An official website of the United States government
Dynamics of a self-interacting sheet in shear flow
Simulations of semi-flexible, self-interacting, athermal sheets in shear flow reveal a rich conformational landscape. The conformational and rotational properties of sheets lead to shear-thinning into shear-thickening rheological behavior.
more »
« less
- Award ID(s):
- 1936696
- PAR ID:
- 10530927
- Publisher / Repository:
- RSC
- Date Published:
- Journal Name:
- Soft Matter
- Volume:
- 20
- Issue:
- 22
- ISSN:
- 1744-683X
- Page Range / eLocation ID:
- 4474 to 4487
- Subject(s) / Keyword(s):
- 2-D polymer, sheets, rheology, topology
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
The complexity of shear-induced grain boundary dynamics has been historically difficult to view at the atomic scale. Meanwhile, two-dimensional (2D) colloidal crystals have gained prominence as model systems to easily explore grain boundary dynamics at single-particle resolution but have fallen short at exploring these dynamics under shear. Here, we demonstrate how an inherent interfacial shear in 2D colloidal crystals drives microstructural evolution. By assembling paramagnetic particles into polycrystalline sheets using a rotating magnetic field, we generate a particle circulation at the interface of particle-free voids. This circulation shears the crystalline bulk, operating as both a source and sink for grain boundaries. Furthermore, we show that the Read-Shockley theory for hard-condensed matter predicts the misorientation angle and energy of shear-induced low-angle grain boundaries based on their regular defect spacing. Model systems containing shear provide an ideal platform to elucidate shear-induced grain boundary dynamics for use in engineering improved/advanced materials.more » « less
-
We use a nonequilibrium variational principle to optimize the steady-state, shear-induced interconversion of self-assembled nanoclusters of DNA-coated colloids. Employing this principle within a stochastic optimization algorithm allows us to identify design strategies for functional materials. We find that far-from-equilibrium shear flow can significantly enhance the flux between specific colloidal states by decoupling trade-offs between stability and reactivity required by systems in equilibrium. For isolated nanoclusters, we find nonequilibrium strategies for amplifying transition rates by coupling a given reaction coordinate to the background shear flow. We also find that shear flow can be made to selectively break detailed balance and maximize probability currents by coupling orientational degrees of freedom to conformational transitions. For a microphase consisting of many nanoclusters, we study the flux of colloids hopping between clusters. We find that a shear flow can amplify the flux without a proportional compromise on the microphase structure. This approach provides a general means of uncovering design principles for nanoscale, autonomous, functional materials driven far from equilibrium.more » « less
-
Abstract We report observations of multiple subscale reconnecting current sheets embedded inside a large-scale heliospheric current sheet (HCS) reconnection exhaust. The discovery was made possible by the unusual skimming trajectory of Parker Solar Probe through a sunward-directed HCS exhaust, sampling structures convecting with the exhaust outflows for more than 3 hr during Encounter 14, at a radial distance of ∼17 solar radii. A large number of subscale current sheets (SCSs) were detected inside the HCS exhaust. Remarkably, five SCSs showed direct evidence for reconnection, displaying near-Alfvénic outflow jets and bifurcated current sheets. The reconnecting SCSs all had small magnetic shears (27°–81°), i.e., strong guide fields. The thickness of the subscale reconnecting current sheets ranged from ∼60 km to ∼5000 km (∼20–2000 ion inertial lengths). The SCS exhausts were directed predominantly in the normal or out-of-plane direction of the HCS, i.e., nearly orthogonal to the HCS exhaust direction. The presence of multiple low-magnetic-shear reconnecting current sheets inside a large-scale exhaust could be associated with coalescence of multiple large flux ropes inside the HCS exhaust. The orientation of some SCS exhausts was partly in the ecliptic plane of the HCS, which may indicate that the coalescence process is highly three-dimensional. Since the coalescence process is likely short-lived, the detection of five such events inside a single HCS crossing could imply the common occurrence of flux rope coalescence in large-scale HCS reconnection exhausts.more » « less
-
Abstract In airborne radargrams, undulating periodic patterns in amplitude that overprint traditional radiostratigraphic layering are occasionally observed, however, they have yet to be analyzed from a geophysical or glaciological perspective. We present evidence supported by theory that these depth‐periodic patterns are consistent with a modulation of the received radar power due to the birefringence of polar ice, and therefore indicate the presence of bulk fabric anisotropy. Here, we investigate the periodic component of birefringence‐induced radar power recorded in airborne radar data at the eastern shear margin of Thwaites Glacier and quantify the lateral variation in azimuthal fabric strength across this margin. We find the depth variability of birefringence periodicity crossing the shear margin to be a visual expression of its shear state and its development, which appears consistent with present‐day ice deformation. The morphology of the birefringent patterns is centered at the location of maximum shear and observed in all cross‐margin profiles, consistent with predictions of ice fabric when subjected to simple shear. The englacial fabric appears stronger inside the ice stream than outward of the shear margin. The detection of birefringent periodicity from non‐polarimetric radargrams presents a novel use of subsurface radar to constrain lateral variations in fabric strength, locate present and past shear margins, and characterize the deformation history of polar ice sheets.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/D4SM00197D
