An official website of the United States government
Abstract 2D materials can be isolated as monolayer sheets when interlayer interactions involve weak van der Waals forces. These atomically thin structures enable novel topological physics and open chemical questions of how to tune the structure and properties of the sheets while maintaining them as isolated monolayers. Here, this work investigates 2D electroactive sheets that exfoliate in solution into colloidal nanosheets, but aggregate upon oxidation, giving rise to tunable interlayer charge transfer absorption and photoluminescence. This optical behavior resembles interlayer excitons, now intensely studied due to their long‐lived emission, but which remain difficult to tune through synthetic chemistry. Instead, the interlayer excitons of these framework sheets can be modulated through control of solvent, electrolyte, oxidation state, and the composition of the framework building blocks. Compared to other 2D materials, these framework sheets display the largest known interlayer binding strengths, attributable to specific orbital interactions between the sheets, and among the longest interlayer exciton lifetimes. Taken together, this study provides a microscopic basis for manipulating long‐range opto‐electronic behavior in van der Waals materials through molecular synthetic chemistry.
more »
« less
Shear annealing of a self-interacting sheet
Applying simple time-dependent shear flow protocols to simulations of semi-flexible, self-interacting, athermal sheets allows for tuning of the shapes and alignments of suspensions of these sheets.
more »
« less
- Award ID(s):
- 1936696
- PAR ID:
- 10543561
- Publisher / Repository:
- RSC
- Date Published:
- Journal Name:
- Soft Matter
- Volume:
- 20
- Issue:
- 35
- ISSN:
- 1744-683X
- Page Range / eLocation ID:
- 6952 to 6964
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Abstract The spatial scale and intensity of Earth’s magnetotail current sheet determine the magnetotail configuration, which is critical to one of the most energetically powerful phenomena in the Earth’s magnetosphere, substorms. In the absence of statistical information about plasma currents, theories of the magnetotail current sheets were mostly based on the isotropic stress balance. Such models suggest that thin current sheets cannot be long and should have strong plasma pressure gradients along the magnetotail. Using Magnetospheric Multiscale and THEMIS observations and global simulations, we explore realistic configuration of the magnetotail current sheet. We find that the magnetotail current sheet is thinner than expected from theories that assume isotropic stress balance. Observed plasma pressure gradients in thin current sheets are insufficiently strong (i.e., current sheets are too long) to balance the magnetic field line tension force. Therefore, pressure anisotropy is essential in the configuration of thin current sheets where instability precedes substorm onset.more » « less
-
Abstract We present a data set and properties of 18,785 proton kinetic-scale current sheets collected over 124 days in the solar wind using magnetic field measurements at 1/11 s resolution aboard the Wind spacecraft. We show that all of the current sheets are in the parameter range where reconnection is not suppressed by diamagnetic drift of the X-line. We argue this necessary condition for magnetic reconnection is automatically satisfied due to the geometry of current sheets dictated by their source, which is the local plasma turbulence. The current sheets are shown to be elongated along the background magnetic field and dependence of the current sheet geometry on local plasma beta is revealed. We conclude that reconnection in the solar wind is not likely to be suppressed or controlled by the diamagnetic suppression condition.more » « less
-
Soft robot deformations are typically estimated using strain sensors to infer change from a nominal shape while taking a robot‐specific mechanical model into account. This approach performs poorly during buckling and when material properties change with time, and is untenable for shape‐changing robots that don't have a well‐defined resting (unactuated) shape. Herein, these limitations are overcome using stretchable shape sensing (S3) sheets that fuse orientation measurements to estimate 3D surface contours without making assumptions about the underlying robot geometry or material properties. The S3 sheets can estimate the shape of target objects to an accuracy of ≈3 mm for an 80 mm long sheet. The authors show the S3 sheets estimating their shape while being deformed in 3D space and also attached to the surface of a silicone three‐chamber pneumatic bladder, highlighting the potential for shape‐sensing sheets to be applied, removed, and reapplied to soft robots for shape estimation. Finally, the S3 sheets detecting their own stretch up to 30% strain is demonstrated. The approach introduced herein provides a generalized method for measuring the shape of objects without making strong assumptions about the objects, thus achieving a modular, mechanics model‐free approach to proprioception for wearable electronics and soft robotics.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/D4SM00710G
