Harnessing the exotic properties of molecular level nanostructures to produce novel sensors, metamaterials, and futuristic computer devices can be technologically transformative. In addition, connecting the molecular nanostructures to ferromagnetic electrodes bring the unprecedented opportunity of making spin property based molecular devices. We have demonstrated that magnetic tunnel junction based molecular spintronics device (MTJMSD) approach to address numerous technological hurdles that have been inhibiting this field for decades (P. Tyagi, J. Mater. Chem., Vol. 21, 4733). MTJMSD approach is based on producing a capacitor like a testbed where two metal electrodes are separated by an ultrathin insulator and subsequently bridging the molecule nanostructure across the insulator to transform a capacitor into a molecular device. Our prior work showed that MTJMSDs produced extremely intriguing phenomenon such as room temperature current suppression by six orders, spin photovoltaic effect, and evolution of new forms of magnetic metamaterials arising due to the interaction of the magnetic a molecule with two ferromagnetic thin films. However, making robust and reproducible electrical connections with exotic molecules with ferromagnetic electrodes is full of challenges and requires attention to MTJMSD structural stability. This paper focuses on MTJMSD stability by describing the overall fabrication protocol and the associated potential threat to reliability. MTJMSD is based on microfabrication methods such as (a) photolithography for patterning the ferromagnetic electrodes, (b) sputtering of metallic thin films and insulator, and (c) at the end electrochemical process for bridging the molecules between two ferromagnetic films separated by ∼ 2nm insulating gap. For the successful MTJMSD fabrication, the selection of ferromagnetic metal electrodes and thickness was found to be a deterministic factor in designing the photolithography, thin film deposition strategy, and molecular bridging process. We mainly used isotropic NiFe soft magnetic material and anisotropic Cobalt (Co) with significant magnetic hardness. We found Co was susceptible to chemical etching when directly exposed to photoresist developer and aged molecular solution. However, NiFe was very stable against the chemicals we used in the MTJMSD fabrication. As compared to NiFe, the Co films with > 10nm thickness were susceptible to mechanical stress-induced nanoscale deformities. However, cobalt was essential to produce (a) low leakage current before transforming the capacitor from the magnetic tunnel junction into molecular devices and (b) tailoring the magnetic properties of the ferromagnetic electrodes. This paper describes our overall MTJMSD fabrication scheme and process optimization to overcome various challenges to produce stable and reliable MTJMSDs. We also discuss the role of mechanical stresses arising during the sputtering of the ultrathin insulator and how to overcome that challenge by optimizing the insulator growth process. This paper will benefit researchers striving to make nanoscale spintronics devices for solving grand challenges in developing advanced sensors, magnetic metamaterials, and computer devices.
This content will become publicly available on October 29, 2024
This paper explores nanoscale energy sensors and absorber metamaterials that can be used in various applications, such as solar cells and infrared detectors. It is possible to gain highly efficient and adjustable energy absorption, creating absorber metamaterials at the nanoscale that enhance the performance of solar cells. These metamaterials are based on molecular spintronics devices (MSD) and magnetic tunnel junctions (MTJ). The pillar shaped MTJs are made of two ferromagnetic metals separated by an insulating barrier, such as aluminum oxide (AlOx). The manufacturing process includes photoresist spin coating on a silicon wafer, photolithography, thin film sputtering, and liftoff. Following fabrication, the top and bottom electrodes are covalently bonded by a single molecule magnet (SMM) on the exposed side edges for strong magnetic coupling that changes the magnetic properties of both ferromagnetic metals. This study has considered different thin film deposition materials, configurations, and thicknesses. Magnetic field resonance and light reflectance measurements have been performed before and after molecule attachment to understand the molecule effect on the metamaterials’ energy absorption behavior. The Electron Spin Resonance (ESR) test revealed that the devices shifted following molecule attachment in both acoustic and optical modes. Moreover, due to molecule attachment, there have been significant alterations in the MTJ’s electromagnetic wave absorption characteristics with about 49% less reflectance. This metamaterial has various potential applications in aerospace, renewable energy, sensing, imaging, and communication. It is also a cheaper alternative to traditional solar cells and can inspire the development of smart metamaterials with selective absorption and tunable response.
more » « less- Award ID(s):
- 1914751
- NSF-PAR ID:
- 10529371
- Publisher / Repository:
- American Society of Mechanical Engineers
- Date Published:
- ISBN:
- 978-0-7918-8764-6
- Format(s):
- Medium: X
- Location:
- New Orleans, Louisiana, USA
- Sponsoring Org:
- National Science Foundation
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