea‐ice rafting during the Pliocene through an investigation of coarse sediment deposited at the AND‐2A site in the Ross Sea and at International Ocean Discovery Program Site U1359 on the Antarctic continental rise. Terrigenous particle‐size distributions and suites of quartz grain microtextures in the sand fraction of the deep‐sea sediments were compared to those from Antarctic glaciomarine diamictites as a baseline for proximal glacial sediment in its source area. Using images acquired through Scanning Electron Microscopy, and following a quantitative approach, fewer immature and potentially glacially transported grains were found in Pliocene deep‐sea sand fractions than in ice‐contact sediments. Specifically, in the lower Pliocene interval silt and fine sand percentages are elevated, and microtextures in at least half of the sand fraction are inconsistent with a primary glacial origin. Larger numbers of chemically altered and abraded grains in the deep‐sea sand fraction, along with microtextures that are diagnostic of periglacial environments, suggest a role for eolian sediment transport. These results highlight the anomalous nature of high‐latitude sediment fluxes during prolonged periods of ice retreat. Furthermore, the identification of a significant offshore sediment flux during Antarctic deglaciation has implications for estimated nutrient supply to the Southern Ocean and the potential for high‐latitude climate feedbacks under warmer climate states. 
    more » « less
  3. null (Ed.)
    Most known porphyry Cu deposits formed in the Phanerozoic and are exclusively associated with moderately oxidized, sulfur-rich, hydrous arc-related magmas derived from partial melting of the asthenospheric mantle metasomatized by slab-derived fluids. Yet, whether similar metallogenic processes also operated in the Precambrian remains obscure. Here we address the issue by investigating the origin, fO2, and S contents of calc-alkaline plutonic rocks associated with the Haib porphyry Cu deposit in the Paleoproterozoic Richtersveld Magmatic Arc (southern Namibia), an interpreted mature island-arc setting. We show that the ca. 1886–1881 Ma ore-forming magmas, originated from a mantle-dominated source with minor crustal contributions, were relatively oxidized (1‒2 log units above the fayalitemagnetite- quartz redox buffer) and sulfur-rich. These results indicate that moderately oxidized, sulfur-rich arc magma associated with porphyry Cu mineralization already existed in the late Paleoproterozoic, probably as a result of recycling of sulfate-rich seawater or sediments from the subducted oceanic lithosphere at that time. 
    more » « less
  4. null (Ed.)
    In far-field records, the response of the East Antarctic Ice Sheet during the Pliocene shows great variability under stable greenhouse gas forcing. However, the extent, mechanisms, and feedbacks related to Pliocene Antarctic ice-sheet dynamics are poorly known from near-field archives. Here we investigate the sediment dispersal path of coarse sediment deposited as ice-rafted debris (IRD) at IODP Site U1359 on the Antarctic Wilkes Land continental rise to assess the relative importance of iceberg and sea ice rafting during the Pliocene. We analyze terrigenous particle size distributions and suites of quartz grain microtextures in ice-rafted sand in comparison to Antarctic ice-contact diamict from the Ross Sea as a baseline for glacial sediment. Using images acquired through Scanning Electron Microscopy (SEM), and following a quantitative approach, we find a smaller number of glacially weathered grains in Pliocene IRD than in ice-contact sediments, which suggests that 30-50% of the IRD is not of primary glacial or iceberg origin. Larger numbers of abraded and chemically altered grains in the IRD, along with microtextures that are diagnostic of periglacial environments, suggest a role for eolian sediment transport onto the sea ice during periods of deglaciation and then transfer to the seafloor as sea ice breaks up. Our findings are entirely consistent with modeling of the land surface exposure and surface wind field during Pliocene ice retreat. These results have implications for the interpretation of sand-dominated IRD records as proxies for ice-sheet dynamics, as well as atmospheric and oceanographic feedbacks in the high-latitude climate system. 
    more » « less
  5. ABSTRACT Organic carbon (OC) radiocarbon ( 14 C) signatures in marine surface sediments are highly variable and the causes of this heterogeneity remain ambiguous. Here, we present results from a detailed 14 C-based investigation of an Arabian Sea sediment, including measurements on organic matter (OM) in bulk sediment, specific grain size fractions, and OC decomposition products from ramped-pyrolysis-oxidation (RPO). Our results show that 14 C ages of OM increase with increasing grain size, suggesting that grain size is an important factor controlling the 14 C heterogeneity in marine sediments. Analysis of RPO decomposition products from different grain size fractions reveals an overall increase in age of corresponding thermal fractions from finer to coarser fractions. We suggest that hydrodynamic properties of sediment grains exert the important control on the 14 C age distribution of OM among grain size fractions. We propose a conceptual model to account for this dimensionality in 14 C variability that invokes two predominant modes of OM preservation within different grain size fractions of Arabian Sea sediment: finer (<63 µm) fractions are influenced by OM-mineral grain aggregation processes, giving rise to relatively uniform 14 C ages, whereas OM preserved in coarser (>63 µm) fractions includes materials encapsulated within microfossils and/or entrained fossil ( 14 C-depleted) OC hosted in detrital mineral grains. Our findings highlight the value of RPO for assessment of 14 C age variability in sedimentary OC, and for assessing mechanisms of OM preservation in aquatic sediments. 
    more » « less